화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.87, 234-241, July, 2020
DOI10.1016/j.jiec.2020.04.006  Export Citation
Low-pressure oligomerization of 1-butene to liquid fuels on HZSM-5 zeolite catalysts: Effect of operating conditions
Marta Díaz, Eva Epelde†, Andrés T. Aguayo, and Javier Bilbao
  • Department of Chemical Engineering, University of the Basque Country (UPV/EHU), P. O. Box 644, 48080 Bilbao, Spain
E-mail:
The capacity of HZSM-5 zeolite (SiO2/Al2O3 ratio = 30-280) based catalysts with a hierarchical porous structure has been explored for the oligomerization of 1-butene at low pressure. Catalysts were characterized (structural, physical and acid properties) and tested in a fixed bed reactor under the following conditions: 1.5 bar; 175.325 °C ; space time, 0.5-10 gcatalyst h (molC)-1; butene partial pressure, 0.375-1.5 bar; time on stream, 10 h. Results were evaluated with the aim of boosting naphtha (C5-C12 =) fraction. A good compromise between conversion (62% in C units contained) and naphtha yield (42%) was achieved by using a HZSM-5 zeolite with SiO2/Al2O3 = 30 at 275 °C and 6 gcatalyst h (molC)-1, where 23% corresponds to C8-C12 = and 19% to C5-C7 =, respectively. Furthermore, the hierarchical porous structure facilitated catalysts to tend to a pseudo-stationary deactivation state after 2-3 h time on stream, which could be interesting for process scale up.
Keywords:Oligomerization;1-Butene;HZSM-5 zeolite;Liquid fuels;Catalyst stability
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