화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.62, 392-400, June, 2018
DOI10.1016/j.jiec.2018.01.019  Export Citation
Sensitive 1,2-dichlorobenzene chemi-sensor development based on solvothermally prepared FeO/CdO nanocubes for environmental safety
Mohammed M. Rahman1, 2, †, M.M. Alam3, and Abdullah M. Asiri1, 2
  • 1Chemistry Department, King Abdulaziz University, Faculty of Science, Jeddah 21589, P.O. Box 80203, Saudi Arabia
  • 2Center of Excellence for Advanced Material Research (CEAMR), King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia
  • 3Department of Chemical Engineering and Polymer Science, Shahjalal University of Science and Technology, Sylhet 3100, Bangladesh
E-mail:
In this approach, we report the assembly of a dynamic, high sensitive, selective and reproducible 1,2- dichlorobenzene (1,2-DCB) chemi-sensor development based on solvothermally prepared nanocubes (NCs) of FeO/CdO. The synthesized FeO/CdO NCs was exhibited as an excellent electron mediator during the sensing performance of 1,2-DCB in aqueous medium and this research work was executed by electrochemical method. The morphological, optical, elemental, and structural characterization of synthesized NCs were investigated by various conventional techniques such as FTIR, UV.vis, FESEM, XPS, EDS, and XRD. NCs were used to fabricate glassy carbon electrode (GCE) with nafion conducting binder. The sensitivity of proposed chemi-sensor was estimated from the slope of calibration curve attained as current versus concentration of 1,2-DCB relation. It was introduced a reliable future sensitive sensor development using FeO/CdO NCs by electrochemical approach for the probable detection of toxic 1,2-DCB and other environmental carcinogenic chemicals for the safety of environmental and health care fields.
Keywords:1,2-Dichlorobenzene chemi-sensor;FeO/CdO nanocubes;Solvothermal method;Electrochemical technique;Sensitivity;Environmental safety
  1. Poplawski K, Lichtenberger J, Keil FJ, Schnitzlein K, Amiridis MD, Catal. Today, 62(4), 329 (2000)
  2. Krishnamoorthy S, Baker JP, Amiridis MD, Catal. Today, 40(1), 39 (1998)
  3. Albonetti S, Blasioli S, Bonelli R, Mengou JE, Scire S, Trifiro F, Appl. Catal. A: Gen., 341(1-2), 18 (2008)
  4. Ma XD, Sun Q, Feng X, He X, Guo J, Sun HW, Cao HQ, Appl. Catal. A: Gen., 450, 143 (2013)
  5. Andreozzi R, Canterino M, Marotta R, Water Res., 40, 3785 (2006)
  6. Besten CD, Vet JJRM, Besselink HT, Kiel GS, Vanberkel BJM, Beem R, Blanderen PJV, Pharmacol. Technol. Appl., 111, 69 (1991)
