화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.47, 439-445, March, 2017
DOI10.1016/j.jiec.2016.12.018  Export Citation
Catalytic combustion of volatile organic compound over spherical-shaped copper.manganese oxide
Chi-Woong Ahn1, 2, Young-Woo You1, 3, Iljeong Heo1, 3, Ji Sook Hong1, 3, Jong-Ki Jeon2, Young-Deok Ko4, YoHan Kim5, Hosik Park6, †, and Jeong-Kwon Suh1, 3, †
  • 1Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu 305-600, Daejeon, Republic of Korea
  • 2Department of Chemical Engineering, KongJu National University, 56 Gongju-Si 314-701, ChungCheongNam-Do, Republic of Korea
  • 3, Korea
  • 4Puresphere, 105, Shinildong-ro, Daedeok-gu 343-24, Daejeon, Republic of Korea
  • 5School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagiro, Buk-gu 500-712, Gwangju, Republic of Korea
  • 6Advanced Materials Division,, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu 305-600, Daejeon, Republic of Korea
E-mail:,
Amorphous spherical-shaped copper.manganese oxide for the catalytic combustion of benzene were successfully obtained by a wet granulation process under different calcination temperatures. The low-temperature (400 °C) calcined catalysts-which showed a larger BET specific surface area, low temperature reducibility, and an amorphous phase-were more active for the catalytic combustion of benzene than the high-temperature calcined catalyst which underwent the amorphous to crystalline phase transition. The catalytic activity tests, depending on the operating parameters, suggested that amorphous spherical-shaped copper-manganese oxide have potential applications for remedying VOC pollution.
Keywords:Catalytic combustion;Volatile organic compound;Spherical-shape;Copper-manganese oxide
  1. Aguero FN, Barbero BP, Gambaro L, Cadus LE, Appl. Catal. B: Environ., 91(1-2), 108 (2009)
  2. Li G, Zhang Z, Sun H, Chen J, An T, Li B, J. Hazard. Mater., 250-251, 147 (2013)
  3. Genuino HC, Dharmarathna S, Njagi EC, Mei MC, Suib SL, J. Phys. Chem. C, 116, 12066 (2012)
  4. Larsson PO, Andersson A, Wallenberg LR, Svensson B, J. Catal., 163(2), 279 (1996)
  5. Gironi F, Piemonte V, Chem. Eng. J., 172(2-3), 671 (2011)
  6. Gupta VK, Verma N, Chem. Eng. Sci., 57(14), 2679 (2002)
  7. van der Vaart DR, Vatvuk WM, Wehe AH, J. Air Waste Manag. Assoc., 41, 92 (1991)
  8. Wang JD, Chen JM, Chem. Eng. J., 123(3), 103 (2006)
  9. Piumetti M, Fino D, Russo N, Appl. Catal. B: Environ., 163, 277 (2015)
  10. Kim SC, Nahm SW, Shim WG, Lee JW, Moon H, J. Hazard. Mater., 141(1), 305 (2007)
  11. Park SJ, Bae I, Nam IS, Cho BK, Jung SM, Lee JH, Chem. Eng. J., 195-196, 392 (2012)
  12. Maldonado-Hodar FJ, J. Hazard. Mater., 194, 216 (2011)
  13. Tidahy HL, Siffert S, Wyrwalski F, Lamonier JF, Aboukais A, Catal. Today, 119(1-4), 317 (2007)
  14. Liotta LF, Appl. Catal. B: Environ., 100(3-4), 403 (2010)
