화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.23, 206-212, March, 2015
Physicochemical properties of mixed micelles composed of chitosan-cinnamic acid conjugate and Pluronic F127-cinnamic acid conjugate
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Chitosan-cinnamic acid conjugate (Chi-CA) and Pluronic F127-cinnamic acid conjugate (Plu-CA) were synthesized for the preparation of mixed micelles. The mixtures of Chi?CA and Plu?CA in the molar ratio of 0.25:1, 0.5:1 and 1:1 were well interface-active. The dimerization degree was in the order of Plu-CA > Chi-CA > free CA. Plu-CA/Chi-CA mixed micelles were circular on TEM, and their mean diameter appreciably decreased when the temperature increased, possibly due to the thermally induced hydrophobic interaction of Plu chains. The temperature-sensitivity was lower when the Chi?CA content was higher. Dry Plu?CA micelles and Plu?CA/Chi?CA mixed micelles exhibited the similar endothermic peak.
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