Synthesis of Poly(methyl methacrylate)/Graphene Oxide Nanocomposite Particles via Pickering Emulsion Polymerization and Their Viscous Response Under an Electric Field

Tae Hong Min; Hyoung Jin Choi

Macromolecular Research, Vol.25, No.6, 565-571, June, 2017

DOI10.1007/s13233-017-5109-6 Export Citation

Synthesis of Poly(methyl methacrylate)/Graphene Oxide Nanocomposite Particles via Pickering Emulsion Polymerization and Their Viscous Response Under an Electric Field

Tae Hong Min, and Hyoung Jin Choi^†

Department of Polymer Science and Engineering, Inha University, Incheon 22212, Korea

E-mail:

Poly(methyl methacrylate) (PMMA)/graphene oxide (GO) core-shell structured particles were fabricated by a Pickering emulsion polymerization method using the GO as a solid stabilizer. Their morphology and chemical bond were measured by transmission electron microscopy and Fourier transform infrared spectroscopy, respectively. The improved thermal stability of the GO-coated PMMA particles was also confirmed by thermogravimetric analysis. The fabricated particles were dispersed in silicone oil to produce an electrorheological (ER) fluid and their response to an electric field was analyzed in a controlled shear rate mode using a rotational rheometer under an applied electric field. The resulting ER fluid exhibited a typical ER behavior fitted well with both Bingham fluid and Sisko models, and well scaled using a modified Mason number.

Keywords:electrorheological fluid;core-shell;Pickering emulsion;graphene oxide;poly(methyl methacrylate)

[References]

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Chen H, Muller MB, Gilmore KJ, Wallace GG, Li D, Adv. Mater., 20(18), 3557 (2008)
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Kim J, Cote LJ, Kim F, Yuan W, Shull KR, Huang J, J. Am. Ceram. Soc., 132, 8180 (2010)
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Gudarzi MM, Sharif F, Soft Matter, 7, 3432 (2011)
Yin D, Geng W, Zhang Q, Zhang B, J. Ind. Eng. Chem., 31, 360 (2015)
Chen W, Liu X, Liu Y, Kim HI, Colloid Polym. Sci., 288, 1393 (2010)
Erdenedelger G, Dao TD, Jeong HM, J. Colloid Interface Sci., 476, 47 (2016)
Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
Zhang WL, Liu YD, Choi HJ, Kim SG, ACS Appl. Mater. Interfaces, 4, 2267 (2012)
Lee SG, Yoon CM, Hong YJ, Jang J, J. Mater. Chem., 2, 6010 (2014)
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Hwang JK, Shin K, Lim HS, Cho JC, Kim JW, Suh KD, Macromol. Res., 20(4), 391 (2012)
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Bitman L, Choi YT, Wereley NM, J. Intell. Mater. Syst. Struct., 13, 633 (2002)
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Slobodian P, Pavlinek V, Lengalova A, Saha P, Curr. Appl. Phys., 9(1), 184 (2009)
Zhang WL, Choi HJ, Soft Matter, 10, 6601 (2014)
Zhang K, Zhang WL, Choi HJ, Colloid Polym. Sci., 291, 955 (2013)
Zhang WL, Liu YD, Choi HJ, Seo Y, RSC Adv., 3, 11723 (2013)
Huang Y, Wang X, Jin X, Wang T, J. Therm. Anal. Calorim., 117, 755 (2014)
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Xie P, Ge X, Fang B, Li Z, Liang Y, Yang C, Colloid Polym. Sci., 291, 1631 (2013)
Suresh KI, Chindambaram K, Vinod V, Rajender N, Venkareswara RM, Miroslav C, Polym. Adv. Technol., 26, 214 (2015)
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Yang Y, Dan Y, Colloid Polym. Sci., 281, 794 (2003)
Feng L, Guan G, Li C, Zhang D, Xiao Y, Zheng L, Zhu W, J. Macromol. Sci.-Phys., 50, 720 (2013)
Kim SD, Zhang WL, Choi HJ, J. Mater. Chem., 2, 7541 (2014)
Dao TD, Erdenedelger G, Jeong HM, Polymer, 55, 4709 (2014)
Yin GN, Zheng Z, Wang HT, Du QG, Zhang HD, J. Colloid Interface Sci., 394, 192 (2013)
Stankovich S, Dikin DA, Piner RD, Kohlhass KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)
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Lee JH, Cho MS, Choi HJ, Jhon MS, Colloid Polym. Sci., 277, 73 (1999)
Liu YD, Choi HJ, Soft Matter, 8, 11961 (2012)
Marshall L, Zukoski CF, J. Chem. Soc.-Faraday Trans., 85, 2785 (1989)
Klingenberg DJ, J. Rheol., 51, 833 (2007)
Ramos-Tejada MM, Espin MJ, Perea R, Delgado AV, J. Non-Newton. Fluid Mech., 159(1-3), 34 (2009)
Seo YP, Choi HJ, Seo Y, Polymer, 52(25), 5695 (2011)

