화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.38, 73-81, June, 2016
DOI10.1016/j.jiec.2016.04.005  Export Citation
Large-scale production of (2,4-DHB)nM micro-nano spheres by spray drying and their application as catalysts for ammonium perchlorate
Wen-yuan Zhao, Tong-lai Zhang†, Li Yang, Li-nong Zhang1, and Zun-ning Zhou
  • State Key Laboratory of Explosion Science & Technology, Beijing Institute of Technology, No. 5, Zhongguancun South Street, Beijing 100081, China
  • 1Innovative Precision Machinery Manufacturing Co., Ltd., Fushun, Fushun 113103, China
E-mail:
A series of 2,4-dihydroxybenzoates {(2,4-DHB)nMs, M = Pb(II), Cu(II), Fe(III), Ni(II) and Co(II), n = 2 or 3} micro-nano spheres with controllable size and morphology were successfully prepared by spray drying method with water or acetone as a solvent. TEM and SEM illustrated that the (2,4-DHB)nMs micro-nano spheres had core.shell or solid structure. The formation of the core.shell structure of the samples was interpreted in terms of the mechanism of spray drying. The results of laser particle analyzer revealed that precursor concentration (PC) and particle size distribution (PSD) of the samples were well fitted with power function. The thermal decomposition of ammonium perchlorate (AP) in the presence of the (2,4-DHB)nMs micro-nano spheres, investigated by differential scanning calorimetry (DSC), showed they effectively lowered the decomposition temperature of AP and exhibited various catalytic performance for AP decomposition.
Keywords:Spray drying;Nanostructure;Particle size;Catalysis;Differential scanning calorimetry
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