Surface modification of PVDF membrane by radiation-induced graft polymerization for novel membrane bioreactor

In Hwan Shin; Seungkwan Hong; Seung Joo Lim; Youn-Suk Son; Tak-Hyun Kim

Journal of Industrial and Engineering Chemistry, Vol.46, 103-110, February, 2017

DOI10.1016/j.jiec.2016.10.020 Export Citation

Surface modification of PVDF membrane by radiation-induced graft polymerization for novel membrane bioreactor

In Hwan Shin^{1, 2}, Seungkwan Hong², Seung Joo Lim^{1, 3}, Youn-Suk Son^{1, 3}, and Tak-Hyun Kim^{1, 3, †}

¹Research Division for Industry & Environment, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup, Jeollabuk-do 56212, Republic of Korea
²Department of Civil, Environmental & Architectural Engineering, Korea University, 1-5 Ga, Anam-dong, Seoul 02841, Republic of Korea
³, Korea

E-mail:

PVDF (poly vinylidene fluoride) membrane was modified with glycidyl methacrylate (GMA) and sodium sulfite using a radiation-induced graft polymerization technique for unique ammonia removal process. Ion exchange capacities (IECs) of unmodified PVDF membrane, modified PVDF membrane and commercial cation exchange membrane (CEM) were investigated. The IEC value increased as the concentration of GMA increased. Batch experiments were carried out to evaluate the ion transport via the modified membrane. The mass flux of ammonia via the CEM and modified membrane at the initial ammonia concentration of 2000 mg/L were 1.16 mg-NH4+/m2 s and 2.89 mg-NH4+/m2 s, respectively.

Keywords:PVDF membrane;Membrane modification;Radiation grafting;Ion-exchange membrane bioreactor;Nitrogen removal

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Kulikowska D, Jozwiak T, Kowal P, Ciesielski S, Bioresour. Technol., 101(10), 3400 (2010)
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Chiu YC, Lee LL, Chang CN, Chao AC, Int. Biodeterior. Biodegrad., 59, 1 (2007)
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Peng DC, Bernet N, Delgenes JP, Moletta R, J. Chem. Technol. Biotechnol., 76(6), 553 (2001)
Wei D, Shi L, Yan T, Zhang G, Wang YF, Du B, Bioresour. Technol., 171, 211 (2014)
Jia WL, Liang S, Ngo HH, Guo WS, Zhang J, Wang R, Zou YN, Bioresour. Technol., 141, 123 (2013)
Zhang F, He Z, J. Chem. Technol. Biotechnol., 87(1), 153 (2012)
Hussain A, Manuel M, Tartakovsky B, J. Environ. Manage., 173, 23 (2016)
Park W, Nam YK, Lee MJ, Kim TH, Water Res., 43, 3820 (2009)
Lim SJ, Park W, Kim TH, Shin IH, Bioresour. Technol., 118, 163 (2012)
Khodabakhshi AR, Madaeni SS, Xu TW, Wu L, Wu C, Li C, Na W, Zolanvari SA, Babayi A, Ghasemi J, Hosseini SM, Khaledi A, Sep. Purif. Technol., 90, 10 (2012)
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Jing R, Yanqun Z, Jiuqiang L, Hongfei H, Radiat. Phys. Chem., 62, 277 (2001)
Madrid JF, Nuesca GM, Abad LV, Radiat. Phys. Chem., 85, 182 (2013)
Yuan Z, Dan-Li X, Desalination, 223(1-3), 438 (2008)
Lee WJ, Kim YJ, Jung MO, Kim DH, Cho DL, Kaang S, Synth. Met., 123, 327 (2001)
Li MZ, Li JH, Shao XS, Miao J, Wang JB, Zhang QQ, Xu XP, J. Membr. Sci., 405, 141 (2012)
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Israelachvili JN, Intermolecular and Surface Forces, revised third edition, Academic Press, 2011.
Karniadakis GE, Beskok A, Aluru N, Microflows and Nanoflows: Fundamentals and Simulation, Springer Science & Business Media, 2006.

[Referenced By]

[1] EPA, Addendum to “Ambient Water Quality Criteria for Ammonia-1984”, (1998).

