인과 황을 포함하는 폴리아마이드 난연제의 합성과 나일론 직물에 적용

Xiangdong Zhou; Yufa Sun; Yingchun Chen; Bing Sun

Polymer(Korea), Vol.42, No.2, 157-166, March, 2018

DOI10.7317/pk.2018.42.2.157 Export Citation

인과 황을 포함하는 폴리아마이드 난연제의 합성과 나일론 직물에 적용

Synthesis and Application of a Polyamide-containing Phosphorous and Sulfur Flame-retardant for Nylon Fabric

Xiangdong Zhou^†, Yufa Sun¹, Yingchun Chen¹, and Bing Sun¹

College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
¹National Engineering Laboratory for Modern Silk, Suzhou 215123, China

E-mail:

Monomer of polyamide (PA66) and flame-retardant intermediate product (FR) were firstly synthesized, and the flame-retardant (PA-FR) was further gained by polymerization of PA66 and FR. The structure of PA-FR was confirmed by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), X-ray photoelectron spectroscopy (XPS), and gel permeation chromatography (GPC). The thermal properties of PA-FR and the finished fabric were evaluated by thermal gravity analysis (TGA) and differential scanning calorimetry (DSC). Moreover, X-ray diffraction analysis (XRD) showed that melting eutectic reaction occurred between PA-FR and nylon fabric. The experimental results showed that the limiting oxygen index (LOI) value of PA-FR treated fabric and PA-FR treated fabric after 10 laundries were improved to 28.8% and 26.4%, respectively. It implied that PA-FR had a good and durable function of imparting fire-resistance to nylon fabric.

Keywords:nylon fabric;flame-retardant;synthesis;flame-retardant finishing;eutectic

[References]

Coquelle M, Duquesne S, Casetta M, Sun J, Zhang S, Bourbigot S, Polym. Degrad. Stabil., 106, 150 (2014)
Salapare HS, Darmanin T, Guittard F, Appl. Surf. Sci., 356, 408 (2015)
Gao ZQ, Sun J, Peng SJ, Yao L, Qiu YP, Appl. Surf. Sci., 120, 2201 (2011)
Levchik SV, Weil ED, Polym. Int., 49, 1033 (2000)
Subbulakshmi MS, Kasturiya N, Hansraj, Bajaj P, Agarwal AK, J. Macromol. Sci.-Polym. Rev, 40, 85 (2000)
Lewin M, Mercel Dekker, New York, Vol 2, 117 (1984).
Yang H, Yang CQ, He QL, Polym. Degrad. Stabil., 94, 1023 (2009)
Lee JH, Park HS, An IG, Lee YH, Kim YS, Lee YK, Nam JD, Polym. Korea, 27(6), 576 (2003)
Lee JR, Choi CS, Kang HJ, Polym. Korea, 33(2), 131 (2009)
Li LY, Chen GH, Liu W, Li JF, Zhang S, Polym. Degrad. Stabil., 94, 996 (2009)
Wabeeke LV, Schryver DD, US Patent 56749 (1997).
Carothes WH, Hill JW, Am. Chem. Soc., 54, 1566 (1932)
Balabanovich AI, Engelmann J, Polym. Degrad. Stabil., 79, 85 (2003)
Bourbigot S, Bras ML, Delobel R, Carbon, 33, 283 (1995)
Jeng RJ, Shau SM, Lin JJ, Su WC, Chiu YS, Eur. Polym. J., 38, 683 (2002)
Ban DM, Wang YZ, Yang B, Zhao GM, Eur. Polym. J., 40, 1909 (2004)
Pramoda KP, Liu TX, Liu ZH, He CB, Sue HJ, Polym. Degrad. Stabil., 81, 47 (2003)
Kwak SB, Jung CH, Nam JD, Kim JH, Choi MA, Kong JH, Polym. Korea, 24(6), 777 (2000)
Yoon HD, Nam S, Tu NDK, Kim D, Kim H, Polym. Korea, 37(5), 638 (2013)
Nguyen TMD, Chang S, Condon B, Slopek R, Fiber Polym., 13, 963 (2012)
Wang X, Li QS, Di YD, Xing GZ, Fiber Polym., 13, 718 (2012)

[1] Coquelle M, Duquesne S, Casetta M, Sun J, Zhang S, Bourbigot S, Polym. Degrad. Stabil., 106, 150 (2014)

[2] Salapare HS, Darmanin T, Guittard F, Appl. Surf. Sci., 356, 408 (2015)

[3] Gao ZQ, Sun J, Peng SJ, Yao L, Qiu YP, Appl. Surf. Sci., 120, 2201 (2011)

[4] Levchik SV, Weil ED, Polym. Int., 49, 1033 (2000)

[5] Subbulakshmi MS, Kasturiya N, Hansraj, Bajaj P, Agarwal AK, J. Macromol. Sci.-Polym. Rev, 40, 85 (2000)

[6] Lewin M, Mercel Dekker, New York, Vol 2, 117 (1984).

[7] Yang H, Yang CQ, He QL, Polym. Degrad. Stabil., 94, 1023 (2009)

[8] Lee JH, Park HS, An IG, Lee YH, Kim YS, Lee YK, Nam JD, Polym. Korea, 27(6), 576 (2003)

[9] Lee JR, Choi CS, Kang HJ, Polym. Korea, 33(2), 131 (2009)

[10] Li LY, Chen GH, Liu W, Li JF, Zhang S, Polym. Degrad. Stabil., 94, 996 (2009)

[11] Wabeeke LV, Schryver DD, US Patent 56749 (1997).

[12] Carothes WH, Hill JW, Am. Chem. Soc., 54, 1566 (1932)

[13] Balabanovich AI, Engelmann J, Polym. Degrad. Stabil., 79, 85 (2003)

[14] Bourbigot S, Bras ML, Delobel R, Carbon, 33, 283 (1995)

[15] Jeng RJ, Shau SM, Lin JJ, Su WC, Chiu YS, Eur. Polym. J., 38, 683 (2002)

[16] Ban DM, Wang YZ, Yang B, Zhao GM, Eur. Polym. J., 40, 1909 (2004)

[17] Pramoda KP, Liu TX, Liu ZH, He CB, Sue HJ, Polym. Degrad. Stabil., 81, 47 (2003)

[18] Kwak SB, Jung CH, Nam JD, Kim JH, Choi MA, Kong JH, Polym. Korea, 24(6), 777 (2000)

[19] Yoon HD, Nam S, Tu NDK, Kim D, Kim H, Polym. Korea, 37(5), 638 (2013)

[20] Nguyen TMD, Chang S, Condon B, Slopek R, Fiber Polym., 13, 963 (2012)

[21] Wang X, Li QS, Di YD, Xing GZ, Fiber Polym., 13, 718 (2012)