Mechanistic insights into nature of complexation between aluminum and phosphates in polyaluminum chloride treated sludge for sustainable phosphorus recovery

Umair Ali Toor; Hyuna Shin; Dong-Jin Kim

Journal of Industrial and Engineering Chemistry, Vol.71, 425-434, March, 2019

DOI10.1016/j.jiec.2018.11.055 Export Citation

Mechanistic insights into nature of complexation between aluminum and phosphates in polyaluminum chloride treated sludge for sustainable phosphorus recovery

Umair Ali Toor, Hyuna Shin, and Dong-Jin Kim^†

Department of Environmental Sciences and Biotechnology & Institute of Energy and Environment, Hallym University, Chuncheon, Gangwon 24252, Republic of Korea

E-mail:

Efficiency of phosphorus recovery from polyaluminum chloride sludge is determined by chemical interactions between Al and P. Chemical structure of Al.P complex and their binding mechanisms in the PAC sludge were investigated with spectroscopy and chemical fractionation. More than 98% of the P was bound with Al, out of which 70% was strongly bound. The ATR-FTIR analysis indicates that the majority of the P formed inner sphere complex with Al through ligand exchange. The availability of highly protonated surface for P sorption at low pH also supports the formation of Al-P outer sphere complex.

Keywords:Al-P complex;Polyaluminum chloride sludge;Inner and outer sphere complex;Phosphorus fractionation;Phosphorus recovery

[References]

Petzet S, Peplinski B, Bodkhe S, Cornel P, Water Sci. Technol., 64, 693 (2011)
Jeon S, Kim DJ, J. Ind. Eng. Chem., 58, 216 (2017)
Chen M, Graedel T, Global Environ. Change, 36, 139 (2016)
Cooper J, Lombardi R, Boardman D, Carliell-Marquet C, Resour. Conserv. Recycl., 57, 78 (2011)
Senthilkumar K, Mollier A, Delmas M, Pellerin S, Nesme T, Resour. Conserv. Recycl., 87, 97 (2014)
Lacasa E, Canizares P, Saez C, Fernandez FJ, Rodrigo MA, Chem. Eng. J., 172(1), 137 (2011)
Lim BH, Kim DJ, J. Ind. Eng. Chem., 46, 62 (2017)
Richardson CJ, King RS, Qian SS, Vaithiyanathan P, Qualls RG, Stow CA, Water Sci. Technol., 41, 8084 (2007)
Guaya D, Valderrama C, Farran A, Armijos C, Cortina JL, Chem. Eng. J., 271, 204 (2015)
Leopold P, Freese SD, Water Research Commission Report, (2009).
Ali TU, Kim DJ, Bioresour. Technol., 217, 233 (2016)
Jing C, Zhaokun L, Fresenius Environ. Bull., 9, 2200 (2010)
Hafsteinsdottir EG, Camenzuli D, Rocavert AL, Walworth J, Gore DB, Appl. Geochem., 59, 47 (2015)
