Journal of Industrial and Engineering Chemistry, Vol.64, 206-218, August, 2018
Improved photoelectric performance via fabricated heterojunction g-C 3N4/TiO2/HNTs loaded photocatalysts for photodegradation of ciprofloxacin
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An Intercalated heterostructural g-C3N4/TiO2/HNTs supported photocatalyst was successfully prepared via sol-gel and calcination methods. The introduction of HNTs and the g-C3N4-TiO2 heterojunction effectively enhanced the charge transfer and separation efficiency of photogenerated electron.hole pairs, which endued the g-C3N4/TiO2/HNTs hybrid material with an outstanding photoelectric performance and good stability. And an obviously enhanced photocatalytic activity was exhibited by photodegrading ciprofloxacin compared with pure TiO2. Furthermore, the main active species were detected through trapping experiment and ESR spin-trap technique with DMPO, which confirmed that the ㆍO2 - and the h+ were the main active species in the photocatalytic system.
- Blair JMA, Webber MA, Baylay AJ, Ogbolu DO, Piddock LJV, Nat. Rev. Microbiol., 13, 42 (2015)
- Xu J, Xu Y, Wang H, Guo C, Qiu H, He Y, Chemosphere, 119, 1379 (2015)
- Wang H, Li J, Zhou M, Guan Q, Lu Z, Huo P, Yan Y, J. Ind. Eng. Chem., 30, 64 (2015)
- Gao Y, Li Y, Zhang L, Huang H, Hu JJ, Shah SM, Su XG, J. Colloid Interface Sci., 368, 540 (2012)
- Moreira FC, Garcia-Segura S, Rui ARB, Brillas E, Vilar VJP, Appl. Catal. B: Environ., 160-161, 492 (2014)
- Ma ZQ, Ma YL, Xie L, Zhang ZY, Wang M, Environ. Sci. Technol., 35, 46 (2012)
- Zhao C, Pelaez M, Duan XD, Deng HP, O’Shea K, Fatta-Kassinos D, Dionysiou DD, Appl. Catal. B: Environ., 134-135, 83 (2013)
- Xue J, Ma S, Zhou Y, Zhang Z, He M, ACS Appl. Mater Interfaces, 7, 9630 (2015)
- Li SZ, Li XY, Wang DM, Sep. Purif. Technol., 34(1-3), 109 (2004)
- Aazam ES, J. Ind. Eng. Chem., 20(5), 2870 (2014)
- Chang MY, Chang CY, Hsieh YH, Yao KS, Cheng TC, Ho CT, Adv. Mater. Res., 47-50, 471 (2008)
- Hou Y, Li X, Zou X, Quan X, Chen G, Environ. Sci. Technol., 43, 858 (2009)
- Xiang Z, Wang Y, Zhang D, Ju P, J. Ind. Eng. Chem., 40, 83 (2016)
- Chen YJ, Dionysiou DD, Appl. Catal. B: Environ., 80(1-2), 147 (2008)
- Nitoi I, Oancea P, Raileanu M, Crisan M, Constantin L, Cristea I, J. Ind. Eng. Chem., 21, 677 (2015)
- Zhou L, Wang LZ, Lei JY, Liu YD, Zhang JL, Catal. Commun., 89, 125 (2017)
- Zhou L, Wang LZ, Zhang JL, Lei JY, Liu YD, Res. Chem. Intermed., 43, 2081 (2017)
- Li H, Zhou L, Wang LZ, Liu YD, Lei JY, Zhang JL, Phys. Chem. Chem. Phys., 17, 17406 (2015)
- Subramanian V, Wolf E, Kamat PV, J. Phys. Chem. B, 105(46), 11439 (2001)
- Pawar RC, Kang S, Ahn SH, Lee CS, RSC Adv., 5, 24281 (2015)
- Jiang Y, Li F, Liu Y, Hong Y, Liu P, Ni L, J. Ind. Eng. Chem., 41, 130 (2016)
