Journal of Polymer Science Part A: Polymer Chemistry, Vol.34, No.5, 747-754, 1996
New Poly(Amide-Imide)S Syntheses .17. Preparation and Properties of Poly(Amide-Imide)S Derived from 3,3-bis(4-(4-Aminophenoxy)Phenyl)Phthalimidine and Various bis(Trimellitimide)S
A series of novel bis(phenoxy)phthalimidine-containing poly(amide-imide)s III were synthesized by the direct polycondensation of 3,3-bis[4-(4-aminophenoxy)phenyl]phthalimidine (BAPP) with various aromatic bis(trimellitimide)s in N-methyl-2-pyrrolidone (NMP) using triphenyl phosphite and pyridine as condensing agents. Poly(amide-imide)s III, having inherent viscosities up to 1.36 dL/g, were obtained in quantitative yields. All resulting polymers showed an amorphous nature and were readily soluble in polar solvents such as NMP and N,N-dimethylacetamide. All the soluble poly(amide-imide)s afforded transparent, flexible, and tough films. The glass transition temperatures of these polymers were in the range of 267-322 degrees C and the 10% weight loss temperatures were above 490 degrees C in nitrogen. Some properties of poly(amide-imide)s III were compared with those of the corresponding isomeric poly(amide-imide)s III’ prepared from 3,3-[4-(4-trimellitimidophenoxy)phenyl]phthalimidine and various aromatic diamines.
Keywords:AROMATIC POLYAMIDE-IMIDES;4-CHLOROFORMYLPHTHALIC ANHYDRIDE;2;5-BIS(4-AMINOPHENYL)-3;4-DIPHENYLTHIOPHENE