화학공학소재연구정보센터
Journal of Polymer Science Part A: Polymer Chemistry, Vol.34, No.5, 739-745, 1996
Copolymerization Effect of M-Acetoxybenzoic Acid on Morphology of Poly(Oxy-1,4-Benzenediylcarbonyl) Whiskers
Copolymerizations of p-acetoxybenzoic acid (p-ABA) and m-acetoxybenzoic acid (m-ABA) were carried out in liquid paraffin at 330 degrees C without stirring. Needlelike crystals are obtained when the content of m-ABA in the feed (chi(f)) is in the range of 0-30 mol %. These needlelike crystals are inclined to show the fibrillation in both ends and the radial growth nature from the central part as chi(f) increased. At higher chi(f) than 40 mol %, crystals are not precipitated during polymerization. The content of m-oxybenzoyl units in the obtained whiskers (chi(w)) are much lower than chi(f). The details of the polymerization and crystallization processes reveal that cooligomers containing more m-oxybenzoyl units cannot participate in the formation of needlelike crystals due to the higher solubility and the segregation effect of crystallization. The whiskers are predominantly formed by co-oligomers consisting almost entirely of p-oxybenzoyl units.