화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.72, 196-213, April, 2019
DOI10.1016/j.jiec.2018.12.019  Export Citation
Graphene oxide as a pH-sensitive carrier for targeted delivery of eco-friendly corrosion inhibitors in chloride solution: Experimental and theroretical investigations
Ali Asghar Javidparvar, Reza Naderi†, Bahram Ramezanzadeh1, †, and Ghasem Bahlakeh2
  • School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran, Iran
  • 1Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
  • 2Department of Chemical Engineering, Faculty of Engineering, Golestan University, Aliabad Katoul, Iran
E-mail:,
Graphene oxide (GO) was used as a smart pH-sensitive carrier for delivery of green corrosion inhibitors to the active corrosion sites of metal. Results demonstrated the physisorption and chemisorption of cerium onto the GO surface. The open circuit potential, polarization test and electrochemical impedance spectroscopy measurements as well as field-emission scanning electron microscopy and energy dispersive spectroscopy were used to study the corrosion inhibition power of GO-Ce system. Results revealed that as a result of cerium oxide/hydroxide film generation on the cathodic regions, the corrosion of mild steel was remarkably inhibited in the chloride solution.
Keywords:Smart pH-sensitive carrier;Graphene oxide;Adsorption;XPS;Nanocontainer
  1. Buchheit RG, Guan H, Mahajanam S, Wong F, Prog. Org. Coat., 47, 174 (2003)
  2. Bethencourt M, Botana FJ, Marcos M, Osuna RM, Sanchez-Amaya JM, Prog. Org. Coat., 46, 280 (2003)
  3. Ramezanzadeh M, Sanaei Z, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 256, 67 (2018)
  4. Parhizkar N, Shahrabi T, Ramezanzadeh B, J. Alloy. Compd., 747, 109 (2018)
  5. Javidparvar AA, Ramezanzadeh B, Ghasemi E, Corrosion, 72, 761 (2016)
  6. Ma NX, Liu J, He WX, Li ZH, Luan YX, Song YM, Garg S, J. Colloid Interface Sci., 490, 598 (2017)
  7. Ma N, Zhang B, Liu J, Zhang P, Li Z, Luan Y, Int. J. Pharm., 496, 984 (2015)
  8. Shi X, Nguyen TA, Suo Z, Liu Y, Avci R, Surf. Coat. Technol., 204, 237 (2009)
  9. Abdullayev E, Price R, Shchukin D, Lvov Y, ACS Appl. Mater. Interfaces, 1, 1437 (2009)
  10. Sepehrian H, Int. J. Nano Dimens., 5, 169 (2014)
  11. Wang N, Cheng K, Wu H, Wang C, Wang Q, Wang F, Prog. Org. Coat., 75, 386 (2012)
  12. Ishizaki T, Kamiyama N, Watanabe K, Serizawa A, Corrosion Sci., 92, 76 (2015)
  13. Zhu Y, Yao C, Ren J, Liu C, Ge L, Colloids Surf. A: Physicochem. Eng. Asp., 465, 26 (2015)
  14. Sonawane SH, Bhanvase BA, Jamali AA, Dubey SA, Kale SS, Pinjari DA, Kulkarni RD, Gogate PR, Pandit AB, Chem. Eng. J., 189-190, 464 (2012)
  15. Gu D, Fein JB, Colloids Surf. A: Physicochem. Eng. Asp., 481, 319 (2015)
