화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.47, 288-296, March, 2017
DOI10.1016/j.jiec.2016.11.045  Export Citation
On the use of infrared spectrometer as detector for Temperature Programmed (TP) techniques in catalysts characterization
Thanh Khoa Phung, and Gabriella Garbarino†
  • Department of Civil, Chemical and Environmental Engineering, Università degli Studi di Genova, P.le J.F. Kennedy 1, I-16129 Genova, Italy
E-mail:
IR spectrometer has been successfully applied as detector for temperature-programmed techniques, i.e. NH3-TPD and H2-TPR, demonstrating an excellent flexibility, robustness and effectiveness in the proposed study. IR allowed also to detect unexpected or coproduced compounds and to avoid in many cases the expensive coupling of different techniques. For NH3-TPD, a successful qualitative and quantitative determination has been achieved with an excellent signal/noise ratio and on materials characterized by different: Brønsted/Lewis acidity, thermal pretreatment, doping elements and oxidation activity. For H2-TPR, the reducibility of different supported Ni-based catalytic systems has been successfully investigated following vapor formation and identifying different Ni species.
Keywords:IR spectroscopy;NH3-TPD;H2-TPR;Temperature programmed techniques;Zeolite
  1. Niemantsverdriet JW, Spectroscopy in Catalysis: an Introduction, Wiley-VCH, 2007.
  2. Mekki-Berrada A, Auroux A, in: Che M, Vedrine JC (Eds.), Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2012, pp. 747.
  3. Busca G, Heterogeneous Catalytic Materials, Elsevier, 2014.
  4. Niwa M, Katada N, Chem. Rec., 13, 432 (2013)
  5. Katada N, Igi H, Kim J, Niwa M, J. Phys. Chem. B, 110, 5969 (1997)
  6. Trombetta M, Busca G, Lenarda M, Storaro L, Ganzerla R, Piovesan L, Lopez AJ, Alcantara-Rodriguez M, Rodriguez-Castellon E, Appl. Catal. A: Gen., 193(1-2), 55 (2000)
  7. Rodriguez-Castellon E, Jimenez-Lopez A, Maireles-Torres P, Jones DJ, Roziere J, Trombetta M, Busca G, Lenarda M, Storaro L, J. Solid State Chem., 175, 159 (2003)
  8. Flessner U, Jones DJ, Roziere J, Zajac J, Storaro L, Lenarda M, Pavan M, Jimenez-Lopez A, Rodriguez-Castellon E, Trombetta M, Busca G, J. Mol. Catal. A-Chem., 168(1-2), 247 (2001)
  9. Derouane EG, Vedrine JC, Pinto RR, Borges PM, Costa L, Lemos MANDA, Lemos F, Ribeiro FR, Catal. Rev.-Sci. Eng., 55(4), 454 (2013)
  10. Niwa M, Katada N, Okumura K, Characterization and Design of Zeolite Catalysts Solid Acidity, Shape Selectivity and Loading Properties, Series in Material Science, vol. 141, Springer, 2010.
  11. Karge HG, Dondur V, Weitkamp J, J. Phys. Chem., 95, 283 (1991)
  12. Hunger A, Szombathely MV, Z. Phys. Chem., 190, 19 (1995)
  13. Costa C, Lopes JM, Lemos F, Ribeiro FR, J. Mol. Catal. A-Chem., 144, 221 (1999)
  14. Lonyi F, Valyon J, Thermochim. Acta, 373(1), 53 (2001)
  15. Niwa M, Suzuki K, Katada N, Kanougi T, Atoguchi T, J. Phys. Chem. B, 109(40), 18749 (2005)
  16. Niwa M, Nishikawa S, Katada N, Microporous Mesoporous Mater., 82, 105 (2005)
  17. Pinto RR, Borges P, Lemos MANDA, Lemos F, Vedrine JC, Derouane EG, Ribeiro FR, Appl. Catal. A: Gen., 284(1-2), 39 (2005)
  18. Auroux A, Jin YS, Vedrine JC, Appl. Catal., 36, 323 (1988)
  19. Ramesh K, Hi LM, Han YF, Borgn A, Catal. Commun., 10, 567 (2009)
  20. Inaba M, Murata K, Takahara I, Inoue K, J. Chem. Technol. Biotechnol., 86(1), 95 (2011)
  21. Rodriguez-Gonzalez L, Simon U, Meas. Sci. Technol., 21, 027003 (2010)
  22. Hurst NW, Gentry SJ, Jones A, McNicol BD, Catal. Rev. Sci. Eng., 24, 233 (1982)
  23. Monti DA, Beaker A, J. Catal., 83, 323 (1983)
  24. Kapteijn F, Moulijn JA, Tarfaoui A, in: van Santen RA, van Leeuwen PWNM, Moulijn JA, Averlill BA (Eds.), Catalysis: an Integrated Approach, Elsevier, Amsterdam, 1999, pp. 525.
