Pervap (TM) 2200, 2201, 2216, 2255, and 2510 hydrophilic, PVA membranes were investigated in pervaporation of water-tetrafluoropropanol mixtures. Physicochemical properties of membranes were characterized by determining the contact angle (CA) of water and glycerol and the surface free energy (SFE). The separation and transport properties of membranes were determined during vacuum pervaporation in contact with water-TFP mixtures containing up to 22 wt.% water. It was found that all membranes were hydrophilic (CA < 90 degrees) and the polar component of SFE was much higher than the dispersive one. The apparent activation energy for water transport was very high (E-app = 81.3 kJ/mol), indicated that water transport is activated thermally. Pervap (TM) membranes were very selective during the dehydration process of TFP. In contact with the Pervap (TM) 2200, 2201, and 2216 permeate contained practically pure water, regardless the feed composition. The process separation index (PSI) for Pervap (TM) 2200 and 2216 was close to 5000 kg m(-2) h(-1), suggesting that both membranes can be efficiently applied in the batch pervaporation process for TFP dehydration. (C) 2016 Elsevier B.V. All rights reserved.