화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3841-3850, September, 2014
DOI10.1016/j.jiec.2013.12.088  Export Citation
Molecular interactions of cationic gemini surfactants (m-s-m) with an environmental friendly nonionic sugar-based surfactant (β-C12G): Interfacial, micellar and aggregation behavior
Jeenat Aslam, Umme Salma Siddiqui†, Imtiyaz Ahmad Bhat, and Kabir-ud-Din
  • Department of Chemistry, Aligarh Muslim University, Aligarh 202 002, India
E-mail:
In the present study, mixtures of cationic gemini surfactants with a non-ionic sugar-based surfactant in aqueous solutions containing electrolyte (NaBr) have been studied. The experimental results were evaluated using the Regular Solution Theory. The strength of interaction of all the surfactants is attributed to the sterical and electrical factors on mixed monolayer and micelle formation and of surfactant-surfactant interactions. The results show stronger interaction at the air/water interface and greater preference for adsorbing at the air/water interface relative to mixed micelle formation in the solution phase. The alkyl chain length and spacer of gemini govern the aggregation behavior of the mixed micelles.
Keywords:Gemini surfactant;Sugar-based surfactant;Mixed micellization;Relative viscosity;Flourimetry
  1. Hill RM, in: Ogino K, Abe M (Eds.), Mixed Surfactant Systems, Surfactant Science Series, vol. 46, Marcel Dekker, New York, 1993 (Chapter 11).
  2. Holmberg K, in: Holmberg K (Ed.), Novel Surfactants. Preparations, Applications, and Biodegradability, Marcel Dekker, New York, 1998 (Chapter 11).
  3. Rosen MJ, ChemTech, 23, 30 (1993)
  4. Menger FM, Keiper JS, Angew. Chem.-Int. Edit., 39, 1906 (2000)
  5. Zana R, Adv. Colloid Interface Sci., 97, 205 (2002)
  6. Ikeda I, in: Zana R, Xia J (Eds.), Gemini Surfactants: Synthesis, Interfacial and Solution-Phase Behavior, and Applications, Surfactant Science Series, vol. 117, Marcel Dekker, New York, 2004 (Chapter 2).
  7. Kabir-ud-Din, Shafi M, Bhat PA, Dar AA, J. Hazard. Mater., 167(1-3), 575 (2009)
  8. Zana R, Talmon Y, Nature, 362, 228 (1993)
  9. Wettig SD, Verrall RE, Foldvari M, Curr. Gene Therapy, 8, 9 (2008)
  10. Rosenzweig HS, Rakhmanova VA, MacDonald RC, Bioconjugate Chem., 12, 258 (2001)
  11. Ruiz CC (Ed.), Sugar-Based Surfactants: Fundamentals and Applications, Surfactant Science Series, vol. 143, CRC Press, New York, 2009.
  12. Griffiths PC, Stilbs P, Paulsen K, Howe AM, Pitt AR, J. Phys. Chem. B, 101(6), 915 (1997)
  13. Kameyama K, Muroya A, Takagi T, J. Colloid Interface Sci., 1496, 48 (1998)
  14. Okano T, Tamura T, Abe Y, Tsuchida T, Lee S, Sugihara G, Langmuir, 16, 1508 (2000)
  15. Sierra ML, Svensson M, Langmuir, 15(7), 2301 (1999)
  16. Bergstrom M, Jonsson P, Persson M, Eriksson JC, Langmuir, 19(26), 10719 (2003)
  17. Zhang R, Zhang L, Somasundaran P, J. Colloid Interface Sci., 278(2), 453 (2004)
  18. Hierrezuelo JM, Aguiar J, Ruiz CC, Langmuir, 20(24), 10419 (2004)
  19. Hierrezuelo JM, Aguiar J, Ruiz CC, Colloids Surf. A: Physicochem. Eng. Asp., 264, 29 (2005)
  20. Martin VI, Rodriguez A, Graciani MD, Robina I, Moya ML, J. Phys. Chem. B, 114(23), 7817 (2010)
  21. Martin VI, Rodriguez A, Lopez-Cornejo P, Moya ML, Colloids Surf. A: Physicochem. Eng. Asp., 418, 139 (2013)
  22. Ruiz CC, in: Ruiz CC (Ed.), Sugar-Based Surfactants: Fundamentals and Applications, Surfactant Science Series, vol. 143, CRC Press, New York, 2009 (Chapter 11).
