화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 278-285, February, 2016
DOI10.1016/j.jiec.2015.11.020  Export Citation
Synthesis and characterization of magnetic metal-organic framework for the adsorptive removal of Rhodamine B from aqueous solution
Haochi Liu, Xiaohui Ren, and Ligang Chen†
  • Department of Chemistry, College of Science, Northeast Forestry University, 26 Hexing Road, Harbin 150040, China
E-mail:
Adsorptive removal of Rhodamine B (RhB) on a novel kind of magnetic metal.organic framework (MOF) was studied in view of adsorption isotherm, thermodynamics and kinetics. The adsorbent was characterized by physical property measurement system, X-ray diffraction and scanning electron microscopy. The adsorption isotherm of RhB on magnetic MOF followed the Freundlich model. The resultant kinetics data was well described by the pseudo-second-order model. Most of the RhB was removed from the aqueous solution within 30 min. Thermodynamic parameters including Gibbs free energy, enthalpy, and entropy of adsorption were obtained. The result confirmed that the adsorption is controlled by an entropy effect rather than an enthalpy change. The maximum removal has been achieved in the pH range of 4-8 at 150 rpm. The sorbent can be used at least five times after washing with methanol including HCl (0.001 mol L-1). The ∏-∏stacking interaction and electrostatic interaction may play an important role in the adsorption of RhB onto magnetic MOF. Compared with other adsorbents, this kind of magnetic material demonstrated a superior dye adsorption capability.
Keywords:Metal-organic framework (MOF);Rhodamine B;Magnetic separation;Adsorption remove;Water treatment
  1. Nagaraja R, Kottam N, Girija CR, Nagabhushana BM, Powder Technol., 215-216, 91 (2012)
  2. Kaur S, Rani S, Kumar V, Mahajan RK, Asif M, Tyagi I, Gupta VK, J. Ind. Eng. Chem., 26, 234 (2015)
  3. Hamed MM, Ahmed IM, Metwally SS, J. Ind. Eng. Chem., 20(4), 2370 (2014)
  4. Shirzad-Siboni M, Khataee A, Joo SW, J. Ind. Eng. Chem., 20(2), 610 (2014)
  5. Canizares P, Martınez F, Jimenez C, Lobato J, Rodrigo MA, Environ. Sci. Technol., 40, 6418 (2006)
  6. Liu MX, Gan LH, Pang YC, Xu ZJ, Hao ZX, Chen LW, Colloids Surf. A: Physicochem. Eng. Asp., 317, 490 (2008)
  7. Kornaros M, Lyberatos G, J. Hazard. Mater., 136(1), 95 (2006)
  8. Lindberg RH, Olofsson U, Rendahl P, Johansson MI, Tysklind M, Andersson BAV, Environ. Sci. Technol., 40, 1042 (2005)
  9. Selvam PP, Preethi S, Basakaralingam P, Thinakaran N, Sivasamy A, Sivanesan S, J. Hazard. Mater., 155(1-2), 39 (2008)
  10. Kadirvelu K, Karthika C, Vennilamani N, Pattabhi S, Chemosphere, 60, 1009 (2005)
  11. Chang SH, Wang KS, Li HC, Wey MY, Chou JD, J. Hazard. Mater., 172(2-3), 1131 (2009)
  12. James SL, Chem. Soc. Rev., 32, 276 (2003)
  13. Rowsell JLC, Yaghi OM, Microporous Mesoporous Mater., 73, 3 (2004)
  14. Ferey G, Chem. Soc. Rev., 37, 191 (2008)
  15. Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)
  16. Cychosz KA, Ahmad R, Matzger AJ, Chem. Sci., 1, 293 (2010)
  17. Anbia M, Hoseini V, Sheykhi S, J. Ind. Eng. Chem., 18, 151 (2012)
  18. Melgar VMA, Kim J, Othman MR, J. Ind. Eng. Chem., 28, 1 (2015)
  19. Hamon L, Serre C, Devic T, Loiseau T, Millange F, Ferey G, De Weireld G, J. Am. Chem. Soc., 131(25), 8775 (2009)
  20. Khan NA, Jun JW, Jeong JH, Jhung SH, Chem. Commun., 47, 1306 (2011)
  21. Haque E, Jun JW, Jhung SH, J. Hazard. Mater., 185, 507 (2011)
  22. Jhung SH, Lee JH, Yoon JW, Serre C, Ferey G, Chang JS, Adv. Mater., 19(1), 121 (2007)
  23. Kim J, Lee JE, Lee J, Yu JH, Kim BC, An K, Hwang Y, Shin CH, Park JG, Kim J, Hyeon T, J. Am. Chem. Soc., 128(3), 688 (2006)
  24. Bastami TR, Entezari MH, Chem. Eng. J., 210, 510 (2012)
  25. Sun X, Ou H, Miao C, Chen L, J. Ind. Eng. Chem., 22, 373 (2015)
  26. Kumar R, Barakat MA, Soliman EM, J. Ind. Eng. Chem., 20(5), 2992 (2014)
  27. Hu YL, Huang ZL, Liao J, Li GK, Anal. Chem., 85, 6885 (2013)
  28. Huo SH, Yan XP, Analyst, 137, 3445 (2012)
  29. Kim PJ, You YW, Park H, Chang JS, Bae YS, Lee CH, Suh JK, Chem. Eng. J., 262, 683 (2015)
  30. Zhang FM, Shi J, Jin Y, Fu YH, Zhong YJ, Zhu WD, Chem. Eng. J., 259, 183 (2015)
  31. Gao L, Chen LG, Microchim. Acta, 180, 423 (2013)
  32. Bhattacharyya KG, SenGupta S, Sarma GK, Appl. Clay Sci., 99, 7 (2014)
  33. Huo SH, Yan XP, J. Mater. Chem., 22, 7449 (2012)
  34. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  35. Freundlich HMF, Z. Phys. Chem., 57A, 385 (1906)
  36. Wen DH, Ho YS, Tang XY, J. Hazard. Mater., 133(1-3), 252 (2006)
  37. Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
  38. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  39. Ho YS, McKay G, J. Environ. Sci. Health Part B-Pestic. Food Contam. Agric. Wastes, 76(B2), 183 (1998)
  40. Li YH, Di ZC, Ding J, Wu DH, Luan ZK, Zhu YQ, Water Res., 39, 605 (2005)
  41. Khan TA, Dahiya S, Ali I, Appl. Clay Sci., 69, 58 (2012)
  42. Al-Rashed SM, Al-Gaid AA, J. Saudi. Chem. Soc., 16, 209 (2012)
  43. Sureshkumar MV, Namasivayam C, Colloids Surf. A: Physicochem. Eng. Asp., 317, 277 (2008)
  44. Khan TA, Sharma S, Ali I, J. Toxicol. Environ. Heal. Sci., 3, 286 (2011)
  45. Huang JH, Huang KL, Liu SQ, Wang AT, Yan C, Colloids Surf. A: Physicochem. Eng. Asp., 330, 55 (2008)