화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.84, 1-22, April, 2020
DOI10.1016/j.jiec.2019.12.020  Export Citation
State-of-the-art modification of polymeric membranes by PEO and PEG for carbon dioxide separation: A review of the current status and future perspectives
Ali Kargari†, and Sheida Rezaeinia
  • Membrane Processes Research Laboratory (MPRL), Department of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Iran
E-mail:
In this paper, the methods for modification of polymeric membranes with Poly (ethylene oxide) (PEO) and Poly (ethylene glycol) (PEG) for CO2 separation is reviewed. PEO-containing membranes considered due to their proper CO2 separation performances and simplicity in fabrication. However, high crystallization tendency and mechanical strength of these PEG-based membranes have limited their applications on commercial scale. Hence, various methods have been proposed to overcome these shortcomings and improve the performance of the membranes, such as blending with other polymers or the formation of new chemical structures by copolymerization and crosslinking. In this paper, the state-of-the-art for the polymeric membranes containing PEO or PEG for CO2 separation is investigated and the separation performance of each category is evaluated and finally, future research directions and recommendations in this field are proposed. According to the present study, in general, although the mixed matrix membranes have shown excellent performances for carbon dioxide separations, the ionic liquid containing membranes also have offered high permeability and selectivity than the other types of membranes, and it seems that the MMMs containing ILs would be promising for future generation membranes.
Keywords:Carbon dioxide;Polymeric membrane;Poly(ethylene glycol);Poly(ethylene oxide);Permeability;Selectivity
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