화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.38, 82-92, June, 2016
DOI10.1016/j.jiec.2016.04.009  Export Citation
Graphene oxide/poly(imidazole/imidazolium) nanocomposite:An effective support for immobilization of large amounts of Pd nanoparticles
Ali Pourjavadi, Niloofar Safaie, Seyed Hassan Hosseini, and Craig Bennett1
  • Polymer Research Laboratory, Department of Chemistry, Sharif University of Technology, Tehran, Iran
  • 1Department of Physics, Acadia University, Wolfville, Nova Scotia, Canada
A multi-layered catalyst based on poly(imidazole/imidazolium) and graphene oxide, with high loading capacity for immobilization of palladium nanoparticles was prepared. The catalyst was proven to be highly efficient for reduction of nitroarenes and also for Heck reaction with the use of only 0.1 mol% of the catalyst. The reduction of nitroarenes and Heck reaction were performed in water medium and excellent yields of products were achieved. The synthesized catalyst was readily recovered and reused for up to 10 subsequent runs without significant loss of activity.
Keywords:Graphene oxide;Pd catalyst;Reduction;Heck reaction
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