화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.102, 312-320, October, 2021
DOI10.1016/j.jiec.2021.07.015  Export Citation
Deep eutectic solvents synthesis of perovskite type cerium aluminate embedded carbon nitride catalyst: High-sensitive amperometric platform for sensing of glucose in biological fluids
Umamaheswari Rajaji, Pattan-Siddappa Ganesh1, Shen-Ming Chen†, Mani Govindasamy, Sang-Youn Kim1, †, Razan A. Alshgari2, and Ganesh Shimoga1
  • Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No. 1, Chung-Hsiao East Road, Section 3, Taipei 10608, Taiwan
  • 1Interaction Laboratory, Future Convergence Engineering, Advanced Technology Research Center, Korea University of Technology and Education, Cheonan-si 31253, Chungcheongnam-do, Republic of Korea
  • 2Chemistry Deparment, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
E-mail:,
In the present work, a novel method for the green synthesis of CeAlO3 (CAO) polycrystalline powder through deep eutectic solvents (DES) was carried out by hydrothermal method. The carbon nitride (CN) was synthesized directly by fractional thermal polymerisation process. The combination of CeAlO3 with CN provides an excellent sensing platform for developing highly sensitive and stable electrocatalyst for non-enzymatic glucose (GLU) oxidation. The structural, morphological and electrochemical analysis of CeAlO3/CN (CAO/CN) shows the successful synthesis without any impurities. The synergistic effects of pyridinic-N, pyrrolic-N and graphitic-N are highly influencing and playing a prominent role in sensory performances of the prepared CAO/CN nano-electrocatalyst towards GLU sensing. The limit of detection (LOD) at CAO/CN modified glassy carbon electrode (CAO/CN/GCE) was calculated to be 0.86 nM in the linear concentration range of 0.01-1034.5 μM by amperometric method. The antiinterference, reproducibility, repeatability and stability analysis suggest the promising performance of the fabricated electrode towards GLU detection. The real time application of CAO/CN/GCE was evaluated towards GLU sensing in human blood, saliva and sweat, a satisfactory result was obtained. Therefore, the CAO/CN/GCE has a great application prospect as a highly efficient catalyst material for highly sensitive and efficient non-enzymatic glucose sensor.
Keywords:Carbon nitride;Perovskite type cerium aluminate;Diabetes;Electrochemical determination;Biological fluids analysis
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