화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.87, 102-109, July, 2020
DOI10.1016/j.jiec.2020.03.019  Export Citation
Cu-impregnated metal.organic frameworks for separation and recovery of CO from blast furnace gas
Tae-Ung Yoon1, Min June Kim2, Ah-Reum Kim1, Jo Hong Kang1, 3, Doseong Ji1, and Youn-Sang Bae1, 2, †
  • 1Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea
  • 2Graduate School of Integrated Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea
  • 3Green Materials & Processes R&D Group, Korea Institute of Industrial Technology, 55 Jongga-ro, Jung-gu, Ulsan 44413, Republic of Korea
E-mail:
The separation and recovery of carbon monoxide (CO) from blast furnace gas (BFG) mixtures is an important issue, as CO is a key substance in the petrochemical industry. We developed a series of Cu(I)- impregnated MIL-100(Fe) (Cu(x)@MIL-100(Fe)) with varied Cu loadings through a facile Cu(I)-loading method that does not require high-temperature thermal treatment. Among these, we found that Cu(0.5) @MIL-100(Fe) is the optimal material, with a high CO/CO2 selectivity (15.4) and large working capacity (0.38 mmol/g). This material showed very high CO/CO2, CO/N2, and CO/H2 selectivities (33.3, 106.4, and 98.4, respectively) for gas mixtures with a typical BFG composition, excellent CO separation from a simulated BFG mixture (CO/CO2/N2/H2 = 22:20:55:3 vol.%) under dynamic flow conditions, and reasonable air stability. These results show that Cu(0.5)@MIL-100(Fe) is an efficient adsorbent for the recovery of CO from BFG.
Keywords:Metal.organic frameworks (MOFs);Gas separation;Carbon monoxide;Carbon dioxide;Blast furnace gas (BFG)
  1. Cuervo-Pinera V, Cifrian-Riesgo D, Nguyen PD, Battaglia V, Fantuzzi M, Della Rocca A, Ageno M, Rensgard A, Wang C, Niska J, Energy Procedia, 120, 357 (2017)
