화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.33, No.10, 2953-2960, October, 2016
Experimental investigation of nanofibrous poly(vinylidene fluoride) membranes for desalination through air gap membrane distillation process
E-mail:,
A comparative study was conducted to evaluate the performance of two membrane types of electrospun poly(vinylidene fluoride) (PVDF) and commercial ploytetrafluoroethylene (PTFE). The optimized needleless electrospinning technique was used to prepare PVDF membranes. Scanning electron microscopy (SEM), wettability tests, water flux, mechanical strength and liquid entry pressure (LEP) measurements were performed to evaluate the prepared membrane. Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our nanofibrous PVDF membrane presents higher water permeation flux (>20 kg/m2 h) compared to commonly used PTFE. In addition, the experimental data confirms that competitive salt rejection efficiency (>99.8%) was obtained in this new membrane.
  1. El-Zanati E, El-Khatib KM, Desalination, 205(1-3), 15 (2007)
  2. Xu Y, Zhu BK, Xu YY, Desalination, 189(1-3), 165 (2006)
  3. Gryta M, Tomaszewska M, Grzechulska J, Morawski AW, J. Membr. Sci., 181(2), 279 (2001)
  4. Hofman-Bieniek M, Jasiewicz K, Pietrzak R, Korean J. Chem. Eng., 31(2), 304 (2014)
  5. Lawson KW, Lloyd DR, J. Membr. Sci., 124(1), 1 (1997)
  6. El-Bourawi MS, Ding Z, Ma R, Khayet M, J. Membr. Sci., 285(1-2), 4 (2006)
  7. Cath TY, Adams VD, Childress AE, J. Membr. Sci., 228(1), 5 (2004)
  8. Izquierdo-Gil MA, Garcia-Payo MC, Fernandez-Pineda C, J. Membr. Sci., 155(2), 291 (1999)
  9. Koros WJ, Ma YH, Shimidzu T, J. Membr. Sci., 120(2), 149 (1996)
  10. Guijt CM, Meindersma GW, Reith T, de Haan AB, Sep. Purif. Technol., 43(3), 233 (2005)
  11. Schofield RW, Fane AG, Fell CJD, Macoun R, Desalination, 77, 279 (1990)
  12. Schofield RW, Fane AG, Fell CJD, J. Membr. Sci., 53, 159 (1990)
  13. Uragami T, Fujimoto M, Sugihara M, Desalination, 34, 311 (1980)
  14. Khayet M, Feng CY, Khulbe KC, Matsuura T, Polymer, 43, 2879 (2002)
  15. Mulder M, Basic principles of membrane technology, First Ed., Kluwer Academic Publishers, Dordrecht (1996).
  16. Moradi R, Karimi-Sabet J, Shariaty-Niassara M, Amini Y, Chem. Eng. Process., 100, 26 (2016)
  17. Moradi R, Karimi-Sabet J, Shariaty-Niassar M, Koochaki MA, Polymers, 7, 1444 (2015)
  18. Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S, Compos. Sci. Technol., 63, 2223 (2003)
  19. Feng C, Khulbe KC, Matsuura I, Gopal R, Kaur S, Rarnakrishna S, Khayet A, J. Membr. Sci., 311(1-2), 1 (2008)
  20. Wu D, Huang X, Lai X, Sun D, Lin L, J. Nanosci. Nanotechnol., 10, 4221 (2010)
  21. Niu HT, Lin T, Wang XG, J. Appl. Polym. Sci., 114(6), 3524 (2009)
  22. Liu F, Hashim NA, Liu YT, Abed MRM, Li K, J. Membr. Sci., 375(1-2), 1 (2011)
  23. Ma Y, Su Y, Li Y, Jiang Z, Korean J. Chem. Eng., 32(9), 1902 (2015)
  24. Hendren ZD, Brant J, Wiesner MR, J. Membr. Sci., 331(1-2), 1 (2009)
  25. Essalhi M, Khayet M, J. Membr. Sci., 433, 167 (2013)
  26. Mulder M, Basic principles of membrane technology, First Ed., Kluwer Academic Publishers, Dordrecht (1996).
  27. Fan HW, Peng YL, Chem. Eng. Sci., 79, 94 (2012)
  28. Phattaranawik J, Jiraratananon R, Fane AG, J. Membr. Sci., 215(1-2), 75 (2003)
  29. Cheng DY, Wiersma SJ, US Patent, 4,419,242 (1983).
  30. Niu HT, Lin T, Wang XG, J. Appl. Polym. Sci., 114(6), 3524 (2009)
  31. Fujii Y, Kigoshi S, Iwatani H, Aoyama M, Fusaoka Y, J. Membr. Sci., 72, 73 (1992)
  32. Feng C, Khulbe KC, Matsuura I, Gopal R, Kaur S, Rarnakrishna S, Khayet A, J. Membr. Sci., 311(1-2), 1 (2008)
  33. Burger C, Hsiao BS, Chu B, Ann. Rev. Mater. Res., 36, 333 (2006)
  34. Zhao ZZ, Li JQ, Yuan XY, Li X, Zhang YY, Sheng J, J. Appl. Polym. Sci., 97(2), 466 (2005)
  35. Wang R, Liu Y, Li B, Hsiao BS, Chu B, J. Membr. Sci., 392, 167 (2012)
  36. Essalhi M, Khayet M, J. Membr. Sci., 433, 167 (2013)
  37. Fujii Y, Kigoshi S, Iwatani H, Aoyama M, J. Membr. Sci., 72, 53 (1992)