A novel selective H2S sensor using dodecylamine and ethylenediamine functionalized graphene oxide

M. Malek Alaie; M. Jahangiri; A.M. Rashidi; A. Haghighi Asl; N. Izadi

Journal of Industrial and Engineering Chemistry, Vol.29, 97-103, September, 2015

DOI10.1016/j.jiec.2015.03.021 Export Citation

A novel selective H2S sensor using dodecylamine and ethylenediamine functionalized graphene oxide

M. Malek Alaie, M. Jahangiri^†, A.M. Rashidi¹, A. Haghighi Asl, and N. Izadi¹

Faculty of Chemical, Petroleum and Gas Eng, Semnan University, P.O. Box 35196-45399, Semnan, Iran
¹Nano Technology Center, Research Institute of Petroleum Industry (RIPI), P.O. Box 14665-1998, Tehran, Iran

E-mail:

Dodecylamine (DDA) and ethylenediamine (EDA) functionalized graphene oxide (GO) nanosensors were synthesized by amidation methods and characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM). The results showed that compared to pristine GO-based sensor, the DDA-GO and EDA-GO chemiresistors have a significant response to hydrogen sulfide (H2S) down to 50 ppm at room temperature. Furthermore, operating temperature effects, H2S concentration and GO suspension concentration on sensor response are also investigated. Functionalized graphene oxide chemiresistors offer advantages such as remarkable potential for mass production due to their ease of manufacturing, significant selectivity and performance.

Keywords:H2S;Amino functionalization;GO;Gas nanosensor

[References]

Lawrence NS, Deo RP, Wang J, Anal. Chim. Acta, 517, 131 (2004)
Dong KY, Choi JK, Hwang I, Lee J, Kang BH, Ham DJ, Lee JH, Ju BK, Sens. Actuators B-Chem., 157, 154 (2011)
Fam DWH, Tok AIY, Palaniappan A, Nopphawan P, Lohani A, Mhaisalkar SG, Sens. Actuators B-Chem., 138, 189 (2009)
Kapse VD, Ghosh SA, Chaudhari GN, Raghuwanshi FC, Gulwade DD, Vacuum, 83, 346 (2009)
Tu JC, Li N, Lai XY, Chi Y, Zhang YJ, Wang W, Li XT, Li JX, Qiu SL, Appl. Surf. Sci., 256(16), 5051 (2010)
Huang XJ, Choi YK, Sens. Actuators B-Chem., 122, 659 (2007)
Capone S, Forleo A, Francioco L, Rella R, Siciliano P, Spadavecchina J, Presicce DS, Taurino AM, J. Optoelectron. Adv. Mater., 5, 1335 (2003)
Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH, Prog. Mater. Sci., 57(7), 1061 (2012)
Sattari S, Reyhani A, Khanlari MR, Khabazian M, Heydari H, J. Ind. Eng. Chem., 20(4), 1761 (2014)
Basu S, Bhattacharyya P, Sens. Actuators B-Chem., 173, 1 (2012)
Pandeya PA, Wilsona NR, Covingtonb JA, Sens. Actuators B-Chem., 183, 478 (2013)
Liu Y, Park M, Shin HK, Pant B, Choi J, Park YW, Lee JY, Park SJ, Kim HY, J. Ind. Eng. Chem., 20(6), 4415 (2014)
Prezioso S, Perrozzi F, Giancaterini L, Cantalini C, Treossi E, Palermo V, Nardone M, Santucci S, Ottaviano L, J. Phys. Chem. C, 117, 10683 (2103)
Yao Y, Xue Y, Sens. Actuators B-Chem., 211, 52 (2015)
Uddin ASM, Phan DT, Chung GS, Sens. Actuators B-Chem., 207, 362 (2015)
Zhou Y, Jiang Y, Xie T, Tai H, Xie G, Sens. Actuators B-Chem., 203, 135 (2014)
Choi S, Jang BH, Lee SJ, Min BK, Rothschild A, Kim ID, Appl. Mater. Interfaces, 6, 2588 (2015)
Gutes A, Hsia B, Sussman A, Mickelson W, Zettl A, Carraroaand C, Maboudian R, Nanoscale, 4, 438 (2012)
Zhou LS, Shen FP, Tian XK, Wang D, Zhang T, Chen W, Nanoscale, 5, 1564 (2013)
Cuong TV, Pham VH, Chung JS, Shin EW, Yoo DH, Hahn SH, Huh JS, Rue GH, Kim EJ, Hur SH, Kohl PA, Mater. Lett., 64, 2479 (2010)
Zhang P, Pan G, Zhang B, Zhen J, Sun Y, Mater. Res., 17, 1439 (2014)
Shen JF, Huang WS, Wu LP, J. Mater. Eng. A, 464(1-2), 151 (2007)
Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115(23), 11540 (2011)
Shen JF, Huang WS, Wu LP, Compos. Pt. A-Appl. Sci. Manuf., 38(5), 1331 (2007)
Stevens JL, Huang AY, Peng HQ, Nano Lett., 3(3), 331 (2003)
Galatsisa K, Cukrovb L, Wlodarskia W, McCormickb P, Kalantar-zadeha K, Cominic E, Sberveglieric G, Sens. Actuators B-Chem., 93, 562 (2003)
Wei BY, Hsu MC, Su PG, Lin HM, Wu RJ, Lai HJ, Sens. Actuators B-Chem., 101, 81 (2004)
Tran TH, Lee JW, Lee K, Lee YD, Ju BK, Sens. Actuators B-Chem., 129, 67 (2008)
Li Y, Wang HC, Yang MJ, Sens. Actuators B-Chem., 121, 496 (2007)