  23. Li F, Rosen MJ, Sulthana SB, Langmuir, 17(4), 1037 (2001)
  24. Sugihara G, Miyazono A, Nagadome S, Oida T, Hayaschi Y, Ko JS, J. Oleo Sci., 52, 449 (2003)
  25. Bakshi MS, Kaur G, J. Colloid Interface Sci., 289(2), 551 (2005)
  26. Paddon-Jones G, Regismond S, Kwetkat K, Zana R, J. Colloid Interface Sci., 243(2), 496 (2001)
  27. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
  28. Holmberg K, J. Colloid Interface Sci., 274(2), 355 (2004)
  29. Zana R, Levy H, Colloids Surf. A: Physicochem. Eng. Asp., 127, 229 (1997)
  30. Zana R, in: Holmberg K (Ed.), Novel Surfactants. Preparation, Applications and Biodegradability, Marcel Dekker, New York, 1998 (Chapter 8).
  31. Kabir-ud-Din, Siddiqui US, Kumar S, Colloids Surf. A: Physicochem. Eng. Asp., 301, 209 (2007)
  32. Ozeki S, Ikeda S, J. Colloid Interface Sci., 77, 219 (1980)
  33. Zana R, Benrraou M, Rueff R, Langmuir, 7, 1072 (1991)
  34. Chattoraj DK, Birdi KS, Adsorption and the Gibbs Surface Excess, Plenum Press, New York, 1984.
  35. Anand K, Yadav OP, Singh PP, Colloids Surf., 55, 345 (1991)
  36. Evans DF, Wennestorm H, The Colloidal Domain: Where Physics, Chemistry and Biology Meet, VCH, New York, 1994.
  37. Rosen MJ, Cohen AW, Dahanayake M, Hua X, J. Phys. Chem., 86, 541 (1982)
  38. Ko JS, Oh SW, Kim YS, Nakashima N, Nagadome S, Sugihara G, J. Oleo Sci., 53, 109 (2004)
  39. Rosen MJ, Sulthana SB, J. Colloid Interface Sci., 239(2), 528 (2001)
  40. Clint JH, Surfactant Aggregation, Blackie/Chapman and Hall, Glasgow and London/New York, 1992.
  41. Rubingh DN, Mittal KL (Eds.), Solution Chemistry of Surfactants, vol. 1, Plenum Press, New York, 1979.
  42. Rosen MJ, Colloid J., 109, 35 (1998)
  43. Kalyanasundaram K, Photochemistry in Microheterogeneous Systems, Academic Press, New York, 1987.
  44. Reekmans S, Bernik D, Gehlen M, van Stam J, Van der Auweraer M, De Schryver FC, Langmuir, 9, 2289 (1993)
  45. Stam JV, Depaemelaere S, Schryver FC, J. Chem. Educ., 75, 93 (1998)
  46. Turro NJ, Yekta A, J. Am. Chem. Soc., 100, 5951 (1978)
  47. Kabir-ud-Din, Siddiqui US, Ghosh G, J. Dispersion Sci. Technol., 30, 1310 (2009)
  48. Dar AA, Rather GM, Ghosh S, Das AR, J. Colloid Interface Sci., 322(2), 572 (2008)
  49. Gamboa C, Sepulveda L, J. Colloid Interface Sci., 113, 566 (1986)
  50. Oda R, Huc I, Candau SJ, Chem. Commun., 21, 2105 (1997)
  51. Wang YJ, Marques EF, Pereira CM, Thin Solid Films, 516(21), 7458 (2008)
  52. Israelachvili JN, Mitchell DJ, Ninham BW, J. Chem. Soc.-Faraday Trans., 272, 1525 (1976)
  53. Siddiqui US, Khan F, Khan IA, Dar AA, Kabir-ud-Din, J. Colloid Interface Sci., 355(1), 131 (2011)