  16. Ramezanzadeh M, Asghari M, Ramezanzadeh B, Bahlakeh G, Chem. Eng. J., 337, 385 (2018)
  17. Chowdhury S, Balasubramanian R, Adv. Colloid Interface Sci., 204, 35 (2014)
  18. Wang X, Liu B, Lu Q, Qu Q, J. Chromatogr. A, 1362, 1 (2014)
  19. Wang SB, Sun HQ, Ang HM, Tade MO, Chem. Eng. J., 226, 336 (2013)
  20. Ramezanzadeh B, Kardar P, Bahlakeh G, Hayatgheib Y, Mahdavian M, J. Phys. Chem. C, 121, 20433 (2017)
  21. Nikpour B, Ramezanzadeh B, Bahlakeh G, Mahdavian M, Corrosion Sci., 127, 240 (2017)
  22. Gupta RK, Malviya M, Verma C, Quraishi MA, Mater. Chem. Phys., 108, 360 (2017)
  23. Galal A, Amin KM, Atta NF, Abd El-Rehim HA, J. Alloy. Compd., 695, 638 (2017)
  24. Nikpour B, Ramezanzadeh B, Bahlakeh G, Mahdavian M, Corrosion Sci., 127, 240 (2017)
  25. Yasakau KA, Zheludkevich ML, Lamaka SV, Ferreira MGS, J. Phys. Chem. B, 110(11), 5515 (2006)
  26. Ramezanzadeh M, Sanaei Z, Ramezanzadeh B, J. Ind. Eng. Chem., 62, 427 (2018)
  27. Brunelli K, Dabala M, Calliari I, Magrini M, Corrosion Sci., 47, 989 (2005)
  28. Lakshmi RV, Yoganandan G, Kavya KT, Basu BJ, Prog. Org. Coat., 76, 367 (2013)
  29. Arenas MA, Conde A, de Damborenea JJ, Corrosion Sci., 44, 511 (2002)
  30. Fahrenholt WG, O’Keefe MJ, Zhou H, Grant JT, Surf. Coat. Technol., 155, 208 (2002)
  31. Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M, Corrosion Sci., 118, 69 (2017)
  32. Vakili H, Ramezanzadeh B, Amini R, Corrosion Sci., 94, 466 (2015)
  33. Mahidashti Z, Shahrabi T, Ramezanzadeh B, Prog. Org. Coat., 114, 19 (2018)
  34. Ramezanzadeh B, Bahlakeh G, Ramezanzadeh M, Corrosion Sci., 137, 111 (2018)
  35. Niroumandrad S, Rostami M, Ramezanzadeh B, Appl. Surf. Sci., 357, 2121 (2015)
  36. Hu T, Shi H, Fan S, Liu F, Han EH, Prog. Org. Coat., 105, 123 (2017)
  37. Lakshmi RV, Yoganandan G, Mohan AVN, Basu BJ, Surf. Coat. Technol., 240, 353 (2014)
  38. Carvalho JBR, Silva RS, Cesarino I, Machado SAS, Eguiluz KIB, Cavalcanti EB, Salazar-Banda GR, Ceram. Int., 40, 13437 (2014)
  39. Coelho LB, Cossement D, Olivier MG, Corrosion Sci., 130, 177 (2018)
  40. Zhu C, Yang HX, Wang YZ, Zhang DQ, Chen Y, Gao LX, Ionics, 1 (2018)
  41. Yu JG, Yu LY, Yang H, Liu Q, Chen XH, Jiang XY, Chen XQ, Jiao FP, Sci. Total Environ., 502, 70 (2015)
  42. Guo XY, Du B, Wei Q, Yang J, Hu LH, Yan LG, Xu WY, J. Hazard. Mater., 278, 211 (2014)
  43. Dong Z, Zhang F, Wang D, Liu X, Jin J, J. Solid State Chem., 224, 88 (2015)
  44. Ramezanzadeh B, Moghadam MHM, Shohani N, Mandavian M, Chem. Eng. J., 320, 363 (2017)
  45. Ramezanzadeh B, Niroumandrad S, Ahmadi A, Mahdavian M, Moghadam MHM, Corrosion Sci., 103, 283 (2016)
  46. Verma R, Samdarshi SK, J. Phys. Chem. C, 120, 22281 (2016)
