Fabrication of branched-TiO2 microrods on the FTO glass for photocatalytic reduction of Cr(VI) under visible-light irradiation

Woocheol Kim; Jae Yeong Park; Younghun Kim

Journal of Industrial and Engineering Chemistry, Vol.73, 248-253, May, 2019

DOI10.1016/j.jiec.2019.01.032 Export Citation

Fabrication of branched-TiO2 microrods on the FTO glass for photocatalytic reduction of Cr(VI) under visible-light irradiation

Woocheol Kim, Jae Yeong Park¹, and Younghun Kim^†

Department of Chemical Engineering, Kwangwoon University, 20 Kwangwoon-ro, Nowon-gu, Seoul 01897, Republic of Korea
¹Department of Electronic Engineering, Kwangwoon University, 20 Kwangwoon-ro, Nowon-gu, Seoul 01897, Republic of Korea

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It is important to prepare a visible-light responsive photocatalyts, which has enhanced absorbance in the range of visible-light. In addition, metal nanoparticles deposited on TiO2 induced the localized surface plasmon resonance (LSPR) effect of Au nanoparticles (AuNPs), and thus enhanced the photocatalytic activity. Herein, TiO2 microrods with nano-branch (B-TiO2) on the fluorine-doped tin oxide glass (FTO) was prepared by hydrothermal method, and AuNPs was deposited on the B-TiO2. Its photocatalytic activity was evaluated by reduction of toxic Cr(VI) to less-toxic Cr(III) under visible-light irradiation. AuNPs/B-TiO2/FTO was successfully photocatalytic reduced target ions and Cr(III) ions were also removed from aqueous phase.

Keywords:Photocatalyst;TiO2;FTO glass;Visible-light-driven;Reduction of Cr(VI)

[References]

