화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.23, 200-205, March, 2015
DOI10.1016/j.jiec.2014.08.016  Export Citation
Synthesis of 5-hydroxymethylfurfural from fructose over chromium-exchanged hydroxyapatite encapsulated γ-Fe2O3
Junfeng Lan1, 2, and Zehui Zhang1, 3, †
  • 1Key Laboratory of Catalysis and Materials Sciences of the State Ethnic Affairs Commission & Ministry of Education, College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074, China
  • 2Department of Chemistry and Life Science, Liuzhou Teachers College, Liuzhou 545004, China
  • 3, China
E-mail:
A novel magnetically recoverable chromium-exchanged hydroxyapatite encapsulated γ-Fe2O3 was prepared and its structure was characterized by XRD, FT-IR, and XPS technologies. The prepared catalysts were used to catalyze the conversion of carbohydrates into 5-hydroxymethylfurfual in DMSO. Various reaction parameters such as catalyst loading, and reaction temperature were investigated. A high HMF yield 88.9% was obtained at 120 °C after 240 min. More importantly, the catalyst could be easily separated by the application of an external magnet. The catalyst could be reused for several times without the loss of its significant catalytic activities.
Keywords:Carbohydrates;Dehydration;Magnetic catalyst;5-Hydroxymethylfurfual;Green chemistry
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