[Referenced By]

[1] Tkachev SV, Yu E. Buslaeva, Naumkin AV, Kotova SL, Laure IV, Gubin SP, Inorg. Mater., 48, 796 (2012)

[2] Chen H, Muller MB, Gilmore KJ, Wallace GG, Li D, Adv. Mater., 20(18), 3557 (2008)

[3] Shao JJ, Lv W, Yang QH, Adv. Mater., 26(32), 5586 (2014)

[4] Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)

[5] Kim J, Cote LJ, Kim F, Yuan W, Shull KR, Huang J, J. Am. Ceram. Soc., 132, 8180 (2010)

[6] Liu Y, Zhang Y, Duan L, Zhang W, Su M, Sun Z, Prog. Org. Coat., 99, 23 (2016)

[7] Gudarzi MM, Sharif F, Soft Matter, 7, 3432 (2011)

[8] Yin D, Geng W, Zhang Q, Zhang B, J. Ind. Eng. Chem., 31, 360 (2015)

[9] Chen W, Liu X, Liu Y, Kim HI, Colloid Polym. Sci., 288, 1393 (2010)

[10] Erdenedelger G, Dao TD, Jeong HM, J. Colloid Interface Sci., 476, 47 (2016)

[11] Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)

[12] Zhang WL, Liu YD, Choi HJ, Kim SG, ACS Appl. Mater. Interfaces, 4, 2267 (2012)

[13] Lee SG, Yoon CM, Hong YJ, Jang J, J. Mater. Chem., 2, 6010 (2014)

[14] Kim YD, Kim HS, Macromol. Res., 21(10), 1153 (2013)

[15] Hwang JK, Shin K, Lim HS, Cho JC, Kim JW, Suh KD, Macromol. Res., 20(4), 391 (2012)

[16] Choi HJ, Kim JW, To KW, Polymer, 40(8), 2163 (1999)

[17] Bitman L, Choi YT, Wereley NM, J. Intell. Mater. Syst. Struct., 13, 633 (2002)

[18] Davis LC, J. Appl. Phys., 81, 4 (1997)

[19] Slobodian P, Pavlinek V, Lengalova A, Saha P, Curr. Appl. Phys., 9(1), 184 (2009)

[20] Zhang WL, Choi HJ, Soft Matter, 10, 6601 (2014)

[21] Zhang K, Zhang WL, Choi HJ, Colloid Polym. Sci., 291, 955 (2013)

[22] Zhang WL, Liu YD, Choi HJ, Seo Y, RSC Adv., 3, 11723 (2013)

[23] Huang Y, Wang X, Jin X, Wang T, J. Therm. Anal. Calorim., 117, 755 (2014)

[24] Perrozzi F, Prezioso S, Ottaviano L, J. Phys. Condens. Matter, 27, 013002 (2015)

[25] Xie P, Ge X, Fang B, Li Z, Liang Y, Yang C, Colloid Polym. Sci., 291, 1631 (2013)

[26] Suresh KI, Chindambaram K, Vinod V, Rajender N, Venkareswara RM, Miroslav C, Polym. Adv. Technol., 26, 214 (2015)

[27] Singhal A, Dubey KA, Bhardwaj YK, Jain D, Choudhury S, Tyagi AK, RSC Adv., 3, 20913 (2013)

[28] Yang Y, Dan Y, Colloid Polym. Sci., 281, 794 (2003)

[29] Feng L, Guan G, Li C, Zhang D, Xiao Y, Zheng L, Zhu W, J. Macromol. Sci.-Phys., 50, 720 (2013)

[30] Kim SD, Zhang WL, Choi HJ, J. Mater. Chem., 2, 7541 (2014)

[31] Dao TD, Erdenedelger G, Jeong HM, Polymer, 55, 4709 (2014)

[32] Yin GN, Zheng Z, Wang HT, Du QG, Zhang HD, J. Colloid Interface Sci., 394, 192 (2013)

[33] Stankovich S, Dikin DA, Piner RD, Kohlhass KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)

[34] Denq BL, Hu YS, Chiu WY, Chen LW, Chiu YS, Polym. Degrad. Stabil., 57, 269 (1997)

[35] Lee JH, Cho MS, Choi HJ, Jhon MS, Colloid Polym. Sci., 277, 73 (1999)

[36] Liu YD, Choi HJ, Soft Matter, 8, 11961 (2012)

[37] Marshall L, Zukoski CF, J. Chem. Soc.-Faraday Trans., 85, 2785 (1989)

[38] Klingenberg DJ, J. Rheol., 51, 833 (2007)

[39] Ramos-Tejada MM, Espin MJ, Perea R, Delgado AV, J. Non-Newton. Fluid Mech., 159(1-3), 34 (2009)

[40] Seo YP, Choi HJ, Seo Y, Polymer, 52(25), 5695 (2011)