Gustafsson JP, Mwamila LM, Kergoat K, Geoderma, 189, 304 (2012)
Kim GJ, Kim HJ, Moon HS, Chon CM, Ahn JS, Chem. Spec. Bioavailab., 14, 67 (2002)
Gregory J, Dupont V, Water Sci. Technol., 44, 231 (2001)
Wu X, Ge X, Wang D, Tang H, Colloids Surf. A: Physicochem. Eng. Asp., 305, 89 (2007)
Tejedor-Tejedor MI, Anderson MA, Langmuir, 6, 602 (1990)
Luengo C, Brigante M, Antelo J, Avena M, J. Colloid Interface Sci., 300(2), 511 (2006)
Elzinga EJ, Sparks DL, J. Colloid Interface Sci., 308(1), 53 (2007)
Kaiserli A, Voutsa D, Samara C, Chemosphere, 46, 1147 (2002)
Huang XL, Chen Y, Shenker M, J. Environ. Qual., 37, 1949 (2008)
Zheng TT, Sun ZX, Yang XF, Holmgren A, Chem. Cent. J., 6, 1 (2012)
Arai Y, Sparks DL, J. Colloid Interface Sci., 241(2), 317 (2001)
Del Nero M, Galindo C, Barillon R, Halter E, Made B, J. Colloid Interface Sci., 342(2), 437 (2010)
Luengo CV, Castellani NJ, Ferullo RM, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 14, 193 (2015)
Xie J, Wang Z, Lu SY, Wu DY, Zhang ZJ, Kong HN, Chem. Eng. J., 254, 163 (2014)
Lee MS, Kim DJ, J. Ind. Eng. Chem., 51, 64 (2017)
Wang J, Song J, Lu J, Zhao X, J. Water Resour. Prot., 6, 902 (2014)
Zhou Y, Xing XH, Liu Z, Cui L, Yu A, Feng Q, Yang H, Chemosphere, 72, 290 (2008)
Ozacar M, Sengil IA, J. Hazard. Mater., 100(1-3), 131 (2003)
APHA A, WEF, Standard Methods for the Examination of Water and Wastewater, APHA/AWWA/WEF, Washington, DC, 2005.
de Vicente I, Huang P, Andersen FO, Jensen HS, Environ. Sci. Technol., 42, 6650 (2008)
Hafner B, (2006). http://www.charfac.umn.edu/instruments/eds_on_sem_-primer.pdf.
Lukkari K, Hartikainen H, Leivuori M, Limnol. Oceanogr. Methods, 5, 433 (2007)
Jan J, Borovec J, Kopacek J, Hejzlar J, Water Res., 47, 547 (2013)
Abdala DB, Northrup PA, Arai Y, Sparks DL, J. Colloid Interface Sci., 437, 297 (2015)
Ozacar M, Sengil I, Turk. J. Eng. Environ. Sci., 27, 227 (2003)
Kim B, Gautier M, Michel P, Gourdon R, Water Sci. Technol., 68, 2257 (2013)
Han JK, Song HY, Saito F, Lee BT, Mater. Chem. Phys., 99(2-3), 235 (2006)
Kwon MD, Kubicki JD, Langmuir, 20(21), 9249 (2004)
Lefevre G, Adv. Colloid Interface Sci., 107, 109 (2004)
Vogel C, Kohl A, Adams C, Appl. Spectrosc., 65, 265 (2011)
Liu J, Zhao F, Chin. J. Geochem., 30, 264 (2011)
Yang Y, Zhao YQ, Babatunde AQ, Wang L, Ren YX, Han Y, Sep. Purif. Technol., 51(2), 193 (2006)
Carabante I, Grahn M, Holmgren A, Kumpiene J, Hedlund J, Colloids Surf. A: Physicochem. Eng. Asp., 346, 106 (2009)

