화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.9, 2527-2535, September, 2017
DOI10.1007/s11814-017-0150-x  Export Citation
Synthesis and characterization of physicochemical properties of hydrophilic imidazolium-based ionic liquids
Maryam Yousefi, Majid Abdouss†, Ali Akbar Miran Beigi1, and Ali Naseri1
  • Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
  • 1Research Institute of Petroleum Industry, Tehran, Iran
E-mail:
A series of ionic liquids based on Octyl and Decyl methylimidazolium with different anions such as chloride, glycinate, dihydrogen phosphate and trihydrogen diphosphate, were synthesized and characterized by 1HNMR and elemental analysis. IL containing trihydrogen diphosphate anion, was synthesized for the first time. Physicochemical properties, including density, viscosity, surface tension, refractive index, and pH, were measured in temperature range 283.15 to 363.15 K and atmospheric pressure. The effects of temperature, alkyl chain, and anion type on physicochemical properties were investigated. The results revealed that the physicochemical properties decreased as a function of temperature. Unlike viscosity, other properties, such as density, surface tension, refractive index and pH values, decreased, while alkyl chain length increased. Understanding ILs properties and determining their unique abilities helps researchers to use them in new applications. These long alkyl chain ILs, are being used as surfactants to reduce Oil/Water interfacial tension in EOR process.
Keywords:Hydrophilic Ionic Liquids;Physicochemical Properties;1-Octyl3-methylimidazolium Based Ionic Liquids;Temperature Dependence
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