Lv T, Pan L, Liu X, Lu T, Zhu G, Sun Z, Sun CQ, Catal. Sci. Technol., 2, 754 (2012)
Zhu JF, Zheng W, Bin HE, Zhang JL, Anpo M, J. Mol. Catal. A-Chem., 216(1), 35 (2004)
Ebraheem S, El-Saied A, Mater. Sci. Appl., 4, 324 (2013)
Ettrup K, Kounina A, Hansen SF, Meesters JAJ, Vea EV, Laurent A, Environ. Sci. Technol., 51, 4027 (2017)
Hong F, Wang Y, Zhou Y, Zhang Q, Ge Y, Chen M, Hong J, Wang L, J. Agric. Food Chem., 64, 346 (2015)
Tong T, Wilke CM, Wu J, Binh CTT, Kelly JJ, Gaillard JF, Gray KA, Environ. Sci. Technol., 49, 8113 (2015)
Li F, Liang Z, Zheng X, Zhao W, Wu M, Wang Z, Aquat. Toxicol., 158, 1 (2015)
Trouiller B, Reliene R, Westbrook A, Solaimani P, Schiestl RH, R. Cancer Res., 15, 0008 (2009)
Ann LC, Mahmud S, Seeni A, Bakhori SKM, Sirelkhatim A, Mohamad D, Hasan H, J. Environ. Chem. Eng., 3, 436 (2015)
Blinova I, vask A, Heinlaan M, Mortimer M, Kahru A, Environ. Pollut., 158, 41 (2010)
Katsumiti A, Gilliland D, Arostegui I, Cajaraville MP, Aquat. Toxicol., 153, 39 (2014)
Liu B, Aydil ES, J. Am. Chem. Soc., 131(11), 3985 (2009)
Ullah K, Meng ZD, Ye S, Zhu L, Oh WC, J. Ind. Eng. Chem., 20(3), 1035 (2014)
Aazam ES, J. Ind. Eng. Chem., 20(6), 4033 (2014)
Vignesh K, Priyanka R, Hariharan R, Rajarajan M, Suganthi A, J. Ind. Eng. Chem., 20(2), 435 (2014)
Yu S, Kim YH, Lee SY, Song HD, Yi J, Angew. Chem.-Int. Edit., 53, 11203 (2014)
Clavero C, Nat. Photonics, 8, 95 (2014)
Li T, Albee B, Alemayehu M, Diaz R, Inham L, Kamal S, Rodriguez M, Bishnoi SW, Anal. Bioanal. Chem., 398, 689 (2010)
Boisselier E, Astruc D, Chem. Soc. Rev., 38, 1759 (2009)
Yu J, Zhuang S, Xu X, Zhu W, Feng B, Hu J, J. Mater. Chem. A, 3, 1199 (2015)
Cho IS, Chen Z, Forman AJ, Kim DR, Rao PM, Jaramillo TF, Zheng X, Nano Lett., 11, 4978 (2011)
Wang H, Bai Y, Wu Q, Zhou W, Zhang H, Li J, Guo L, Phys. Chem. Chem. Phys., 13, 7008 (2011)
Zhu CL, Zhang ML, Qiao YJ, Xiao G, Zhang F, Chen YJ, J. Phys. Chem. C, 114, 16229 (2010)
He Q, Zhang Z, Xiaong J, Xiong Y, Xiao H, Opt. Mater., 31, 380 (2008)
Liu J, Xu J, Che R, Chen H, Liu M, Liu Z, J. Chem. Eur., 19, 6746 (2013)
Oh S, Kang T, Kim H, Moon J, Hong S, Yi J, J. Membr. Sci., 301(1-2), 118 (2007)
Lee H, Jeong U, Kim Y, Joo JB, Top Catal., 60, 763 (2017)
Karakouz T, Maoz BM, Lando G, Vaskevich A, Rubinstein I, ACS Appl. Mater. Interfaces, 3, 978 (2011)
Lu B, Ma N, Wang Y, Qju Y, Hu H, Zhao J, Liang D, Xu S, Li X, Zhu Z, Cui C, J. Alloy. Compd., 630, 163 (2015)
Zhu Z, Yu Y, Huang H, Yao X, Dong H, Liu Z, Yan Y, Li C, Huo P, Catal. Sci. Technol., 7, 4092 (2017)
Park S, Selvaraj R, Meetani MA, Kim Y, J. Ind. Eng. Chem., 45, 206 (2017)
Silva CG, Cla’udia J, Raquel M, Tiziana M, Molinari R, Garcia H, J. Am. Ceram. Soc., 133, 595 (2010)
Wang K, Wu X, Zhang G, Li J, Li Y, ACS Sustain. Chem. Eng., 6, 6682 (2018)
Guo S, Zhang G, Yu JC, J. Colloid Interface Sci., 448, 460 (2015)
Deng S, Bai R, Water Res., 38, 2424 (2004)
Bellu S, Sala L, Gonzalez J, Garcia S, Frascaroli M, Blanes P, Garcia J, Peregrin JS, Atria A, Ferron J, Harada M, Cong C, Niwa Y, J. Water Res. Prot., 2, 888 (2010)

[1] Lv T, Pan L, Liu X, Lu T, Zhu G, Sun Z, Sun CQ, Catal. Sci. Technol., 2, 754 (2012)

[2] Zhu JF, Zheng W, Bin HE, Zhang JL, Anpo M, J. Mol. Catal. A-Chem., 216(1), 35 (2004)

[3] Ebraheem S, El-Saied A, Mater. Sci. Appl., 4, 324 (2013)

[4] Ettrup K, Kounina A, Hansen SF, Meesters JAJ, Vea EV, Laurent A, Environ. Sci. Technol., 51, 4027 (2017)

[5] Hong F, Wang Y, Zhou Y, Zhang Q, Ge Y, Chen M, Hong J, Wang L, J. Agric. Food Chem., 64, 346 (2015)

[6] Tong T, Wilke CM, Wu J, Binh CTT, Kelly JJ, Gaillard JF, Gray KA, Environ. Sci. Technol., 49, 8113 (2015)

[7] Li F, Liang Z, Zheng X, Zhao W, Wu M, Wang Z, Aquat. Toxicol., 158, 1 (2015)

[8] Trouiller B, Reliene R, Westbrook A, Solaimani P, Schiestl RH, R. Cancer Res., 15, 0008 (2009)

