불포화도에 따른 부틸고무 복합체의 가교 반응 연구

이상호; 최수형; 전현욱; Sangho Lee; Soo-Hyung Choi; Hyun-Uk Jeon

Polymer(Korea), Vol.45, No.4, 552-559, July, 2021

DOI10.7317/pk.2021.45.4.552 Export Citation

불포화도에 따른 부틸고무 복합체의 가교 반응 연구

Degree of Unsaturation Dependence of Curing Reaction for Butyl Rubber Complexes

이상호, 최수형^†, 전현욱¹

홍익대학교 화학공학과
¹용진유화

Sangho Lee, Soo-Hyung Choi^†, and Hyun-Uk Jeon¹

Department of Chemical Engineering, Hongik UniversityV, Seoul 04066, Korea
¹Yongjin Fine Chemical Co., Ulsan 44785, Korea

E-mail:

초록

본 연구에서는 부틸고무의 불포화도에 따른 블래더용 부틸고무 복합체의 가교 반응 속도를 연구하였다. 양이온 중합법을 이용하여 다양한 고불포화도를 갖는 고분자량 부틸고무를 합성하였다. 상용 부틸고무는 2 mol% 내외의 불포화도를 포함하고 있지만, 본 연구에서는 불포화도를 8.4 mol%까지 변화시킴으로써, 부틸고무 시스템에서 불포화도에 따른 가교 속도, 가교 밀도, 노화 및 가교 메커니즘에 대해 체계적으로 연구하였다. 본 연구는 부틸고무를 사용하는 블래더를 포함한 다양한 제품 생산의 품질 향상과 공정조건 최적화에 활용될 수 있다.

Curing reaction for butyl rubber complexes applicable to a tire bladder is investigated as a function of the degree of unsaturation (DU). High molecular weight butyl rubbers with various DU were synthesized by cationic polymerization, providing three butyl rubbers between 1.8 and 8.4 mol% of DU. Dynamic mechanical measurement and swelling test were conducted for the systematic study of curing rate, curing density, aging, and curing mechanism. Our findings shed new light on technologically important butyl rubber-based materials.

Keywords:butyl rubber;bladder;curing rate;unsaturation

[References]