  7. Ameen S, Akhtar MS, Shin HS, Talanta, 100, 377 (2012)
  8. Ahmad R, Tripathy N, Jung D, Hahn YB, Chem. Commun., 50, 1890 (2014)
  9. Zhoua T, Lu P, Zhanga Z, Wang Q, Umar A, Sens. Actuators B-Chem., 235, 457 (2016)
  10. Lundberg B, Sundqvist K, J. Appl. Phys., 60, 1074 (1986)
  11. Rahman MM, Jamal A, Khan SB, Faisal M, Superlattices Microstruct., 50, 369 (2011)
  12. Rahman MM, Gruner G, Al-Ghamd MS, Daous MA, Khan SB, Asiri AM, Int. J. Electrochem. Sci., 8, 520 (2013)
  13. Liu X, Xu Z, Liu Y, Shen Y, Sens. Actuators B-Chem., 52, 270 (1998)
  14. Guo Z, Li M, Liu J, Nanotechnology, 19, 245611 (2008)
  15. Chen T, Liu QJ, Zhou ZL, Wang YD, Nanotechnology, 19, 095506 (2008)
  16. Fu X, Liuc J, Han T, Zhang X, Meng F, Liu J, Sens. Actuators B-Chem., 184, 260 (2013)
  17. Salunkhe RR, Dhawale DS, Patil UM, Lokhande CD, Sens. Actuators B-Chem., 136, 39 (2009)
  18. Speight JG, Sixteenth edition, Lange’s Handbook of Chemistry,1, McGraw-Hill, New York, p.1.331 2005.
  19. Rahmana MM, Alam MM, Asiri AM, Islam MA, Talanta, 176, 17 (2018)
  20. Rahman MM, Alam MM, Asiri AM, Awual MR, New J. Chem., 41, 9159 (2017)
  21. Rahman MM, Alam MM, Asiri AM, New J. Chem., 41, 9938 (2017)
  22. Zhang F, Yang H, Xie X, Li L, Zhang L, Yu J, Zhao H, Liu B, Sens. Actuators B-Chem., 141, 381 (2009)
  23. Pan L, Tang J, Wang F, Cent. Eur. J. Chem., 11, 763 (2013)
  24. Salehi B, Mortaz E, Tabarsi P, Adv. Biomed. Res., 4, 105 (2015)
  25. Rahman MM, Alam MM, Asiri AM, Islam MA, RSC Adv., 7, 22627 (2017)
  26. Rahman MM, Khan SB, Marwani HM, Asiri AM, Alamry KA, Rub MA, Khan A, Khan AAP, Azuma N, J. Int. Eng. Chem., 20, 2278 (2014)