  15. Kim HS, Kim TW, Koh HL, Lee SH, Min BR, Appl. Catal. A: Gen., 280(2), 125 (2005)
  16. Li JJ, Li L, Cheng W, Wu F, Lu XF, Li ZP, Chem. Eng. J., 244, 59 (2014)
  17. Sager SM, Kondarides DI, Verykios XE, Appl. Catal. B: Environ., 103(3-4), 275 (2011)
  18. Li S, Wang H, Li W, Wu X, Tang W, Chen Y, Appl. Catal. B: Environ., 166-167, 260 (2015)
  19. Gu Z, Hohn KL, Ind. Eng. Chem. Res., 43(1), 30 (2004)
  20. Kim SC, J. Hazard. Mater., 91(1-3), 285 (2002)
  21. Zhou L, Zhang J, He JH, Hu YC, Tian H, Mater. Res. Bull., 46(10), 1714 (2011)
  22. Hettige C, Mahanama KRR, Dissanayake DP, Chemosphere, 43, 1079 (2001)
  23. Lahousse C, Bernier A, Grange P, Delmon B, Papaefthimiou P, Ioannides T, Verykios X, J. Catal., 178(1), 214 (1998)
  24. Larsson PO, Andersson A, Appl. Catal. B: Environ., 24(3-4), 175 (2000)
  25. Wang CH, Lin SS, Chen CL, Weng HS, Chemosphere, 64, 503 (2006)
  26. Saqer S, Kondarides D, Verykios X, Top. Catal., 52, 517 (2009)
  27. Yu D, Liu Y, Wu Z, Catal. Commun., 11, 788 (2010)
  28. Tsoncheva T, Issa G, Nieto JML, Blasco T, Concepcion P, Dimitrov M, Atanasova G, Kovacheva D, Microporous Mesoporous Mater., 180, 156 (2013)
  29. Delimaris D, Ioannides T, Appl. Catal. B: Environ., 89(1-2), 295 (2009)
  30. Karthik M, Lin LY, Bai H, Microporous Mesoporous Mater., 117, 153 (2009)
  31. Palacio LA, Silva ER, Catalao R, Silva JM, Hoyos DA, Ribeiro FR, Ribeiro MR, J. Hazard. Mater., 153(1-2), 628 (2008)
  32. Chen H, Tong XL, Li YD, Appl. Catal. A: Gen., 370(1-2), 59 (2009)
  33. Morales MR, Barbero BP, Cadus LE, Appl. Catal. B: Environ., 67(3-4), 229 (2006)
  34. Waskowska A, Gerward L, Olsen JS, Steenstrup S, Talik E, J. Phys. Condens. Matter, 13, 2549 (2001)
  35. Veprek S, Cocke DL, Kehl S, Oswald HR, J. Catal., 100, 250 (1986)
  36. Buciuman FC, Patcas F, Hahn T, Chem. Eng. Process., 38(4-6), 563 (1999)
  37. Kim PJ, You YW, Park H, Chang JS, Bae YS, Lee CH, Suh JK, Chem. Eng. J., 262, 683 (2015)
  38. Bazer-Bachi D, Assie L, Lecocq V, Harbuzaru B, Falk V, Powder Technol., 255, 52 (2014)
  39. Li WB, Zhuang M, Wang JX, Catal. Today, 137, 340 (2008)
  40. Kang M, Park ED, Kim JM, Yie JE, Catal. Today, 111(3-4), 236 (2006)
  41. Kim MH, Cho KH, Shin CH, Kang SE, Ham SW, Korean J. Chem. Eng., 28(4), 1139 (2011)
  42. Papavasiliou J, Avgouropoulos G, Ioannides T, J. Catal., 251(1), 7 (2007)
  43. Tang WX, Wu XF, Li SD, Shan X, Liu G, Chen YF, Appl. Catal. B: Environ., 162, 110 (2015)
  44. Tanaka Y, Utaka T, Kikuchi R, Takeguchi T, Sasaki K, Eguchi K, J. Catal., 215(2), 271 (2003)
  45. Tang XJ, Fei JH, Hou ZY, Zheng XM, Lou H, Energy Fuels, 22(5), 2877 (2008)
  46. Kramer M, Schmidt T, Stowe K, Maier WF, Appl. Catal. A: Gen., 302(2), 257 (2006)
  47. Veser G, Ziauddin M, Schmidt LD, Catal. Today, 47(1-4), 219 (1999)
  48. Wang CH, Lin SS, Chen CL, Weng HS, Chemosphere, 64, 503 (2006)