화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.38, No.4, 872-884, April, 2021
DOI10.1007/s11814-021-0744-1  Export Citation
A novel synthesis of ditrimethylolpropane biphosphoramide diethyleneamine as flame retardant and antistatic textiles
Wei Jiang, Jin-Feng Li, Zi-Yuan Li, Xiao-Yan Zhang1, Fan-Long Jin†, and Soo-Jin Park2, †
  • Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, P. R. China
  • 1Refinery of Jilin Petrochemical Company, Jilin City 132022, P. R. China
  • 2Department of Chemistry, Inha University, Incheon 22212, Korea
E-mail:,
A novel phosphorous- and nitrogen-containing flame retardant, ditrimethylolpropane biphosphoramide diethyleneamine (DBD), was synthesized. Its chemical structure is characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. The effect of DBD on the physical, mechanical, and antistatic properties, thermal stability, and flame retardancy of wool fabric was systematically investigated. Thermogravimetric analysis showed that the initial decomposition temperature of DBD was 165 oC and 243 oC under nitrogen and air atmosphere, respectively. Furthermore, after 30 washes, the treated wool fabric exhibited excellent wash durability and good antistatic properties. Vertical burning tests indicated that both the burning time and char length of the treated wool fabric were lower than those of the flame-retardant standard, leading to a B1 flame retardant rating for the treated wool fabric. Compared to untreated wool fabric, the limiting oxygen index value of treated wool fabric increased significantly from 25.7% to 34.7%.
Keywords:Flame Retardant;Wool Fabric;Thermal Stability;Antistatic Property;Limiting Oxygen Index
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