Sloan JM, Butyl Rubber: Compound Development and Characterization, 2000.
Caron PA, Larreteguy AE, Porta PF, Lat. Am. Appl. Res., 47, 59 (2017)
Dorko ZJ, Edwards DC, Lumb PB, Rubber Chem. Technol., 35, 705 (1962)
Kim SM, Cho HW, Kim JW, Kim KJ, Elastomers. Compos., 45, 223 (2010)
Imanifar M, Movahed SO, Ahmadpour A, J. Appl. Polym. Sci., 135, 46213 (2018)
Hinchiranan N, Lertweerasirikun W, Poonsawad W, Rempel GL, Prasassarakich P, J. Appl. Polym. Sci., 111(6), 2813 (2009)
Khang TH, Ariff ZM, J. Therm. Anal. Calorim., 109, 1545 (2012)
Formela K, Haponiuk JT, Iran Polym. J., 23, 185 (2014)
Garratt S, Guerrero A, Hughes DL, Bochmann M, Angew. Chem.-Int. Edit., 43, 2166 (2004)
Guerrero A, Kulbaba K, Bochmann M, Macromol. Chem. Phys., 209, 1714 (2008)
Tse CKW, Penciu A, McInenly PJ, Kumar KR, Drewitt MJ, Baird MC, Eur. Polym. J., 40, 2653 (2004)
McInenly PJ, Drewitt MJ, Baird MC, Macromol. Chem. Phys., 205, 1707 (2004)
Mark JE, Polymer Data Handbook, 2nd ed.; Oxford University Press: New York, USA, 1999.
Mkkvickova L, Lopour P, Pokorny S, Janca J, Angew. Makromol. Chem., 90, 217 (1980)
Ahmed K, Nizami SS, Raza NZ, Shirin K, Adv. Mater. Phys. Chem., 2, 90 (2012)
Ayala JA, Hess WM, Kistler FD, Joyce GA, Rubber Chem. Technol., 64, 19 (1991)
Mitra S, Chattopadhyay S, Bhowmick AK, Rubber Chem. Technol., 81, 842 (2008)
Mok KL, Eng AH, Mal. J. Chem., 20, 118 (2018)
Lund R, Willner L, Lindner P, Richtert D, Macromolecules, 42(7), 2686 (2009)
Kraus G, J. Appl. Polym. Sci., 7, 861 (1963)
Moon B, Lee J, Park S, Seok CS, Polymers, 10, 658 (2018)
Mitra S, Chattopadhyay S, Bhowmick AK, Rubber Chem. Technol., 81, 842 (2008)
Isayev AI, Deng JS, Rubber Chem. Technol., 61, 340 (1988)
Yeoh OH, Rubber Chem. Technol., 85, 482 (2012)
Su WF, Principles of Polymer Design and Synthesis, Springer: Heidelberg, Germany, 2013.
Fisher JD, Phenolic Resins: A Century of Progress, Springer: Heidelberg, Germany, 2010.
Tawney PO, Little JR, Viohl P, Rubber Chem. Technol., 33, 229 (1960)
Hopkins W, von Hellens CW, Curing of Butyl Rubber with a Phenolic Resin, European patent EP1016691A1, July 5, 2000.
Fei Z, Long C, Qingyan P, Shugao ZJ, Macromol. Sci. B, 51, 1208 (2012)
Zielinka AJ, Noordermeer JWM, Talma AG, Van Duin M, Rubber Chem. Technol., 84, 243 (2011)
Chaikumpollert O, Yamamoto Y, Suchiva K, Kawahara S, Polym. J., 44, 772 (2012)
Gonzalez L, Rodriguez A, Valentin JL, Marcos-Fernandez A, Posadas P, KGK Rubberpoint, 58, 638 (2005)
Krongauz VV, Thermochim. Acta, 503(1-2), 70 (2010)
Manaila E, Stelescu MD, Craciun G, Int. J. Mol. Sci., 19, 2862 (2018)
Krumova M, Lopez D, Benavente R, Mijangos C, Perena JM, Polymer, 41(26), 9265 (2000)
Rybinski P, Janowska G, J. Therm. Anal., 117, 377 (2014)
Kamal MR, Sourour S, Polym. Eng. Sci., 13, 59 (1973)
Ivan G, Bugaru E, Volintiru TA, Acta Polym., 39, 647 (1988)
Hu JH, Shan JY, Zhao JQ, Tong Z, Thermochim. Acta, 632, 56 (2016)
Dziemidkiewicz A, Maciejewska M, Pingot MJ, Therm. Anal. Calorim., 138, 4395 (2018)
Sathi SG, Jang JY, Jeong KU, Nah C, J. Appl. Polym. Sci., 133, 44092 (2016)
Sathi SG, Park C, Huh YI, Jeon J, Yun CH, Won J, Jeong KU, Nah C, Rubber Chem. Technol., 92, 110 (2019)

[1] Sloan JM, Butyl Rubber: Compound Development and Characterization, 2000.

[2] Caron PA, Larreteguy AE, Porta PF, Lat. Am. Appl. Res., 47, 59 (2017)

[3] Dorko ZJ, Edwards DC, Lumb PB, Rubber Chem. Technol., 35, 705 (1962)

[4] Kim SM, Cho HW, Kim JW, Kim KJ, Elastomers. Compos., 45, 223 (2010)

[5] Imanifar M, Movahed SO, Ahmadpour A, J. Appl. Polym. Sci., 135, 46213 (2018)

[6] Hinchiranan N, Lertweerasirikun W, Poonsawad W, Rempel GL, Prasassarakich P, J. Appl. Polym. Sci., 111(6), 2813 (2009)

[7] Khang TH, Ariff ZM, J. Therm. Anal. Calorim., 109, 1545 (2012)

[8] Formela K, Haponiuk JT, Iran Polym. J., 23, 185 (2014)

[9] Garratt S, Guerrero A, Hughes DL, Bochmann M, Angew. Chem.-Int. Edit., 43, 2166 (2004)

[10] Guerrero A, Kulbaba K, Bochmann M, Macromol. Chem. Phys., 209, 1714 (2008)

[11] Tse CKW, Penciu A, McInenly PJ, Kumar KR, Drewitt MJ, Baird MC, Eur. Polym. J., 40, 2653 (2004)

[12] McInenly PJ, Drewitt MJ, Baird MC, Macromol. Chem. Phys., 205, 1707 (2004)

[13] Mark JE, Polymer Data Handbook, 2nd ed.; Oxford University Press: New York, USA, 1999.

