화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.20, No.2, 435-443, March, 2014
Fabrication of CdS and CuWO4 modified TiO2 nanoparticles and its photocatalytic activity under visible light irradiation
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CdS and CuWO4 modified TiO2 nanoparticles (CdS.CuWO4-TiO2) were prepared by the chemical impregnation method. The as-prepared nanoparticles were characterized using UV-visible-diffuse reflectance spectroscopy (UV-vis-DRS), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS) and B.E.T. surface area analysis techniques. The photocatalytic activity was evaluated based on the degradation of a dye (eosin-Y) and inactivation of a bacterium (Pseudomonas aeruginosa). The results revealed that CdS-CuWO4-TiO2 showed high photocatalytic activity over CdS-TiO2, CuWO4-TiO2 and TiO2. Moreover the reusability and stability of the photocatalyst for the degradation of eosin-Y was also studied.
  1. Pearce CI, Lloyd JR, Guthrie JTJ, Dyes Pigment., 58, 179 (2003)
  2. Talarposhti AM, Donnelly T, Anderson GK, Water Res., 35, 425 (2001)
  3. Borker P, Salker AV, Mater. Sci. Eng. B, 133, 55 (2006)
  4. Ghaedi M, Karimi F, Barazesh B, Sahraei R, Daneshfar A, J. Ind. Eng. Chem., 19(3), 756 (2013)
  5. Ghaedi M, Hajati S, Barazesh B, Karimi F, Ghezelbash G, J. Ind. Eng. Chem., 19, 223 (2013)
  6. Dos Santos AB, Cervantes FJ, Van Lier JB, Bioresour. Technol., 981, 2369 (2007)
  7. Palmisano G, Augugliaro V, Pagliaro M, Palmisano L, Chem. Commun., 33, 3425 (2007)
  8. Ravelli D, Dondi D, Fagnoni M, Albini A, Chem. Soc. Rev., 38, 1999 (2009)
  9. Liu Y, Xin F, Wang F, Luo S, Yin X, J. Alloy. Compd., 498, 179 (2010)
  10. Chae YK, Park JW, Mori S, Suzuki M, J. Ind, 18(4), 1237 (2012)
  11. Oh WC, Zhang FJ, Chen ML, J. Ind. Eng. Chem., 16(2), 299 (2010)
  12. Nguyen-Phan TD, Shin EW, J. Ind. Eng. Chem., 17(3), 397 (2011)
  13. Ghosh T, Cho KY, Ullah K, Nikam V, Park CY, Meng ZD, Oh WC, J. Ind. Eng. Chem., 19(3), 797 (2013)
  14. Zhang ZY, Shao CL, Zhang LN, Li XH, Liu YC, J. Colloid Interface Sci., 351(1), 57 (2010)
  15. Ding H, Sun H, Shan Y, J. Photochem. Photobiol. A-Chem., 169, 101 (2005)
  16. Subrahmanyam A, Biju KP, Rajesh P, Kumar KJ, Kiran MR, Sol. Energy Mater. Sol. Cells, 101, 241 (2012)
  17. Cheng XW, Yu XJ, Xing ZP, Appl. Surf. Sci., 258(7), 3244 (2012)
  18. Thind SS, Wu G, Chen A, Appl. Catal. B: Environ., 111-112, 38 (2012)
  19. Lu XF, Li J, Wang C, Duan MY, Luo Y, Yao GP, Wang JL, Appl. Sur, 257(3), 795 (2010)
  20. Zhao ZH, Fan JM, Liu SH, Wang ZZ, Chem. Eng. J., 151(1-3), 134 (2009)
  21. Vignesh K, Suganthi A, Rajarajan M, Sakthivadivel R, Appl. Surf. Sci., 258(10), 4592 (2012)
  22. Jafari S, Azizian S, Jaleh B, J. Ind. Eng. Chem., 18(6), 2124 (2012)
  23. Yamin Y, Keller N, Keller V, J. Photochem. Photobiol. A-Chem., 245, 43 (2012)
  24. Park H, Choi W, Hoffmann MR, J. Mater. Chem., 18, 2379 (2008)
  25. Di Paola A, Palmisano L, Augugliaro V, Catal. Today, 58(2-3), 141 (2000)
  26. Wang Y, Cai L, Li Y, Tang Y, Xie C, Physica E, 43, 503 (2010)
