화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.45, No.3, 380-389, May, 2021
DOI10.7317/pk.2021.45.3.380  Export Citation
바이오매스 기반의 반응형 가소제 합성 및 Poly(vinyl chloride)의 가공 특성에 대한 영향
Synthesis of Biomass-based Reactive Plasticizer and Its Effects on the Processing Properties of Poly(vinyl chloride)
김재구†, 허강무
  • 충남대학교 고분자공학과
Jae-Koo Kim†, and Kang Moo Huh
  • Department of Polymer Science and Engineering, Chungnam National University, 99, Daehak-ro, Yuseong-gu, Daejeon 34134, Korea
E-mail:
초록
바이오매스의 일종인 폐식물유는 대부분 주거 및 상업 부문에서 대량으로 생성되며, 재활용률이 낮은 자원이다. 폐식물유는 환경에 대한 관심이 고조되고 석유화학 자원의 고갈에 따라 재생가능한 자원으로서 지대한 관심을 받아오고 있다. 본 연구에서는 바이오매스 기반의 폐식물유를 재활용하여 고내열성 및 고강도 특성이 우수한 반응형 가소제(BmBP)를 기존의 7단계 에폭시화 반응 공정을 혁신적으로 단순화한 3단계 공정을 통해 합성하였다. 합성된 가소제는 대응하는 특수 가소제인 TINTM 및 DIDP와 가공성 측면에서 상대 비교를 하였다.
Waste vegetable cooking oil (WVCO), a type of biomass, is primarily produced in large quantities within the residential and commercial sectors and is a resource with low recycling rate. WVCO has been receiving much attention as a renewable resource due to rising environmental concerns and the depletion of petrochemical resources. In this study, reactive plasticizer (BmBP) recycled with biomass-based WVCO was synthesized via a three-step process that was innovatively simplified from the conventional seven-step epoxidation process, which has high heat resistance and high strength. The synthesized BmBP was compared with corresponding specialty plasticizers, such as TINTM and DIDP, in terms of processability.
Keywords:biomass;reactive plasticizer;poly(vinyl chloride);thermal property;mechanical properties
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