Removal of mercury ions in a simulated wastewater using functionalized poly(glycidyl methacrylate)

Hyun Hee Kim; Tai Gyu Lee

Journal of Industrial and Engineering Chemistry, Vol.47, 446-450, March, 2017

DOI10.1016/j.jiec.2016.12.019 Export Citation

Removal of mercury ions in a simulated wastewater using functionalized poly(glycidyl methacrylate)

Hyun Hee Kim, and Tai Gyu Lee^†

Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea

E-mail:

Porous poly(glycidyl methacrylate) (PGMA) was prepared via water-in-oil (W/O) emulsion polymeriza-tion and was grafted with thiol groups. The removal of mercury (Hg) ions from water was evaluated using the functionalized PGMA. First, PGMA was synthesized and functionalized. Then, FTIR was used to assess the bonding of thiol groups with PGMA. SEM was used to analyze the porous characteristics of the material. To determine the effect of the pH on the Hg adsorption to functionalized PGMA, Hg adsorption tests were performed by varying the solution pH from 2 to 10. Additionally, a Hg adsorption test was performed by changing the initial Hg concentration.

Keywords:W/O;PGMA;Emulsion polymerization;L-cysteine;Thiol

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[Referenced By]

[1] Cho JH, Eom Y, Jeon SH, Lee TG, J. Ind. Eng. Chem., 19(1), 144 (2013)

[2] United Nations Environment Program, Minamata Convention on Mercury-Text and Annexes, (2013).

[3] Won JH, Lee JY, Chung D, Shin SK, Lee TG, J. Ind. Eng. Chem., 19(5), 1560 (2013)

[4] Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219 (2003)

[5] Kadirvelu K, Thamaraiselvi K, Namasivayam C, Bioresour. Technol., 76(1), 63 (2001)

[6] ShamsiJazeyi H, Kaghazchi T, J. Ind. Eng. Chem., 16(5), 852 (2010)

[7] Anirudhan TS, Sreekumari SS, J. Environ. Sci., 23, 1989 (2011)

[8] Gebremedhin-Haile T, Olguin MT, Solache-Rios M, Water Air Soil Pollut., 148, 179 (2003)

[9] Erdem E, Karapinar N, Donat R, J. Colloid Interface Sci., 280(2), 309 (2004)

[10] Mahmoud ME, Osman MM, Amer ME, Anal. Chim. Acta, 415, 33 (2000)

[11] Najafi M, Yousefi Y, Rafati AA, Sep. Purif. Technol., 85, 193 (2012)

[12] Davis TA, Volesky B, Mucci A, Water Res., 37, 4311 (2003)

[13] Saeed A, Akhter MW, Iqbal M, Sep. Purif. Technol., 45(1), 25 (2005)

[14] Abd El-Ghaffar MA, Mohamed MH, Elwakeel KZ, J. Chem. Eng., 151, 30 (2009)

[15] Aksu Z, Yener J, Waste Manage., 21, 695 (2001)

[16] Merrifield JD, Davids WG, MacRae JD, Amirbahman A, Water Res., 38, 3132 (2004)

[17] Hubicki Z, Kołodynska D, in: Kilislioglu A (Ed.), Ion Exchange Technologies, INTECH Open Access Publisher, Turkey, 2012, pp. 193.

[18] Shechter L, Wynstra J, Kurkjy RP, Ind. Eng. Chem., 48, 94 (1956)

[19] Han JX, Du ZJ, Zou W, Li HQ, Zhang C, J. Hazard. Mater., 276, 225 (2014)

[20] Caykara T, Cakar F, Demirci S, Polym. Int., 60, 141 (2011)

[21] Chowdhury A, Bhowal A, Datta S, Water, 4, 37 (2012)

[22] Alencastro RBD, Sandorfy C, Can. J. Chem., 50, 3594 (1972)

[23] McCarthy SA, Davies GL, Gun’ko YK, Nat. Protoc., 7, 1677 (2012)

[24] Lagadic IL, Mitchell MK, Payne BD, Environ. Sci. Technol., 35, 984 (2001)

[25] Mouaziz H, Lacki K, Larsson A, Sherrington DC, J. Mater. Chem., 14, 2421 (2004)

[26] Paez-Hernandez ME, Aguilar-Arteaga K, Galan-Vidal CA, Palomar-Pardave M, Romero-Romo M, Ramirez-Silva MT, Environ. Sci. Technol., 39, 7667 (2005)

[27] Dubinsky S, Zhang H, Nie ZH, Gourevich I, Voicu D, Deetz M, Kumacheva E, Macromolecules, 41(10), 3555 (2008)

[28] Kim M, Yoon SH, Choi E, Gil B, LWT-Food Sci. Technol., 41, 701 (2008)

[29] Clauss M, Tafin UF, Betrisey B, van Garderen N, Trampuz A, Ilchmann T, Bohner M, Eur. Cell Mater., 28, 39 (2014)

[30] Nisola GM, Limjuco LA, Vivas EL, Lawagon CP, Park MJ, Shon HK, Chung W, J. Chem. Eng., 280, 536 (2015)

[31] Ito Y, Ochiai Y, Park YS, Imanishi Y, J. Am. Chem. Soc., 119(7), 1619 (1997)

[32] Pieracci J, Wood DW, Crivello JV, Belfort G, Chem. Mater., 12, 2123 (2000)

[33] Denizli A, Kesenci K, Arica Y, Piskin E, React. Funct. Polym., 44, 235 (2000)

[34] Kadirvelu K, Kavipriya M, Karthika C, Vennilamani N, Pattabhi S, Carbohydr. Polym., 42, 745 (2004)

[35] Tuzun I, Bayramoglu G, Yalcin E, Basaran G, Celik G, Arica MY, J. Environ. Manage., 77, 85 (2005)

[36] Igwe JC, Abia AA, Ibeh CA, Int. J. Environ. Sci. Technol., 5, 83 (2008)