Fluorescence Behaviors of Metal Complexes/PVC Composites

Chenxi Fan; Yongyan Cui

Macromolecular Research, Vol.25, No.4, 357-364, April, 2017

DOI10.1007/s13233-017-5047-3 Export Citation

Fluorescence Behaviors of Metal Complexes/PVC Composites

Chenxi Fan, and Yongyan Cui^†

College of Chemical Engineering and Material, Tianjin University of Science and Technology, Tianjin 300457, P. R. China

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16 kinds of metal complexes were synthesized using ZnCl2, AlCl3, BiCl3, EuCl3, and ligands of 1,10- phenanthroline (phen), salicylic acid (Hsal) and 8-hydroxyquinoline (Oxin). Then metal complexes/polyvinyl chloride (PVC) composite thin films were produced using melt blending method with metal complexes and PVC resin as raw materials. The optimal addition ratio was obtained by changing the dosage of metal complexes. Fluorescence excitation and emission spectrum of metal complexes and the produced thin films were also investigated by thermogravimetric analysis (TG), fluorescence spectrum, transmissivity and haze test and tensile test. All the complexes show luminescent emissions in the solid phase.

Keywords:composite;thin films;metal complexes;fluorescence;polyvinyl chloride (PVC)

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[2] Jin J, Gong Y, Li L, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2, 137C (2015)

[3] Qian X, Xu Z, Chem. Soc. Rev., 14, 44 (2015)

[4] Redshaw C, Yong T, Chem. Soc. Rev., 12, 41 (2012)

[5] Raman N, Mahalakshmi R, Arun T, Packianathan S, J. Photochem. Photobiol. B-Biol., 1, 138 (2014)

[6] Noh SK, Wen LJ, Lee DH, Macromol. Res., 1, 12 (2004)

[7] Chen Z, Li X, Jin X, Shi L, Liu M, Macromol. Res., 9, 23 (2015)

[8] Brechin EK, Calucci L, Englert U, Margheriti L, Pampaloni G, Inorganica Chim. Acta, 8, 361 (2008)

[9] Wang G, He Y, Yang L, Qi B, J. Lumines., 10, 129 (2009)

[10] Gao B, Zhang W, Lei Q, Macromol. Res., 6, 21 (2013)

[11] Tian J, Guo JT, Li P, Zhang X, Chen ZK, Macromol. Res., 8, 17 (2009)

[12] Kornhauser A, Wei RR, Yamaguchi Y, Coelho SG, Kaidbey K, J. Dermatol. Sci., 1, 55 (2009)

[13] Cheng Y, Han X, Ouyang H, Rao Y, Chem. Commun., 23, 48 (2012)

[14] Sharma RP, Singh A, Brandao P, Felix V, Venugopalan P, Polyhedron, 17, 30 (2011)

[15] Nagesh GY, Raj KM, Mruthyunjayaswamy BHM, J. Mol. Struct., 423-432, 1079 (2014)

[16] Aladilee KJ, Abass AK, Taher AM, J. Mol. Struct., 457, 1108 (2015)

[17] Chan SO, Lee JY, Org. Electron., 5, 15 (2014)

[18] Yang N, Sun H, Coord. Chem. Rev., 17-20, 251 (2007)

[19] Roggan S, Limberg C, Cheminform, 13, 38 (2007)

[20] Yong HK, Baek NK, Oh JB, Macromol. Res., 3, 15 (2007)

[21] Bala M, Kumar S, Taxak VB, Boora P, Khatkar SP, J. Fluor. Chem., 6-13, 178 (2015)

[22] Yun MH, Yeon JW, Jin HJ, Lee HI, Ji MK, Macromol. Res., 5, 19 (2011)

[23] Zhang JL, Chen BW, Luo X, Du K, Chin. Chem. Lett., 8, 55 (2012)