[Referenced By]

[1] Lawrence NS, Deo RP, Wang J, Anal. Chim. Acta, 517, 131 (2004)

[2] Dong KY, Choi JK, Hwang I, Lee J, Kang BH, Ham DJ, Lee JH, Ju BK, Sens. Actuators B-Chem., 157, 154 (2011)

[3] Fam DWH, Tok AIY, Palaniappan A, Nopphawan P, Lohani A, Mhaisalkar SG, Sens. Actuators B-Chem., 138, 189 (2009)

[4] Kapse VD, Ghosh SA, Chaudhari GN, Raghuwanshi FC, Gulwade DD, Vacuum, 83, 346 (2009)

[5] Tu JC, Li N, Lai XY, Chi Y, Zhang YJ, Wang W, Li XT, Li JX, Qiu SL, Appl. Surf. Sci., 256(16), 5051 (2010)

[6] Huang XJ, Choi YK, Sens. Actuators B-Chem., 122, 659 (2007)

[7] Capone S, Forleo A, Francioco L, Rella R, Siciliano P, Spadavecchina J, Presicce DS, Taurino AM, J. Optoelectron. Adv. Mater., 5, 1335 (2003)

[8] Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH, Prog. Mater. Sci., 57(7), 1061 (2012)

[9] Sattari S, Reyhani A, Khanlari MR, Khabazian M, Heydari H, J. Ind. Eng. Chem., 20(4), 1761 (2014)

[10] Basu S, Bhattacharyya P, Sens. Actuators B-Chem., 173, 1 (2012)

[11] Pandeya PA, Wilsona NR, Covingtonb JA, Sens. Actuators B-Chem., 183, 478 (2013)

[12] Liu Y, Park M, Shin HK, Pant B, Choi J, Park YW, Lee JY, Park SJ, Kim HY, J. Ind. Eng. Chem., 20(6), 4415 (2014)

[13] Prezioso S, Perrozzi F, Giancaterini L, Cantalini C, Treossi E, Palermo V, Nardone M, Santucci S, Ottaviano L, J. Phys. Chem. C, 117, 10683 (2103)

[14] Yao Y, Xue Y, Sens. Actuators B-Chem., 211, 52 (2015)

[15] Uddin ASM, Phan DT, Chung GS, Sens. Actuators B-Chem., 207, 362 (2015)

[16] Zhou Y, Jiang Y, Xie T, Tai H, Xie G, Sens. Actuators B-Chem., 203, 135 (2014)

[17] Choi S, Jang BH, Lee SJ, Min BK, Rothschild A, Kim ID, Appl. Mater. Interfaces, 6, 2588 (2015)

[18] Gutes A, Hsia B, Sussman A, Mickelson W, Zettl A, Carraroaand C, Maboudian R, Nanoscale, 4, 438 (2012)

[19] Zhou LS, Shen FP, Tian XK, Wang D, Zhang T, Chen W, Nanoscale, 5, 1564 (2013)

[20] Cuong TV, Pham VH, Chung JS, Shin EW, Yoo DH, Hahn SH, Huh JS, Rue GH, Kim EJ, Hur SH, Kohl PA, Mater. Lett., 64, 2479 (2010)

[21] Zhang P, Pan G, Zhang B, Zhen J, Sun Y, Mater. Res., 17, 1439 (2014)

[22] Shen JF, Huang WS, Wu LP, J. Mater. Eng. A, 464(1-2), 151 (2007)

[23] Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115(23), 11540 (2011)

[24] Shen JF, Huang WS, Wu LP, Compos. Pt. A-Appl. Sci. Manuf., 38(5), 1331 (2007)

[25] Stevens JL, Huang AY, Peng HQ, Nano Lett., 3(3), 331 (2003)

[26] Galatsisa K, Cukrovb L, Wlodarskia W, McCormickb P, Kalantar-zadeha K, Cominic E, Sberveglieric G, Sens. Actuators B-Chem., 93, 562 (2003)

[27] Wei BY, Hsu MC, Su PG, Lin HM, Wu RJ, Lai HJ, Sens. Actuators B-Chem., 101, 81 (2004)

[28] Tran TH, Lee JW, Lee K, Lee YD, Ju BK, Sens. Actuators B-Chem., 129, 67 (2008)

[29] Li Y, Wang HC, Yang MJ, Sens. Actuators B-Chem., 121, 496 (2007)