- Li ZS, Yang SY, Zhou JM, Li DH, Zhou XF, Ge CY, Fang YP, Chem. Eng. J., 241, 344 (2014)
- Di J, Xia JX, Yin S, Xu H, He MQ, Li HM, Xu L, Jiang YP, RSC Adv., 3, 19624 (2013)
- Sun JX, Yuan YP, Qiu LG, Jiang X, Xie AJ, Shen YH, Zhu JF, Dalton Trans., 41, 6756 (2012)
- Katsumata H, Tachi Y, Suzuki T, Kaneco S, RSC Adv., 4, 21405 (2014)
- Zhang JY, Wang YS, Jin J, Zhang J, Huang F, Yu JG, ACS Appl. Mater. Interfaces, 5, 10317 (2013)
- Chen XF, Wei J, Hou RJ, Liang Y, Xie ZL, Zhu YG, Zhang XW, Wang HT, Appl. Catal. B: Environ., 188, 342 (2016)
- Li J, Zhang M, Li QY, Yang JJ, Appl. Surf. Sci., 391, 184 (2017)
- Abdelwahab NA, Helaly FM, J. Ind. Eng. Chem., 50, 162 (2017)
- Jiang D, Xu Y, Hou B, Wu D, Sun YH, J. Solid State Chem., 180, 1787 (2007)
- Li CP, Wang J, Guo H, Ding SJ, J. Colloid Interface Sci., 458, 1 (2015)
- Rather RA, Singh S, Pal B, J. Ind. Eng. Chem., 37, 288 (2016)
- Pajootan E, Rahimdokht M, Arami M, J. Ind. Eng. Chem., 55, 149 (2017)
- Zhang J, Zhang L, Zhou S, Chen H, Zhong H, Zhao Y, Wang X, J. Ind. Eng. Chem., 20(5), 3884 (2014)
- Wang RJ, Jiang GH, Ding YW, Wang Y, Sun XK, Wang XH, Chen WX, Acs Appl. Mater. Interfaces, 3, 4154 (2011)
- Li JZ, Zhou MJ, Ye ZF, Wang HQ, Ma CC, Huo PW, Yan YS, RSC Adv., 5, 91177 (2015)
- Zheng PW, Du YY, Chang PR, Ma XF, Appl. Surf. Sci., 329, 256 (2015)
- Ye ZF, Li JZ, Zhou MJ, Wang HQ, Ma Y, Huo PW, Yu LB, Yan YS, Chem. Eng. J., 304, 917 (2016)
- Du Y, Zheng P, Korean J. Chem. Eng., 31(11), 2051 (2014)
- Yan SC, Li ZS, Zou ZG, Langmuir, 25(17), 10397 (2009)
- Liu FH, Yu J, Tu GY, Qu L, Xiao JC, Liu YD, Wang LZ, Lei JY, Zhang JL, Appl. Catal. B: Environ., 201, 1 (2017)
- Song X, Hu Y, Zheng MM, Wei CH, Appl. Catal. B: Environ., 182, 587 (2016)
- Papailias I, Todorova N, Giannakopoulou T, Yu JG, Dimotikali D, Trapalis C, Catal. Today, 280, 37 (2017)
- Tong ZW, Yang D, Xiao TX, Tian Y, Jiang ZY, Chem. Eng. J., 260, 117 (2015)
- Li CQ, Sun ZM, Xue YL, Yao GY, Zheng SL, Adv. Powder Technol., 27(2), 330 (2016)
- Lu Z, Zeng L, Song WL, Qin ZY, Zeng DW, Xie CS, Appl. Catal. B: Environ., 202, 489 (2017)
- Jiang ZF, Qian K, Zhu CZ, Sun HL, Wan WM, Xie JM, Li HM, Wong PK, Yuan SQ, Appl. Catal. B: Environ., 210, 194 (2017)
- Yang HG, Liu G, Qiao SZ, Sun CH, Jin YG, Smith SC, Zou J, Cheng HM, Lu GQ, J. Am. Chem. Soc., 131(11), 4078 (2009)
- Xu X, Gao ZH, Cui ZD, Liang YQ, Li ZY, Zhu SL, Yang XJ, Ma JM, Acs Appl. Mater. Interfaces, 8, 91 (2005)
- Pan XY, Chen XX, Yi ZG, Acs Appl. Mater. Interfaces, 8, 10104 (2016)
- Yang YC, Wen JW, Wei JH, Xiong R, Shi J, Pan CX, ACS Appl. Mater Interfaces, 5, 6201 (2013)
- Thomas A, Fischer A, Goettmann F, Antonietti M, Mueller MO, Schloegl R, Carlsson JM, Cheminform, 18, 4893 (2008)