[9] Ann LC, Mahmud S, Seeni A, Bakhori SKM, Sirelkhatim A, Mohamad D, Hasan H, J. Environ. Chem. Eng., 3, 436 (2015)

[10] Blinova I, vask A, Heinlaan M, Mortimer M, Kahru A, Environ. Pollut., 158, 41 (2010)

[11] Katsumiti A, Gilliland D, Arostegui I, Cajaraville MP, Aquat. Toxicol., 153, 39 (2014)

[12] Liu B, Aydil ES, J. Am. Chem. Soc., 131(11), 3985 (2009)

[13] Ullah K, Meng ZD, Ye S, Zhu L, Oh WC, J. Ind. Eng. Chem., 20(3), 1035 (2014)

[14] Aazam ES, J. Ind. Eng. Chem., 20(6), 4033 (2014)

[15] Vignesh K, Priyanka R, Hariharan R, Rajarajan M, Suganthi A, J. Ind. Eng. Chem., 20(2), 435 (2014)

[16] Yu S, Kim YH, Lee SY, Song HD, Yi J, Angew. Chem.-Int. Edit., 53, 11203 (2014)

[17] Clavero C, Nat. Photonics, 8, 95 (2014)

[18] Li T, Albee B, Alemayehu M, Diaz R, Inham L, Kamal S, Rodriguez M, Bishnoi SW, Anal. Bioanal. Chem., 398, 689 (2010)

[19] Boisselier E, Astruc D, Chem. Soc. Rev., 38, 1759 (2009)

[20] Yu J, Zhuang S, Xu X, Zhu W, Feng B, Hu J, J. Mater. Chem. A, 3, 1199 (2015)

[21] Cho IS, Chen Z, Forman AJ, Kim DR, Rao PM, Jaramillo TF, Zheng X, Nano Lett., 11, 4978 (2011)

[22] Wang H, Bai Y, Wu Q, Zhou W, Zhang H, Li J, Guo L, Phys. Chem. Chem. Phys., 13, 7008 (2011)

[23] Zhu CL, Zhang ML, Qiao YJ, Xiao G, Zhang F, Chen YJ, J. Phys. Chem. C, 114, 16229 (2010)

[24] He Q, Zhang Z, Xiaong J, Xiong Y, Xiao H, Opt. Mater., 31, 380 (2008)

[25] Liu J, Xu J, Che R, Chen H, Liu M, Liu Z, J. Chem. Eur., 19, 6746 (2013)

[26] Oh S, Kang T, Kim H, Moon J, Hong S, Yi J, J. Membr. Sci., 301(1-2), 118 (2007)

[27] Lee H, Jeong U, Kim Y, Joo JB, Top Catal., 60, 763 (2017)

[28] Karakouz T, Maoz BM, Lando G, Vaskevich A, Rubinstein I, ACS Appl. Mater. Interfaces, 3, 978 (2011)

[29] Lu B, Ma N, Wang Y, Qju Y, Hu H, Zhao J, Liang D, Xu S, Li X, Zhu Z, Cui C, J. Alloy. Compd., 630, 163 (2015)

[30] Zhu Z, Yu Y, Huang H, Yao X, Dong H, Liu Z, Yan Y, Li C, Huo P, Catal. Sci. Technol., 7, 4092 (2017)

[31] Park S, Selvaraj R, Meetani MA, Kim Y, J. Ind. Eng. Chem., 45, 206 (2017)

[32] Silva CG, Cla’udia J, Raquel M, Tiziana M, Molinari R, Garcia H, J. Am. Ceram. Soc., 133, 595 (2010)

[33] Wang K, Wu X, Zhang G, Li J, Li Y, ACS Sustain. Chem. Eng., 6, 6682 (2018)

[34] Guo S, Zhang G, Yu JC, J. Colloid Interface Sci., 448, 460 (2015)

[35] Deng S, Bai R, Water Res., 38, 2424 (2004)

[36] Bellu S, Sala L, Gonzalez J, Garcia S, Frascaroli M, Blanes P, Garcia J, Peregrin JS, Atria A, Ferron J, Harada M, Cong C, Niwa Y, J. Water Res. Prot., 2, 888 (2010)