[2] Zhang QL, Liu Y, Ai GM, Miao LL, Zheng HY, Liu ZP, Bioresour. Technol., 108, 35 (2012)

[3] Kulikowska D, Jozwiak T, Kowal P, Ciesielski S, Bioresour. Technol., 101(10), 3400 (2010)

[4] Zhang P, Qi Z, Front. Environ Sci. Eng. China, 1, 49 (2007)

[5] Chiu YC, Lee LL, Chang CN, Chao AC, Int. Biodeterior. Biodegrad., 59, 1 (2007)

[6] Reza M, Cuenca MA, J. Environ. Chem. Eng., 4, 130 (2016)

[7] Peng DC, Bernet N, Delgenes JP, Moletta R, J. Chem. Technol. Biotechnol., 76(6), 553 (2001)

[8] Wei D, Shi L, Yan T, Zhang G, Wang YF, Du B, Bioresour. Technol., 171, 211 (2014)

[9] Jia WL, Liang S, Ngo HH, Guo WS, Zhang J, Wang R, Zou YN, Bioresour. Technol., 141, 123 (2013)

[10] Zhang F, He Z, J. Chem. Technol. Biotechnol., 87(1), 153 (2012)

[11] Hussain A, Manuel M, Tartakovsky B, J. Environ. Manage., 173, 23 (2016)

[12] Park W, Nam YK, Lee MJ, Kim TH, Water Res., 43, 3820 (2009)

[13] Lim SJ, Park W, Kim TH, Shin IH, Bioresour. Technol., 118, 163 (2012)

[14] Khodabakhshi AR, Madaeni SS, Xu TW, Wu L, Wu C, Li C, Na W, Zolanvari SA, Babayi A, Ghasemi J, Hosseini SM, Khaledi A, Sep. Purif. Technol., 90, 10 (2012)

[15] Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination, 284, 191 (2012)

[16] Tang F, Chen G, Brow RK, Volz JS, Koenigstein ML, Corrosion Sci., 59, 157 (2012)

[17] Botelho G, Silva M, Goncalves A, Sencadas V, Serrado-Nunes J, Lanceros-Mendez S, Polym. Test, 27, 818 (2008)

[18] Yamaguchi T, Yamahara S, Nakao S, Kimura SJ, J. Membr. Sci., 95(1), 39 (1994)

[19] Poynton SD, Varcoe JR, Solid State Ion., 277, 38 (2015)

[20] O'Connell DW, Birkinshaw C, O'Dwyer TF, Bioresour. Technol., 99(15), 6709 (2008)

[21] Chakrabarty T, Jasti A, Goel N, Shahi VK, Sabharwal S, Radiat. Phys. Chem., 80, 803 (2011)

[22] Taeger A, Vogel C, Lehmann D, Jehnichen D, Komber H, Meier-Haack J, Ochoa NA, Nunes SP, Peinemann KV, React. Funct. Polym., 57(2-3), 77 (2003)

[23] Estrada-Villegas G, Bucio E, Radiat. Phys. Chem., 92, 61 (2013)

[24] Park J, Enomoto K, Yamashita T, Takagi Y, Todaka K, Maekawa Y, J. Membr. Sci., 438, 1 (2013)

[25] Nasef MM, Hegazy ESA, Prog. Polym. Sci, 29, 499 (2004)

[26] Aouadj S, Chapiro A, Die Angew. Makromol. Chem., 235, 73 (1996)

[27] Jing R, Yanqun Z, Jiuqiang L, Hongfei H, Radiat. Phys. Chem., 62, 277 (2001)

[28] Madrid JF, Nuesca GM, Abad LV, Radiat. Phys. Chem., 85, 182 (2013)

[29] Yuan Z, Dan-Li X, Desalination, 223(1-3), 438 (2008)

[30] Lee WJ, Kim YJ, Jung MO, Kim DH, Cho DL, Kaang S, Synth. Met., 123, 327 (2001)

[31] Li MZ, Li JH, Shao XS, Miao J, Wang JB, Zhang QQ, Xu XP, J. Membr. Sci., 405, 141 (2012)

[32] Yao C, Li XS, Neoh KG, Shi ZL, Kang ET, J. Membr. Sci., 320(1-2), 259 (2008)

[33] Yu HY, Xie Y, Hu MX, Wang JL, Wang SY, Xu ZK, J. Membr. Sci., 254(1-2), 219 (2005)

[34] Fu HY, Jia LD, Xu JP, J. Appl. Polym. Sci., 51(8), 1399 (1994)

[35] Masuelli MA, Grasselli M, Marchese J, Ochoa NA, J. Membr. Sci., 389, 91 (2012)

[36] Tuckerman ME, Marx D, Parrinello M, Nature, 417, 925 (2002)

[37] Israelachvili JN, Intermolecular and Surface Forces, revised third edition, Academic Press, 2011.

[38] Karniadakis GE, Beskok A, Aluru N, Microflows and Nanoflows: Fundamentals and Simulation, Springer Science & Business Media, 2006.