  27. Rahman MM, Alam MM, Asiri AM, Islam MA, Talanta, 170, 215 (2017)
  28. Thuy NT, Minh DL, Adv. Mater. Sci. Eng., 6 (2012).
  29. Thema FT, Beukes P, Fakim AG, Maaza M, J. Alloy. Compd., 646, 1043 (2015)
  30. Garcia VP, Toledo N, Denardin J, Yazigi DV, Cruz C, Spodine E, Luo Z, J. Chil. Chem. Soc., 58, 4 (2013)
  31. Cao H, Wang G, Zhang L, Liang Y, Zhang S, Zhang X, Chem. Phys., 7, 1897 (2006)
  32. Gotic M, Koscec G, Music S, J. Mol. Struct., 347, 924 (2009)
  33. Wang X, Chen XY, Ma XC, Zheng HG, Ji MR, Zhang Z, Chem. Phys. Lett., 384(4-6), 391 (2004)
  34. Thomas P, Sreekanth P, Abraham KE, J. Appl. Phys., 117, 053103 (2015)
  35. Tummala R, Guduru RK, Mohanty PS, Mater. Res. Bull., 47(3), 700 (2012)
  36. Banerjee A, Bid S, Dutta H, Chaudhuri S, Das D, Pradhan SK, J. Asian Ceram. Soc., 49, 6 (2013)
  37. Deokate RJ, Moholkar AV, Agawane GL, Pawar SM, Kim JH, Rajpure KY, Appl. Surf. Sci., 256(11), 3522 (2010)
  38. Jenkins R, Snyder RL, Lange’s Handbook of Chemistry, John Wiley & Sons, pp.750 1994.
  39. Shen X, Liu Q, Ji Z, Zhu G, Zhoub H, Chen K, Cryst. Eng. Commun., 17, 5522 (2015)
  40. Murugesan C, Chandrasekaran G, RSC Adv., 5, 73714 (2015)
  41. Ghazzal MN, Wojcieszak R, Raj G, Gaigneaux EM, Beils. J. Nanotechnol., 5, 68 (2014)
  42. Shen M, Jia W, You Y, Hu Y, Li F, Tian S, Li J, Jin Y, Han D, Nanoscale Res. Lett., 8, 253 (2013)
  43. Li Z, Zhang W, Yuan C, Su Y, RSC Adv., 7, 12931 (2017)
  44. Zhang K, Deng Y, Yang Y, Liao Y, Wang B, Gong B, Yang W, RSC Adv., 7, 13509 (2017)
  45. Ma M, Zhang Y, Guo Z, Gu N, Nanoscale Res. Lett., 8, 16 (2013)
  46. Rosales GA, Poirier T, Cosp JP, Lira-Olivares J, Carda-Castello JB, Interceramics, 1 (2011)
  47. Khan AAP, Khan A, Rahman MM, Asiri AM, Oves M, Int. J. Biol. Macromol., 98, 256 (2017)
  48. Rahman MM, Khan SB, Asiri AM, Microchim. Acta, 182, 487 (2015)
  49. Rahman MM, Khan SB, Jamal A, Faisal M, Asiri AM, Talanta, 95, 18 (2012)
  50. Rahman MM, Gruner G, Algamdi MS, Al-Daaose M, Khan SB, Asiri AM, Int. J. Electrochem. Sci., 8, 520 (2013)
  51. Rahman MM, Khan SB, Marwani HM, Asiri AM, Alamry KA, Rub MA, Khan A, Khan AAP, Qusti AH, J. Ind. Eng. Chem., 20(3), 1071 (2014)
  52. Rahman MM, Hussain MM, Asiri AM, Microchim. Acta, 183, 3255 (2016)
  53. Ahmed J, Rahman MM, Siddiquey IA, Asiri AM, Hasnat MA, Sens. Actuators B-Chem., 256, 383 (2018)
  54. Hasnat MA, Aoun SB, Rahman MM, Asiri AM, Mohamed N, J. Ind. Eng. Chem., 28, 131 (2015)
  55. Hussain MM, Rahman MM, Asiri AM, Sci. Rep., 7, 5832 (2017)
  56. Rahman MM, Hussain MM, Asiri AM, New J. Chem., 41, 6667 (2017)
  57. Khan AAP, Asiri AM, Khan A, Azum N, Rub MA, Rahman MM, Khan SB, Siddiqi KS, Alamry KA, J. Ind. Eng. Chem., 19(2), 595 (2013)
  58. Rahman MM, Ahmed J, Asiri AM, Biosens. Bioelectron., 99, 586 (2018)
  59. Awual MR, Alharthi NH, Hasan MM, Karim MR, Islam A, Znad H, Hossain MA, Halim ME, Rahman MM, Khaleque MA, Chem. Eng. J., 324, 130 (2017)
  60. Hasnat MA, Safwan JA, Islam MS, Rahman Z, Karim MR, Pirzada TJ, Samed AJ, Rahman MM, J. Ind. Eng. Chem., 21, 787 (2015)
  61. Rahman MM, Hussain MM, Asiri AM, PLOS ONE, 12, e01778 (2017)
  62. Rahman MM, Alam MM, Asiri AM, Islam MA, Talanta, 176, 17 (2018)
  63. Awual MR, Alharthi NH, Okamoto Y, Karim MR, Halim ME, Hasan MM, Rahman MM, Islam MM, Khaleque MA, Sheikh MC, Chem. Eng. J., 320, 427 (2017)
  64. Rub MA, Asiri AM, Azum N, Khan A, Khan AAP, Khan SB, Rahman MM, Kabir-ud-Din J, Ind. Eng. Chem., 19, 1774 (2013)
  65. Hussain MM, Rahman MM, Arshad MN, Asiri AM, ACS Omega, 2, 420 (2017)
  66. Rahman MM, Khan SB, Marwani HM, Asiri AM, Alamry KA, Rub MA, Khan A, Khan AAP, Azum N, J. Ind. Eng. Chem., 20(4), 2278 (2014)
  67. Rahman MM, Hussein MA, Salam MA, Asiri AM, New J. Chem., 41, 10761 (2017)