  2. Suzuki K, Hayashi K, Kuribara K, Nakagaki T, Kasahara S, ISIJ Int., 55, 340 (2015)
  3. Moon DK, Park Y, Kim SH, Oh M, Lee CH, Sep. Purif. Technol., 181, 95 (2017)
  4. Yao X, Yu Q, Xu G, Han Z, Qin Q, Korean J. Chem. Eng., 36(5), 722 (2019)
  5. Lee JK, Lee IB, Han JH, J. Ind. Eng. Chem., 75, 77 (2019)
  6. Xie Y, Zhang J, Qiu J, Tong X, Fu J, Yang G, Yan H, Tang Y, Absorption, 3, 27 (1997)
  7. Saha D, Deng SG, J. Chem. Eng. Data, 54(8), 2245 (2009)
  8. Sethia G, Somani RS, Bajaj HC, RSC Adv., 5, 12773 (2015)
  9. Yeom C, Kim Y, Korean J. Chem. Eng., 35, 587 (2018)
  10. Park JH, Noh H, Chang TS, Shin CH, Korean J. Chem. Eng., 35(3), 645 (2018)
  11. Vo TK, Kim JH, Kwon HT, Kim J, J. Ind. Eng. Chem. (2019).
  12. Rahimpour MR, Baktash MS, Vaferi B, Mazinani S, J. Ind. Eng. Chem., 17(2), 198 (2011)
  13. Kim AR, Yoon TU, Kim SI, Cho K, Han SS, Bae YS, Chem. Eng. J., 348, 135 (2018)
  14. Yang RT, Adsorbents: Fundamentals and Applications, John Wiley & Sons Inc., Hoboken, 2003.
  15. Khan NA, Jhung SH, J. Hazard. Mater., 325, 198 (2017)
  16. Youchang X, Jiaping Z, Jianguo Q, Adsorption, 3, 37 (1996)
  17. Huang Y, Tao Y, He L, Duan Y, Xiao J, Li Z, Adsorption, 21, 373 (2015)
  18. Ma JH, Li L, Ren J, Li RF, Sep. Purif. Technol., 76(1), 89 (2010)
  19. Tamon H, Kitamura K, Okazaki M, AIChE J., 42(2), 422 (1996)
  20. Rowsell JL, Yaghi OM, Microporous Mesoporous Mater., 73, 3 (2004)
  21. Ferey G, Chem. Soc. Rev., 37, 191 (2008)
  22. Kitagawa S, Kitaura R, Noro S, Angew. Chem.-Int. Edit., 43, 2334 (2004)
  23. Dinca M, Long JR, Angew. Chem.-Int. Edit., 47, 6766 (2008)
  24. Khan NA, Jhung SH, J. Hazard. Mater., 237, 180 (2012)
  25. Horcajada P, Surble S, Serre C, Hong DY, Seo YK, Chang JS, Greneche JM, Margiolaki I, Ferey G, Chem. Commun., 2820 (2007).
  26. Kim AR, Yoon TU, Kim EJ, Yoon JW, Kim SY, Yoon JW, Hwang YK, Chan JS, Bae YS, Chem. Eng. J., 331, 777 (2018)
  27. Wiersum AD, Giovannangeli C, Vincent D, Bloch E, Reinsch H, Stock N, Lee JS, Chang JS, Llewellyn PL, ACS Comb. Sci., 15, 111 (2013)
  28. Llewellyn P, Reinoso FR, Rouqerol J, Seaton N, Proceedings of the 7th International Symposium on the Characterization of Porous Solids (COPS-VII), Aix-en-Provence, France, 26-28 May 2005, Elsevier, 2006.
  29. Bae YS, Yazaydin AO, Snurr RQ, Langmuir, 26(8), 5475 (2010)
  30. Lee SJ, Yoon TU, Kim AR, Kim SY, Cho KH, Hwang YK, Yeon JW, Bae YS, J. Hazard. Mater., 320, 513 (2016)
  31. Lee SJ, Kim KC, Yoon TU, Kim MB, Bae YB, Microporous Mesoporous Mater., 236, 284 (2016)
  32. Yoon JW, Yoon TU, Kim EJ, Kim AR, Jung TS, Han SS, Bae YS, J. Hazard. Mater., 341, 321 (2018)
  33. Kim MB, Kim KM, Kim TH, Yoon TU, Kim EJ, Kim JH, Bae YS, Chem. Eng. J., 339, 223 (2018)
  34. Jee JG, Kim MB, Lee CH, Chem. Eng. Sci., 60(3), 869 (2005)
  35. He Y, Krishna R, Chen B, Energy Environ. Sci., 5, 9107 (2012)
  36. Furukawa H, Gandara F, Zhang YB, Jiang JC, Queen WL, Hudson MR, Yaghi OM, J. Am. Chem. Soc., 136(11), 4369 (2014)
  37. Yoon JW, Seo YK, Hwang YK, Chang JS, Leclerc H, Wuttke S, Bazin P, Vimont A, Daturi M, Bloch E, Angew. Chem.-Int. Edit., 49, 5949 (2010)
  38. Myers A, Prausnitz JM, AlChE J., 11, 121 (1965)
  39. Bae YS, Mulfort KL, Frost H, Ryan P, Punnathanam S, Broadbelt LJ, Hupp JT, Snurr RQ, Langmuir, 24(16), 8592 (2008)
  40. Goj A, Sholl DS, Akten ED, Kohen D, J. Phys. Chem. B, 106(33), 8367 (2002)
  41. Bae YS, Snurr RQ, Angew. Chem.-Int. Edit., 50, 11586 (2011)
  42. Gao F, Wang YQ, Wang SH, Chem. Eng. J., 290, 418 (2016)
  43. Ma JH, Li L, Ren J, Li RF, Sep. Purif. Technol., 76(1), 89 (2010)
  44. Xie YC, Zhang JP, Qiu JG, Tong XZ, Fu JP, Yang G, Yan HJ, Tang YQ, Adsorption, 3, 27 (1996)
  45. Yoon JW, Yoon TU, Kim EJ, Kim AR, Jung TS, Han SS, Bae YS, J. Hazard. Mater., 341, 321 (2018)