화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.100, 296-309, August, 2021
DOI10.1016/j.jiec.2021.05.009  Export Citation
Tribological performances of copper perrhenate/graphene nanocomposite as lubricating additive under various temperatures
Junhai Wang1, 2, †, Weipeng Zhuang1, Tingting Yan1, Wenfeng Liang1, Ting Li2, Lixiu Zhang2, and Xiaoyi Wei1
  • 1School of Mechanical Engineering, Shenyang Jianzhu University, Shenyang 110168, China
  • 2Research Center for Analytical and Inspection Technology, Shenyang Jianzhu University, Shenyang 110168, China
E-mail:
Herein, copper perrhenate (Cu(ReO4)2) was synthesized using a micro-emulsion method and adhered to graphene (Gr) using an ultrasonic process. Then, the as-prepared Cu(ReO4)2/Gr composite was added into the synthetic oil as a lubricant additive with the help of ionic liquid to achieve enhanced dispersion stability within the base oil. The tribological performances of the Cu(ReO4)2/Gr additive were investigated using four-ball tests and the ball-on-disk reciprocating configuration under various temperatures. The potential lubrication mechanisms of the Cu(ReO4)2/Gr additive were performed using a series of characterization methods including XRD, Raman, SEM-EDS, TEM, DSC/TG, and XPS. The results of four-ball tests at room temperature indicated that the Cu(ReO4)2/Gr additive could substantially improve the tribological performances of the base oil. The smallest coefficient of friction (COF) and wear scar diameter (WSD) values were 0.068 and 495 μm, respectively, when 0.05 wt% of Cu(ReO4)2/Gr was added. Additionally, the graphene accelerated friction-induced heat transfer, which led to decreased friction and wear. The results of reciprocating friction experiments at elevated temperatures revealed that the Cu(ReO4)2/Gr additive had excellent friction-reduction properties when the temperature was high. This could be attributed to the generation of a protective layer containing tribo-oxides from the alloy, some residual carbides and copper perrhenate induced by friction heat and stress. This protective layer was uniformly and stably covered on the worn surface, which could effectively alleviate direct contact between the rubbing pair.
Keywords:Copper perrhenate/graphene;Nanocomposite;Oil additive;Various temperatures;Tribological performances
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