Chemical surface modification of lignin particle and its application as filler in the polypropylene composites

Jun-Seok Yeo; Dong-Wook Seong; Seok-Ho Hwang

Journal of Industrial and Engineering Chemistry, Vol.31, 80-85, November, 2015

DOI10.1016/j.jiec.2015.06.010 Export Citation

Chemical surface modification of lignin particle and its application as filler in the polypropylene composites

Jun-Seok Yeo, Dong-Wook Seong, and Seok-Ho Hwang^†

Department of Polymer Science & Engineering, Center for Photofunctional Energy Materials, Dankook University, Yongin, Gyeonggi 448-701, Republic of Korea

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The pristine lignin was chemically modified by hydrolysis condensation reaction using (3-aminopropyl) triethoxysilane and then was subsequently treated with polypropylene-graft-maleic anhydride to give MAPP anchored lignin (MAPP-a-Lignin). The modified lignin particles prepared at each steps were characterized by FT-IR, SEM-EDX and XPS measurements. Polypropylene composites with MAPP-a-Lignin were prepared through melt-blending method. In this work, the effects of content of MAPP-a-Lignin on the properties of the polypropylene composites were investigated. From the results of mechanical properties, melting/crystallization behaviors and the morphologies of the composites, it was found that there was a stronger interfacial interaction between MAPP-a-Lignin and polypropylene in the composites.

Keywords:Lignin;Surface modification;Polypropylene;Composite;Filler

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Ichazo MN, Albano C, Gonzalez J, Perera R, Candal MV, Compos. Struct., 54, 207 (2001)
Lisperguer J, Perez P, Urizar SJ, Child. Chem. Soc., 54, 460 (2009)
Kazayawoko M, Balatinecz JJ, Woodhams RT, Sodhi RNS, J. Wood Chem. Technol., 18, 1 (1998)
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[3] Lora JH, Glasser WG, J. Polym. Environ., 10, 39 (2002)

[4] Goncalves AR, Benar P, Bioresour. Technol., 79(2), 103 (2001)

[5] De Paoli MA, Furlan LT, Polym. Degrad. Stabil., 13, 129 (1985)

[6] Kosikova B, Demianova V, Kakurakova M, J. Appl. Polym. Sci., 47, 1065 (1993)

[7] Kosikova B, Miklesova K, Demianova V, Eur. Polym. J., 29, 1495 (1993)

[8] Rozman HD, Tan KW, Kumar RN, Abubakar A, Ishak Mohd ZA, Ismai H, Eur. Polym. J., 36, 1483 (2000)

[9] Morandim-Giannetti AA, Agnelli JAM, Lancas BZ, Magnabosco R, Casarin SA, Bettini SHP, Carbohydr. Polym., 87, 2563 (2012)

[10] Simionescu CI, Macoveanu MM, Vasile C, Ciobanu F, Esanu M, Ioanid A, Vidrascu P, Georgesc-Buruntea N, Cell Chem. Technol., 30, 411 (1996)

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[12] Kharade AY, Kale DD, J. Appl. Polym. Sci., 72(10), 1321 (1999)

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