  47. Bai G, Wang J, Yang Z, Wang H, Wang Z, Yang S, RSC Adv., 4, 47096 (2014)
  48. Avouris P, Dimitrakopoulos C, Mater. Today, 15, 86 (2012)
  49. Sahu SC, Samantara AK, Seth M, Parwaiz S, Singh BP, Rath PC, Jena BK, Electrochem. Commun., 32, 22 (2013)
  50. Yu H, Zhang B, Bulin C, Li R, Xing R, Sci. Rep., 6, 36143 (2016)
  51. Yang YF, Wang J, Zhang J, Liu JC, Yang XL, Zhao HY, Langmuir, 25(19), 11808 (2009)
  52. Jiang L, Yao M, Liu B, Li Q, Liu R, Lv H, Lu S, Gong C, Zou B, Cui T, Liu B, Hu G, Wagberg T, J. Phys. Chem. C, 116, 11741 (2012)
  53. Patterson A, Phys. Rev., 56, 978 (1939)
  54. Huang ZH, Zheng XY, Lv W, Wang M, Yang QH, Kang FY, Langmuir, 27(12), 7558 (2011)
  55. Nayak P, Santhosh PN, Ramaprabhu S, J. Nanosci. Nanotechnol., 15, 4855 (2015)
  56. Srivastava M, Das AK, Khanra P, Uddin ME, Kim NH, Lee JH, J. Mater. Chem. A, 1, 9792 (2013)
  57. Ji X, Xu Y, Zhang W, Cui L, Liu J, Compos. Pt. A-Appl. Sci. Manuf., 87, 29 (2016)
  58. Li J, Zeng X, Ren T, van der Heide E, Lubricants, 2, 137 (2014)
  59. Sheshmani S, Nematzadeh MA, Shokrollahzadeh S, Ashori A, Int. J. Biol. Macromol., 80, 475 (2015)
  60. Li XJ, Yan CJ, Luo WJ, Gao Q, Zhou Q, Liu C, Zhou S, Chem. Eng. J., 284, 333 (2016)
  61. Lahiji MN, Keshtkar AR, Moosavian MA, Part. Sci. Technol., 1 (2016)
  62. Awual MR, Yaita T, Shiwaku H, Chem. Eng. J., 228, 327 (2013)
  63. Torab-Mostaedi M, Asadollahzadeh M, Hemmati A, Khosravi A, Res. Chem. Intermed., 41, 559 (2015)
  64. Vijayaraghavan K, Sathishkumar M, Balasubramanian R, Ind. Eng. Chem. Res., 49(9), 4405 (2010)
  65. Vijayaraghavan K, Balasubramanian R, Chem. Eng. J., 163(3), 337 (2010)
  66. Kutahyah C, Sert S, Cetinkaya B, Yalcintas E, Acar MB, Wood Sci. Technol., 46, 721 (2012)
  67. Sert S, Kutahyali C, Inan S, Talip Z, Cetinkaya B, Eral M, Hydrometallurgy, 90, 13 (2008)
  68. Zare-Dorabei R, Jalalat V, Tadjarodi A, New J. Chem., 40, 5128 (2016)
  69. Kutahyali C, Sert S, Cetinkaya B, Inan S, Eral M, Sep. Sci. Technol., 45(10), 1456 (2010)
  70. Liu L, Li C, Bao C, Jia Q, Xiao P, Liu X, Zhang Q, Talanta, 93, 350 (2012)
  71. Yang S, Li L, Pei Z, Li C, Lv J, Xie J, Wen B, Zhang S, Colloids Surf. A: Physicochem. Eng. Asp., 457, 100 (2014)
  72. Wang C, Feng C, Gao YJ, Ma XX, Wu QH, Wang Z, Chem. Eng. J., 173(1), 92 (2011)
  73. Hu LH, Yang ZP, Cui LM, Li Y, Ngo HH, Wang YG, Wei Q, Ma HM, Yan LG, Du B, Chem. Eng. J., 287, 545 (2016)
  74. Christmann K, Institut fur Chemie und Biochemie, Freie Universitat Berlin, 2012.
  75. Wang H, Yuan X, Wu Y, Huang H, Zeng G, Liu Y, Wang X, Lin N, Qi Y, Appl. Surf. Sci., 279, 432 (2013)
  76. Larabi L, Harek Y, Benali O, Ghalem S, Prog. Org. Coat., 54, 256 (2005)