  25. Jankovic B, Adnadevic B, Mentus S, Chem. Eng. Sci., 63(3), 567 (2008)
  26. Kresnawahjuesa O, Gorte RJ, de Oliveira D, Lau LY, Catal. Lett., 82(3-4), 155 (2002)
  27. Gervasini A, Fenyvesi J, Auroux A, Catal. Lett., 43(3-4), 219 (1997)
  28. Garbarino G, Travi I, Pani M, Carnasciali MM, Busca G, Catal. Commun., 70, 77 (2015)
  29. Vu DV, Hirota Y, Nishiyama N, Egashira Y, Ueyama K, J. Japan Pet. Inst., 53, 232 (2010)
  30. Garbarino G, Riani P, Lucchini MA, Canepa F, Kawale S, Busca G, Int. J. Hydrog. Energy, 38(1), 82 (2013)
  31. Garbarino G, Valsamakis I, Riani P, Busca G, Catal. Commun., 51, 37 (2014)
  32. Strom L, Carlsson PA, Skoglundh M, Harelind H, Appl. Catal. B: Environ., 181, 403 (2016)
  33. Phung TK, Lagazzo A, Crespo MAR, Escribano VS, Busca G, J. Catal., 311, 102 (2014)
  34. Jimenez O, Muller TE, Schwieger W, Lercher JA, J. Catal., 239(1), 42 (2006)
  35. Phung TK, Carnasciali MM, Finocchio E, Busca G, Appl. Catal. A: Gen., 470, 72 (2014)
  36. Rodriguez-Gonzalez L, Hermes F, Bertmer M, Rodriguez-Castellon E, Jimenez-Lopez A, Simon U, Appl. Catal. A: Gen., 328(2), 174 (2007)
  37. Tavan Y, Nikou MRK, Shariati A, J. Ind. Eng. Chem., 20, 658 (2014)
  38. Hao K, Shen B, Wang Y, Ren J, J. Ind. Eng. Chem., 18(5), 1736 (2012)
  39. Hunger B, Hoffmann J, Heitzsch O, Hunger M, J. Therm. Anal., 36, 1379 (1990)
  40. Rac V, Rakic V, Stosic D, Otman O, Auroux A, Microporous Mesoporous Mater., 194, 126 (2014)
  41. Hong Y, Fripiat JJ, Microporous Mesoporous Mater., 4, 323 (1995)
  42. van der Bij HE, Aramburo LR, Arstad B, Dynes JJ, Wang J, Weckhuysen BM, Chem. Phys. Chem., 15, 283 (2014)
  43. van der Bij HE, Weckhuysen BM, Phys. Chem. Chem. Phys., 16, 9892 (2014)
  44. Phung TK, Radikapratama R, Garbarino G, Lagazzo A, Riani P, Busca G, Fuel Process. Technol., 137, 290 (2015)
  45. Barthos R, Lonyi F, Onyestyak G, Valyon J, Solid State Ion., 141-142, 253 (2001)
  46. Resini C, Montanari T, Nappi L, Bagnasco G, Turco M, Busca G, Bregani F, Notaro M, Rocchini G, J. Catal., 214(2), 179 (2003)
  47. Ramis G, Busca G, Lorenzelli V, Forzatti P, Appl. Catal., 64, 243 (1990)
  48. Garbarino G, Chitsazan S, Phung TK, Riani P, Busca G, Appl. Catal. A: Gen., 505, 86 (2015)
  49. Chang FW, Kuo MS, Tsay MT, Hsieh MC, J. Chem. Technol. Biotechnol., 79(7), 691 (2004)
  50. Li CP, Chen YW, Thermochim. Acta, 256(2), 457 (1995)
  51. Garbarino G, Riani P, Infantes-Molina A, Rodriguez-Castellon E, Busca G, Appl. Catal. A: Gen., 525, 180 (2016)
  52. Handyla BE, Jacobo A, Galindo MGC, Gonzalez M, LLanos ME, de Lourdes Guzman M, Hernandez F, Top. Catal., 19, 249 (2002)
  53. Hidalgo CV, Itoh H, Hattori T, Niwa M, Murakami Y, J. Catal., 85, 362 (1984)
  54. Yao W, Li J, Feng Y, Wang W, Zhang X, Chen Q, Komarneni S, Wang Y, RSC Adv., 5, 30485 (2015)
  55. Ramesh K, Jie C, Han YF, Borgna A, Ind. Eng. Chem. Res., 49(9), 4080 (2010)
  56. Wang BD, Manos G, Ind. Eng. Chem. Res., 46(24), 7977 (2007)
  57. Fan Y, Cai Y, Li X, Yin H, Xia J, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2016.10.024.
  58. Meng B, Zhao ZB, Wang XZ, Liang JJ, Qiu JS, Appl. Catal. B: Environ., 129, 491 (2013)
  59. Zhang QM, Song CL, Lv G, Bin F, Pang HT, Song JO, J. Ind. Eng. Chem., 24, 79 (2015)
  60. Zhang X, Shen B, Wang K, Chen J, J. Ind. Eng. Chem., 19(4), 1272 (2013)
  61. Tanimu G, Jermy BR, Asaoka S, Al-Khattaf S, J. Ind. Eng. Chem., doi:http://dx.doi.org/10.1016/j.jiec.2016.09.013., 45, 111 (2017)
  62. Wu H, Pantaleo G, Di Carlo G, Guo S, Marci G, Conception P, Venezia AM, Liotta LF, Catal. Sci. Technol., 5, 1888 (2015)
  63. Garbarino G, Bellotti D, Riani P, Magistri L, Busca G, Int. J. Hydrog. Energy, 40(30), 9171 (2015)
  64. Garbarino G, Bellotti D, Finocchio E, Magistri L, Busca G, Catal. Today, 277, 21 (2016)
  65. Mallet P, Caballero A, J. Chem. Soc.-Faraday Trans., 84, 2369 (1988)
  66. Garbarino G, Finocchio E, Lagazzo A, Valsamakis I, Riani P, Escribano VS, Busca G, Appl. Catal. B: Environ., 147, 813 (2014)
  67. Busca G, Riani P, Garbarino G, Ziemacki G, Gambino L, Montanari E, Millini R, Appl. Catal. A: Gen., 486, 176 (2014)
  68. Mile B, Stirling D, Zammitt MA, Lovell A, Webb M, J. Catal., 114, 217 (1988)
  69. Garbarino G, Wang C, Valsamakis I, Chitsazan S, Riani P, Finocchio E, Flytzani-Stephanopoulos M, Busca G, Appl. Catal. B: Environ., 200, 458 (2017)