  27. Chen Y, Liu S, Zhang H, Xiu Z, Yu X, Wang E, Li T, Mater. Sci. Eng. B, 174, 187 (2010)
  28. Min YL, Zhang K, Chen YC, Zhang YG, Zhao W, Sep. Purif. Technol., 92, 115 (2012)
  29. Arora SK, Mathew T, Chudasama B, Kothari A, J. Cryst. Growth, 275, 651 (2005)
  30. Li CL, Yuan JA, Han BY, Shangguan WF, Int. J. Hydrog. Energy, 36(7), 4271 (2011)
  31. Liu MC, Jing DW, Zhao LA, Guo LJ, Int. J. Hydrog. Energy, 35(13), 7058 (2010)
  32. Bai SL, Li HY, Guan YJ, Jiang ST, Appl. Surf. Sci., 257(15), 6406 (2011)
  33. Chen S, Paulose M, Ruan C, Mor G, Varghese O, Kouzoudis D, Grimes C, J. Photochem. Photobiol. A-Chem., 177, 177 (2006)
  34. Tristao JC, Magalhaes F, Corio P, Sansiviero MTC, J. Photochem. Photobiol. A-Chem., 181, 152 (2006)
  35. Kim J, Choi J, Lee Y, Hong J, Lee J, Yang J, Lee W, Hur N, Chem. Commun., 48, 5024 (2006)
  36. Huang B, Yang Y, Chen X, Ye D, Catal. Commun., 11, 844 (2010)
  37. Meng Z, Zhu L, Choi J, Park C Y, Oh W, Ultrason. Sonochem., 19, 143 (2012)
  38. Zhao WX, Bai ZP, Ren AL, Guo B, Wu C, Appl. Surf. Sci., 256(11), 3493 (2010)
  39. Vignesh K, Suganthi A, Rajarajan M, Sara SA, Powder Technol., 224, 331 (2012)
  40. Subash B, Krishnakumar B, Pandiyan V, Swaminathan M, Shanthi M, Sep. Purif. Technol., 96, 204 (2012)
  41. Karunakaran C, Abiramasundari G, Gomathisankar P, Manikandan G, Anandi V, J. Colloid Interface Sci., 352(1), 68 (2010)
  42. Sathishkumar P, Sweena R, Wu JJ, Anandan S, Chem. Eng. J., 171(1), 136 (2011)
  43. Sajjad AKL, Shamaila S, Tian BZ, Chen F, Zhang JL, Appl. Catal. B: Environ., 91(1-2), 397 (2009)
  44. Ge L, Xu M, Mater. Sci. Eng. B, 131, 222 (2006)
  45. Maurya A, Chauhan P, Materials Characterization, 62, 382 (2011)
  46. Zhongliang S, Fumei L, Shuhua Y, J. Rare. Earths, 28, 737 (2010)
  47. Riaz N, Chong FK, Dutta BK, Man ZB, Khan MS, Nurlaela E, Chem. Eng. J., 185-186, 108 (2012)
  48. Sing KSW, Everett DH, Moscou L, Pierrotti R, Roquerol J, Siemeniewska T, Pure, 57, 603 (1985)
  49. Li CL, Yuan JA, Han BY, Jiang L, Shangguan WF, Int. J. Hydrog. Energy, 35(13), 7073 (2010)
  50. Wu L, Yu JC, Fu XZ, J. Mol. Catal. A-Chem., 244(1-2), 25 (2006)
  51. Song S, Hong FY, He ZQ, Cai QL, Chen JM, J. Colloid Interface Sci., 378, 159 (2012)
  52. Jiang LC, Zhang WD, Yu YX, Wang J, Electrochem. Commun., 13, 627 (2011)
  53. Yang GD, Yan ZF, Xiao TC, Appl. Surf. Sci., 258(22), 8704 (2012)
  54. Velmurugan R, Krishnakumar B, Subash B, Swaminathan M, Sol. Energy Mater. Sol. Cells, 108, 205 (2013)
  55. Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C, 31, 1062 (2011)
  56. Liu L, Liu Z, Bai H, Sun DD, Water Res., 46, 1101 (2012)
  57. Yousef A, Barakat NAM, Amna T, Al-Deyab SS, Hassan MS, Abdel-hay A, Kim HY, Ceram. Int., 38, 4525 (2012)
  58. Karunakaran C, Vijayabalan A, Manikandan G, Gomathisankar P, Catal. Commun., 12, 826 (2011)
  59. Prasad GK, Ramacharyulu PVRK, Merwyn S, Agarwal GS, Srivastava AR, Singh B, Rai GP, Vijayaraghavan R, J. Hazard. Mater., 185(2-3), 977 (2011)
  60. Pal B, Singh I, Angrish K, Aminedi R, Das N, Mater. Chem. Phys., 136(1), 21 (2012)