화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.29, No.4, 257-266, April, 2021
DOI10.1007/s13233-021-9031-6  Export Citation
Carbazole-Based Hyperbranched Polyester Polyol: Structural, Rheological, Thermal and Optical Properties
Edwin A. Murillo†, Margarita Cerón1, and M. Judith Percino1
  • Grupo de Investigación en Materiales Poliméricos (GIMAPOL), Departamento de Química, Universidad Francisco de Paula Santander, Avenida Gran Colombia No. 12E-96 Barrio Colsag, Cúcuta, Colombia
  • 1Laboratorio de Polímeros, Centro de Química, Instituto de Ciencias, Benemérita Universidad Autónoma de Puebla (BUAP), Complejo de Ciencias, ICUAP, Edif. 103H, 22 Sur y San Claudio, C.P. 72570 Puebla, México, Mexico
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The present study sought to obtain a hyperbranched polyester polyol derivative with fluorescent properties. Initially, a 4-((4-(9H-carbazol-9-yl)benzyl)oxy)- 4-oxobut-2-enoic acid (CAV) was synthesized and esterified with a hyperbranched polyester polyol obtained from fourth generation (HBP) to synthesize carbazolebased hyperbranched polyester polyols (HBPCAV). The proportions employed of CAV were 5, 10, 15, and 20 wt% relative to that of HBP. The grafted CAV percentage (P gCAV) increased with the CAV content. The conversion percentages (CP) of the reactions for obtaining HBPCAV were higher than 95% and the hydroxyl values (OHV) were lower than that of HBP. The modification percentage (MP) of the HBP was between 9.33 and 27.38%. Using proton nuclear magnetic resonance (1H NMR) and infrared (IR) analyses was evidenced the formation of CAV and HBPCAV. Dynamic light scattering (DLS) analysis showed that HBPCAV exhibited aggregations. The number average molar mass (M n), viscosity (η), and glass transition temperature (T g) values of the HBPCAV samples were higher than those of the HBP, and also increased with the P gCAV values. The rheological behaviors of the HBP and HBPCAV samples were mainly Newtonian and shear-thinning, respectively. All HBPCAV exhibited electroluminescent properties.
Keywords:hyperbranched polyester;carbazole derivative;esterification;modification;properties
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