화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.71, 293-300, March, 2019
DOI10.1016/j.jiec.2018.11.038  Export Citation
Electrical heating behavior of flexible thermoplastic polyurethane/ Super-P nanoparticle composite films for advanced wearable heaters
Zhen Xiao1, Chengjie Sheng2, Yang Xia2, †, Xiaojun Yu2, 3, Chu Liang2, Hui Huang2, Yongping Gan2, Jun Zhang2, and Wenkui Zhang2, †
  • 1College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, China
  • 2College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • 3Ningbo Aike Sunwik New Material Technology Co., Ltd, Ningbo 315000, China
E-mail:,
A rationally designed flexible electrothermal film is composed of Super-P (SP, nanoparticle), thermoplastic polyurethane (TPU) and silica. The electric heating behavior of electrothermal films can be facilely adjusted by SP contents and applied voltages. TPU/SP composite with 25 wt.% SP presents robust structural stability, fast response feature and superior electrothermal reproducibility. The conductive network formed by SP nanoparticles not only could quickly convert the electric energy to heat, but also is stable under stepwise periodic and long-term electric heating.cooling conditions. Finally, a smart wrist band integrated electric heater and temperature indicator is verified the high potential in multifunctional wearable device applications.
Keywords:Flexible electrothermal film;Super-P;Thermoplastic polyurethane;Electric heating behavior;Wearable device
  1. Janas D, Koziol KK, Carbon, 59, 457 (2013)
  2. Kang J, Kim H, Kim KS, Lee SK, Bae S, Ahn JH, Kim YJ, Choi JB, Hong BH, Nano Lett., 11, 5154 (2011)
  3. Lee BJ, Jeong GH, Curr. Appl. Phys., 12, S113 (2012)
  4. Bae JJ, Lim SC, Han GH, Jo YW, Doung DL, Kim ES, Chae SJ, Huy TQ, Luan NV, Lee YH, Adv. Funct. Mater., 22(22), 4819 (2012)
  5. Yoon YH, Song JW, Kim D, Kim J, Park JK, Oh SK, Han CS, Adv. Mater., 19(23), 4284 (2007)
  6. Luo J, Lu HF, Zhang QC, Yao YC, Chen MH, Li QW, Carbon, 110, 343 (2016)
  7. Li C, Xu YT, Zhao B, Jiang L, Chen SG, Xu JB, Fu XZ, Sun R, Wong CP, J. Mater. Sci., 51(2), 1043 (2016)
  8. Yan J, Jeong YG, Compos. Sci. Technol., 106, 134 (2015)
  9. Shin KY, Hong JY, Lee S, Jang J, J. Mater. Chem., 22, 23404 (2012)
  10. Lan W, Chen YX, Yang ZW, Han WH, Zhou JY, Zhang Y, Wang JY, Tang GM, Wei YP, Dou W, Su Q, Xie EQ, ACS Appl. Mater. Interfaces, 9, 6644 (2017)
  11. Li YQ, Zhu WB, Yu XG, Huang P, Fu SY, Hu N, Liao K, ACS Appl. Mater. Interfaces, 8, 33189 (2016)
  12. Sui D, Huang Y, Huang L, Liang JJ, Ma YF, Chen YS, Small, 7, 3186 (2011)
  13. Zhang X, Zheng SD, Zheng XF, Liu ZY, Yang W, Yang MB, Phys. Chem. Chem. Phys., 18, 8081 (2016)
  14. Janas D, Koziol KK, Nanoscale, 6, 3037 (2014)
  15. Chu K, Park SH, J. Ind. Eng. Chem., 35, 195 (2016)
  16. Yan J, Jeong YG, Appl. Phys. Lett., 105, 051907 (2014)