- Jiang ZF, Jiang DL, Yan ZX, Liu D, Qian K, Xie JM, Appl. Catal. B: Environ., 170-171, 195 (2015)
- Reli M, Huo PW, Sihor M, Ambrozova N, Troppova I, Matejova L, Lang J, Svoboda L, Kustrowski P, Ritz M, Praus P, Koci K, J. Phys. Chem. A, 120(43), 8564 (2016)
- Xue C, Zhang TX, Ding SJ, Wei JJ, Yang GD, ACS Appl. Mater. Interfaces, 9, 16091 (2017)
- Sun P, Liu GM, Lv D, Dong X, Wu JS, Wang DJ, RSC Adv., 5, 52916 (2015)
- Yang SY, Liu ZM, Jiao YQ, Liu YP, Ji CW, Zhang YF, J. Mater. Sci., 49, 4270 (2014)
- Xiang QJ, Yu JG, Jaroniec M, J. Phys. Chem. C, 115, 7355 (2011)
- Li J, Shen B, Hong Z, Lin B, Gao B, Chen Y, Chem. Commun., 48, 12017 (2012)
- Yu HX, Zhang YT, Sun XB, Liu JD, Zhang HQ, Chem. Eng. J., 237, 322 (2014)
- Zhang Y, Fu LJ, Yang HM, Colloids Surf. A: Physicochem. Eng. Asp., 414, 115 (2012)
- Lu DZ, Fang PF, Liu XZ, Zhai SB, Li CH, Zhao XN, Ding JQ, Xiong RY, Appl. Catal. B: Environ., 179, 558 (2015)
- Li YG, Wei XL, Li HJ, Wang RR, Feng J, Yun H, Zhou AN, RSC Adv., 5, 14074 (2015)
- Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW, Pure Appl. Chem., 38, 25 (2011)
- Li CQ, Sun ZM, Xue YL, Yao GY, Zheng SL, Adv. Powder Technol., 27(2), 330 (2016)
- Zhang LW, Fu HB, Zhu YF, Adv. Funct. Mater., 18, 2180 (2010)
- Leong KH, Liu SL, Sim LC, Saravanan P, Jang M, Ibrahim S, Appl. Surf. Sci., 358, 370 (2015)
- Jiang JZ, Ou-yang L, Zhu LH, Zheng AM, Zou J, Yi XF, Tang HQ, Carbon, 80, 213 (2014)
- Serpone N, Lawless D, Khairutdinov R, J. Phys. Chem., 99(45), 16646 (1995)
- Li K, Gao SM, Wang QY, Xu H, Wang ZY, Huang BB, Dai Y, Lu J, ACS Appl. Mater. Interfaces, 7, 9023 (2015)
- Li GY, Nie X, Chen JY, Jiang Q, An TC, Wong PK, Zhang HM, Zhao HJ, Yamashita H, Water Res., 86, 17 (2015)
- Kong M, Li YZ, Chen X, Tian TT, Fang PF, Zheng F, Zhao XJ, J. Am. Chem. Soc., 133(41), 16414 (2011)
- He YM, Cai J, Li TT, Wu Y, Yi YM, Luo MF, Zhao LH, Ind. Eng. Chem. Res., 51, 14729 (2011)
- Li GR, Wang F, Jiang QW, Gao XP, Shen PW, Angew. Chem.-Int. Edit., 49, 3653 (2010)
- Li JX, Xu JH, Dai WL, Fan KN, J. Phys. Chem. C, 113, 8343 (2009)
- Chen XF, Wei J, Hou RJ, Liang Y, Xie ZL, Zhu YG, Zhang XW, Wang HT, Appl. Catal. B: Environ., 188, 342 (2016)
- Tu WG, Zhou Y, Liu Q, Yan SC, Bao SS, Wang XY, Xiao M, Zou ZG, Adv. Funct. Mater., 23(14), 1743 (2013)
- Li CM, Du YH, Wang DP, Yin SM, Tu WG, Chen Z, Kraft M, Chen G, Xu R, Adv. Funct. Mater., 27, 160432 (2016)
- Lu ZY, Zhu Z, Wang DD, Ma ZF, Shi WD, Yan YS, Zhao XX, Dong HJ, Yang L, Fa ZH, Catal. Sci. Technol., 6, 1367 (2016)
- Li JZ, Ma Y, Ye ZF, Zhou MJ, Wang HQ, Ma CC, Wang DD, Huo PW, Yan YS, Appl. Catal. B: Environ., 204, 224 (2017)
- Zhou MJ, Han DL, Liu XL, Ma CC, Wang HQ, Tang YF, Huo PW, Shi WD, Yan YS, Yang JH, Appl. Catal. B: Environ., 172-173, 174 (2015)