화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.6, 1341-1347, June, 2018
DOI10.1007/s11814-018-0027-7  Export Citation
Gd3+ doped Fe3O4 nanoparticles with proper magnetic and supercapacitive characteristics: A novel synthesis platform and characterization
Mustafa Aghazadeh1, †, Isa Karimzadeh2, Mohammad Ghannadi Maragheh1, and Mohammad Reza Ganjali3, 4
  • 1Materials and Nuclear Research School, NSTRI, P. O. Box 14395-834, Tehran, Iran
  • 2Department of Physics, Bonab Branch, Islamic Azad University, Bonab, Iran
  • 3Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran
  • 4Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
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A novel electrochemical procedure was developed for the facile preparation of Gd-doped iron oxide nanoparticles (GdIO-NPs). A simple galvanostatic deposition (i=10mA cm-2) was done in an additive-free aqueous solution containing FeCl2·4H2O, Fe(NO3)3·9H2O and GdCl3·6H2O. The XRD, FE-SEM, EDS and TEM characterizations showed that the product is composed of 15% GdIO-NPs with 10 nm in size. VSM analysis proved that the GdIONPs are superparamagnetic. The cyclic voltammetry and charge-discharge tests showed that the prepared GdIO-NPs are capable to deliver specific capacity as high as 190.1 F g-1 at 0.5A g-1 and capacity retention of 95.1% after 2000 cycling. Based on the results, it was concluded that the developed electrochemical strategy acts as an efficient procedure for the preparation of lanthanide doped MNPs with proper magnetic and supercapacitive characters.
Keywords:Iron Oxide;Gd Ion Doping;Nanoparticles;Electrodeposition;Magnetic Materials;Supercapacitors
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