  17. Lu C, Wang R, Hu XN, Cao QQ, Huang XH, He YX, Zhang YQ, Polym. Bull., 71(3), 545 (2014)
  18. Jeong YG, Jeon GW, ACS Appl. Mater. Interfaces, 5, 6527 (2013)
  19. Jang HS, Jeon SK, Nahm SH, Carbon, 49, 111 (2011)
  20. Bai BC, Kang SC, Im JS, Lee SH, Lee YS, Mater. Res. Bull., 46(9), 1391 (2011)
  21. Zhang TY, Zhao HM, Wang DY, Wang Q, Pang Y, Deng NQ, Cao HW, Yang Y, Ren TL, Nanoscale, 9, 14357 (2017)
  22. An JE, Jeong YG, Eur. Polym. J., 49, 1322 (2013)
  23. Wei Y, Li ZY, Liu XH, Dai K, Zheng GQ, Liu CT, Chen JB, Shen CY, Colloid Polym. Sci., 292, 2891 (2014)
  24. Song YH, Zheng Q, Polym. Int., 53, 1517 (2004)
  25. El-Tantawy F, Kamada K, Ohnabe H, Mater. Lett., 56, 112 (2002)
  26. El-Tantawy F, Kamada K, Ohnabe H, Mater. Lett., 57, 242 (2002)
  27. Liu XH, Pan YM, Zheng GQ, Schubert DW, Compos. Sci. Technol., 128, 1 (2016)
  28. Pan YM, Liu XH, Kaschta J, Hao XQ, Liu CT, Schubert DW, Polymer, 113, 34 (2017)
  29. Xia Y, Yu XJ, Sheng CJ, Liang C, Huan H, Gan YP, Zhang J, Tao XY, Xiao Z, Zhang WK, Mater. Res. Bull., 90, 273 (2017)
  30. Zhang XD, Wang XL, Liu XH, Lv CJ, Wang YM, Zheng GQ, Liu H, Liu CT, Guo ZH, Shen CY, ACS Sustain. Chem. Eng., 6, 12580 (2018)
  31. Nakano H, Shimizu K, Takahashi S, Kono A, Ougizawa T, Horibe H, Polymer, 53(26), 6112 (2012)
  32. Kono A, Shimizu K, Nakano H, Goto Y, Kobayashi Y, Ougizawa T, Horibe H, Polymer, 53(8), 1760 (2012)
  33. Im H, Jang EY, Choi A, Kim WJ, Kang TJ, Park YW, Kim YH, ACS Appl. Mater. Interfaces, 4, 2338 (2012)
  34. Radzi AM, Sapuan SM, Jawaid M, Mansor MR, Fibers Polym., 18, 1353 (2017)
  35. Wang XL, Pan YM, Shen CY, Liu CT, Liu XH, Macromol. Rapid Commun., 39, 180063 (2018)
  36. Kim JW, Lee JS, Fibers Polym., 18, 81 (2017)
  37. Ramoa SDAS, Barra GMO, Oliveira RVB, de Oliveira MG, Cossa M, Soares BG, Polym. Int., 62, 1477 (2013)
  38. Atiqah A, Jawaid M, Ishak MR, Sapuan SM, J. Nat. Fibers, 15, 251 (2018)
  39. El-Shekeil YA, Sapuan SM, Jawaid M, Al-Shuja’a OM, Mater. Des., 58, 130 (2014)
  40. Atiqah A, Jawaid M, Sapuan SM, Ishak MR, Alotman OY, Compos. Struct., 202, 954 (2018)
  41. Christ JF, Aliheidari N, Ameli A, Potschke P, Mater. Des., 131, 394 (2017)
  42. Li YH, Zhou B, Zheng GQ, Liu XH, Li TX, Yan C, Cheng CB, Dai K, Liu CT, Shen CY, Guo ZH, J. Mater. Chem. C6, 2258, 2018
  43. Kim JW, Lee JS, Fibers Polym., 18, 81 (2017)
  44. Kasgoz A, Korkmaz M, Alanalp MB, Durmus A, J. Polym. Res., 24, 148 (2017)
  45. Lu Y, Jiang JQ, Yoon SH, Kim KS, Kim JH, Park SH, Kim SH, Piao LH, ACS Appl. Mater. Interfaces, 10, 2093 (2018)
  46. Liang C, Zhou LT, Zhou CH, Huang H, Liang S, Xia Y, Gan YP, Tao XY, Zhang J, Zhang WK, Mater. Res. Bull., 96, 347 (2017)
  47. Yuan Q, Zhou T, Li L, Zhang JH, Liu XF, Ke XL, Zhang AM, RSC Adv., 5, 31153 (2015)
  48. Zhang SM, Deng H, Zhang Q, Fu Q, ACS Appl. Mater. Interfaces, 6, 6835 (2014)