Introduction of reversible crosslinker into artificial marbles toward chemical recyclability

Seongjun Moon; Jaewon Shin; Sang-Ho Cha; Yoonseok Shin; Kyung Jin Lee

Journal of Industrial and Engineering Chemistry, Vol.31, 86-90, November, 2015

DOI10.1016/j.jiec.2015.06.011 Export Citation

Introduction of reversible crosslinker into artificial marbles toward chemical recyclability

Seongjun Moon, Jaewon Shin, Sang-Ho Cha¹, Yoonseok Shin², and Kyung Jin Lee^†

Department of Fine Chemical Engineering and Applied Chemistry, College of Engineering, Chungnam National University, 99 Daehak-ro (st), Yuseong-gu, Daejeon, 305-764, Republic of Korea
¹Department of Chemical Engineering, Kyonggi University, Suwon 443-760, Republic of Korea
²Department of Plant and Architectural Engineering, Kyonggi University, Suwon 443-760, Republic of Korea

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Organic/inorganic composites containing thermally breakable crosslinker were prepared for exploring the possibility in fabrication of recyclable artificial marble composed of acrylic resin and aluminum hydroxide. The breakable crosslinker was fabricated using Diels.Alder reaction from furfuryl methacrylate and bismaleimide. De-crosslinking reaction was also triggered by retro-Diels.Alder reaction. The basic properties of artificial marbles fabricated by breakable crosslinker, i.e chemical, thermal, mechanical and coloring properties, are compared to that of conventional one, which is based on unbreakable crosslinker.

Keywords:Organic-inorganic composite;Diels-Alder reaction;Self-healing;Reversible crosslinker;Artificial marble

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[3] Chang YH, Huang PH, Wu BY, Chang SW, Constr. Build. Mater., 83, 1 (2015)

[4] Zhao J, Rock Mechanics in Civil and Environmental Engineering, CRC Press, London, 2010.

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[7] Riddle H, Monomeric Acrylic Esters, Reinhold Publishing Co., New York, NY, 1954.

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[12] Montero MA, Jordan MM, Hernandez-Crespo MS, Sanfeliu T, Appl. Clay Sci., 46, 404 (2009)

[13] Acchar W, Vieira FA, Hotza D, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 419, 306 (2006)

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[20] Kavitha AA, Singha NK, ACS Appl. Mater. Interfaces, 1, 1427 (2009)

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[24] Nicolaou KC, Snyder SA, Montagnon T, Vassilikogiannakis G, Angew. Chem.-Int. Edit., 10, 1668 (2002)

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[32] Salamone JC, Polymeric Materials Encyclopedia, CRC Press, New York, NY, 1996.

[33] Kutz M, Mechanical Engineers’ Handbook, Materials and Engineering Mechanics, John Wiley & Sons, New York, NY, 2015.