[Referenced By]

[1] Petzet S, Peplinski B, Bodkhe S, Cornel P, Water Sci. Technol., 64, 693 (2011)

[2] Jeon S, Kim DJ, J. Ind. Eng. Chem., 58, 216 (2017)

[3] Chen M, Graedel T, Global Environ. Change, 36, 139 (2016)

[4] Cooper J, Lombardi R, Boardman D, Carliell-Marquet C, Resour. Conserv. Recycl., 57, 78 (2011)

[5] Senthilkumar K, Mollier A, Delmas M, Pellerin S, Nesme T, Resour. Conserv. Recycl., 87, 97 (2014)

[6] Lacasa E, Canizares P, Saez C, Fernandez FJ, Rodrigo MA, Chem. Eng. J., 172(1), 137 (2011)

[7] Lim BH, Kim DJ, J. Ind. Eng. Chem., 46, 62 (2017)

[8] Richardson CJ, King RS, Qian SS, Vaithiyanathan P, Qualls RG, Stow CA, Water Sci. Technol., 41, 8084 (2007)

[9] Guaya D, Valderrama C, Farran A, Armijos C, Cortina JL, Chem. Eng. J., 271, 204 (2015)

[10] Leopold P, Freese SD, Water Research Commission Report, (2009).

[11] Ali TU, Kim DJ, Bioresour. Technol., 217, 233 (2016)

[12] Jing C, Zhaokun L, Fresenius Environ. Bull., 9, 2200 (2010)

[13] Hafsteinsdottir EG, Camenzuli D, Rocavert AL, Walworth J, Gore DB, Appl. Geochem., 59, 47 (2015)

[14] Gustafsson JP, Mwamila LM, Kergoat K, Geoderma, 189, 304 (2012)

[15] Kim GJ, Kim HJ, Moon HS, Chon CM, Ahn JS, Chem. Spec. Bioavailab., 14, 67 (2002)

[16] Gregory J, Dupont V, Water Sci. Technol., 44, 231 (2001)

[17] Wu X, Ge X, Wang D, Tang H, Colloids Surf. A: Physicochem. Eng. Asp., 305, 89 (2007)

[18] Tejedor-Tejedor MI, Anderson MA, Langmuir, 6, 602 (1990)

[19] Luengo C, Brigante M, Antelo J, Avena M, J. Colloid Interface Sci., 300(2), 511 (2006)

[20] Elzinga EJ, Sparks DL, J. Colloid Interface Sci., 308(1), 53 (2007)

[21] Kaiserli A, Voutsa D, Samara C, Chemosphere, 46, 1147 (2002)

[22] Huang XL, Chen Y, Shenker M, J. Environ. Qual., 37, 1949 (2008)

[23] Zheng TT, Sun ZX, Yang XF, Holmgren A, Chem. Cent. J., 6, 1 (2012)

[24] Arai Y, Sparks DL, J. Colloid Interface Sci., 241(2), 317 (2001)

[25] Del Nero M, Galindo C, Barillon R, Halter E, Made B, J. Colloid Interface Sci., 342(2), 437 (2010)

[26] Luengo CV, Castellani NJ, Ferullo RM, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 14, 193 (2015)

[27] Xie J, Wang Z, Lu SY, Wu DY, Zhang ZJ, Kong HN, Chem. Eng. J., 254, 163 (2014)

[28] Lee MS, Kim DJ, J. Ind. Eng. Chem., 51, 64 (2017)

[29] Wang J, Song J, Lu J, Zhao X, J. Water Resour. Prot., 6, 902 (2014)

[30] Zhou Y, Xing XH, Liu Z, Cui L, Yu A, Feng Q, Yang H, Chemosphere, 72, 290 (2008)

[31] Ozacar M, Sengil IA, J. Hazard. Mater., 100(1-3), 131 (2003)

[32] APHA A, WEF, Standard Methods for the Examination of Water and Wastewater, APHA/AWWA/WEF, Washington, DC, 2005.

[33] de Vicente I, Huang P, Andersen FO, Jensen HS, Environ. Sci. Technol., 42, 6650 (2008)

[34] Hafner B, (2006). http://www.charfac.umn.edu/instruments/eds_on_sem_-primer.pdf.

[35] Lukkari K, Hartikainen H, Leivuori M, Limnol. Oceanogr. Methods, 5, 433 (2007)

[36] Jan J, Borovec J, Kopacek J, Hejzlar J, Water Res., 47, 547 (2013)

[37] Abdala DB, Northrup PA, Arai Y, Sparks DL, J. Colloid Interface Sci., 437, 297 (2015)

[38] Ozacar M, Sengil I, Turk. J. Eng. Environ. Sci., 27, 227 (2003)

[39] Kim B, Gautier M, Michel P, Gourdon R, Water Sci. Technol., 68, 2257 (2013)

[40] Han JK, Song HY, Saito F, Lee BT, Mater. Chem. Phys., 99(2-3), 235 (2006)

[41] Kwon MD, Kubicki JD, Langmuir, 20(21), 9249 (2004)

[42] Lefevre G, Adv. Colloid Interface Sci., 107, 109 (2004)

[43] Vogel C, Kohl A, Adams C, Appl. Spectrosc., 65, 265 (2011)

[44] Liu J, Zhao F, Chin. J. Geochem., 30, 264 (2011)

[45] Yang Y, Zhao YQ, Babatunde AQ, Wang L, Ren YX, Han Y, Sep. Purif. Technol., 51(2), 193 (2006)

[46] Carabante I, Grahn M, Holmgren A, Kumpiene J, Hedlund J, Colloids Surf. A: Physicochem. Eng. Asp., 346, 106 (2009)