Korean Journal of Chemical Engineering, Vol.33, No.4, 1362-1368, April, 2016
Pilot-scale study on dehydration of synthetic and lignocellulosic ethanol by NaA membrane
E-mail:,
A pilot scale vapor permeation unit was assembled to study the dehydration of bioethanols with NaA membrane. The operational parameters, such as feed concentration, temperature, and downstream pressure in permeate, were varied. Long-term operation of an ethanol dehydration unit was demonstrated. Additionally, the lingocellulosic ethanol distillate was dehydrated to fuel grade ethanol with less than 1% water content. The changes in impurities, such as methanol, ethylacetate, 2-propanol, 1-propanol, 1-butanol, and Isoamyl alcohol, were dependent on the volatility of the compounds. The ethanol concentrations in the permeate stream were lower than 1%, indicating high separation performance of the membrane system.
- Gnansounou E, Dauriat A, Bioresour. Technol., 101(13), 4980 (2010)
- Menon V, Rao M, Prog. Energy Combust. Sci., 38(4), 522 (2012)
- Klinpratoom B, Ontanee A, Ruangviriyachai C, Korean J. Chem. Eng., 32(3), 413 (2015)
- Weng YH, Huang HC, Guo GL, Hwang WS, J. Energy Power Eng., 5, 928 (2011)
- Lim JS, Manan ZA, Alwi SRW, Hashim H, Renew. Sust. Energ. Rev., 16, 3084 (2012)
- Khan S, Ul-Islam M, Khattak WA, Ullah MW, Yu B, Park JK, Korean J. Chem. Eng., 32(4), 694 (2015)
- Huang HJ, Ramaswamy S, Tschirner UW, Ramarao BV, Sep. Purif. Technol., 62(1), 1 (2008)
- CNS 15109, Denatured fuel ethanol for blending with gasolines for use as automotive spark-ignition engine fuel (2007).
- Baker RW, In Membrane Technology and Applications, 2nd Ed., Baker RW, Ed., John Wiley & Sons Ltd.: West Sussex (2004).
- Jiang LY, Wang Y, Chung TS, Qiao XY, Lai JY, Prog. Polym. Sci, 34, 1135 (2009)
- Wee SL, Tye CT, Bhatia S, Sep. Purif. Technol., 63(3), 500 (2008)
- Vane LM, Sep. Sci. Technol., 48(3), 429 (2013)
- Peng P, Shi BL, Lan YQ, Sep. Sci. Technol., 46(2), 234 (2011)
- Morigami Y, Kondo M, Abe J, Kita H, Okamoto K, Sep. Purif. Technol., 25(1-3), 251 (2001)
- Caro J, Noack M, Kolsch P, Adsorpt.-J. Int. Adsorpt. Soc., 11, 215 (2005)
- Richter H, Voigt I, Kuhnert JT, Desalination, 199(1-3), 92 (2006)
- Sato K, Sugimoto K, Nakane T, J. Membr. Sci., 307(2), 181 (2008)
- Shafiei K, Pakdehi SG, Moghaddam MK, Mohammadi T, Sep. Sci. Technol., 49(6), 797 (2014)
- Li HZ, Wang JQ, Xu J, Meng XD, Xu B, Yang JH, Li SY, Lu JM, Zhang Y, He XL, Yin DH, J. Membr. Sci., 444, 513 (2013)
- Abels C, Carstensen F, Wessling M, J. Membr. Sci., 444, 285 (2013)
- Reddy LV, Reddy LP, Wee YJ, Reddy OVS, Food Bioprocess Technol., 4, 142 (2011)
- Fadeev AG, Kelley SS, McMillan JD, Selinskaya YA, Khotimsky VS, Volkov VV, J. Membr. Sci., 214(2), 229 (2003)
- Chen WH, Tsai CC, Lin CF, Tsai PY, Hwang WS, Bioresour. Technol., 128, 297 (2013)
- Lin TH, Huang CF, Guo GL, Hwang WS, Huang SL, Bioresour. Technol., 116, 314 (2012)
- Inocermic GmbH company, http://www.ikts.fraunhofer.de/en/research_fields/Environmental_EngineeringandBioenergy/biofuels. html (2014).
- Weng YH, Tsai TY, Wei HJ, TW M425125 (2011).
- Baker RW, Wijmans JG, Huang Y, J. Membr. Sci., 348(1-2), 346 (2010)
- Zah J, Krieg HM, Breytenbach JC, J. Membr. Sci., 284(1-2), 276 (2006)
- Wang JH, Tsuru T, J. Membr. Sci., 369(1-2), 13 (2011)
- Cho CH, Oh KY, Kim SK, Yeo JG, Lee YM, J. Membr. Sci., 366(1-2), 229 (2011)
- Okamoto K, Kita H, Horii K, Tanaka K, Kondo M, Ind. Eng. Chem. Res., 40(1), 163 (2001)
- Sommer S, Melin T, Chem. Eng. Sci., 60(16), 4509 (2005)
- Niemisto J, Pasanen A, Hirvela K, Myllykoski L, Muurinen E, Keiski RL, J. Membr. Sci., 447, 119 (2013)
- Osorio-Viana W, Quintero-Arias JD, Dobrosz-Gomez I, Fontalvo J, Gomez-Garcia MA, Desalin. Water Treat., 51, 2377 (2013)
- Styarinia D, Aristiawana Y, Auliaa F, Abimanyua H, Sudiyania Y, Energy Procedia, 32, 153 (2013)