[14] Mkkvickova L, Lopour P, Pokorny S, Janca J, Angew. Makromol. Chem., 90, 217 (1980)

[15] Ahmed K, Nizami SS, Raza NZ, Shirin K, Adv. Mater. Phys. Chem., 2, 90 (2012)

[16] Ayala JA, Hess WM, Kistler FD, Joyce GA, Rubber Chem. Technol., 64, 19 (1991)

[17] Mitra S, Chattopadhyay S, Bhowmick AK, Rubber Chem. Technol., 81, 842 (2008)

[18] Mok KL, Eng AH, Mal. J. Chem., 20, 118 (2018)

[19] Lund R, Willner L, Lindner P, Richtert D, Macromolecules, 42(7), 2686 (2009)

[20] Kraus G, J. Appl. Polym. Sci., 7, 861 (1963)

[21] Moon B, Lee J, Park S, Seok CS, Polymers, 10, 658 (2018)

[22] Mitra S, Chattopadhyay S, Bhowmick AK, Rubber Chem. Technol., 81, 842 (2008)

[23] Isayev AI, Deng JS, Rubber Chem. Technol., 61, 340 (1988)

[24] Yeoh OH, Rubber Chem. Technol., 85, 482 (2012)

[25] Su WF, Principles of Polymer Design and Synthesis, Springer: Heidelberg, Germany, 2013.

[26] Fisher JD, Phenolic Resins: A Century of Progress, Springer: Heidelberg, Germany, 2010.

[27] Tawney PO, Little JR, Viohl P, Rubber Chem. Technol., 33, 229 (1960)

[28] Hopkins W, von Hellens CW, Curing of Butyl Rubber with a Phenolic Resin, European patent EP1016691A1, July 5, 2000.

[29] Fei Z, Long C, Qingyan P, Shugao ZJ, Macromol. Sci. B, 51, 1208 (2012)

[30] Zielinka AJ, Noordermeer JWM, Talma AG, Van Duin M, Rubber Chem. Technol., 84, 243 (2011)

[31] Chaikumpollert O, Yamamoto Y, Suchiva K, Kawahara S, Polym. J., 44, 772 (2012)

[32] Gonzalez L, Rodriguez A, Valentin JL, Marcos-Fernandez A, Posadas P, KGK Rubberpoint, 58, 638 (2005)

[33] Krongauz VV, Thermochim. Acta, 503(1-2), 70 (2010)

[34] Manaila E, Stelescu MD, Craciun G, Int. J. Mol. Sci., 19, 2862 (2018)

[35] Krumova M, Lopez D, Benavente R, Mijangos C, Perena JM, Polymer, 41(26), 9265 (2000)

[36] Rybinski P, Janowska G, J. Therm. Anal., 117, 377 (2014)

[37] Kamal MR, Sourour S, Polym. Eng. Sci., 13, 59 (1973)

[38] Ivan G, Bugaru E, Volintiru TA, Acta Polym., 39, 647 (1988)

[39] Hu JH, Shan JY, Zhao JQ, Tong Z, Thermochim. Acta, 632, 56 (2016)

[40] Dziemidkiewicz A, Maciejewska M, Pingot MJ, Therm. Anal. Calorim., 138, 4395 (2018)

[41] Sathi SG, Jang JY, Jeong KU, Nah C, J. Appl. Polym. Sci., 133, 44092 (2016)

[42] Sathi SG, Park C, Huh YI, Jeon J, Yun CH, Won J, Jeong KU, Nah C, Rubber Chem. Technol., 92, 110 (2019)