QCM and Electrochemical Studies of Li and Zn Intercalation in V6O13(NS)

Heai-Ku Park; Soong-Hyuek Such; W. H. Smyrl

Journal of Industrial and Engineering Chemistry, Vol.1, No.1, 28-35, December, 1995

Heai-Ku Park, Soong-Hyuek Such, and W. H. Smyrl¹

Dept. of Chem. Eng., Keimyung University, Taegu 704-701, Korea
¹Dept. of Chem. Eng. and Materials Science, University of Minnesota, Minneapolis, U. S. A., USA

Quartz crystal microbalance(QCM) and linear sweep voltammetry were employed to perform in situ mass and cahrge measurement on Li/V₆O₁₃(NS) and Zn/V₆O₁₃(NS) cells. At low Li and Zn compositions in V₆O₁₃, the simple metal ion intercalation/release process was observed. But at high Li and Zn compositions, secondary processes(morphology change and other complexities), in addition to simple metal ion insertion, were involved during intercalation process and morphology change occurred during deintercalation process. Early faradaic capacity loss of the cell was largely due to the secondary processes.

[References]

Whittingham MS, Jacobson AJ, "Intercalation Chemistry," 595, Academic Press, New York (1982)
Murphy DW, Christian PA, Science, 205, 651 (1979)
West K, Zachau-Christiansen B, Ostergard MJL, Jacobsen T, J. Power Sources, 20, 165 (1987)
Jacobsen T, West K, Zachau-Christiansen B, Atlung S, Electrochim. Acta, 30, 1205 (1985)
Abraham KM, Goldman JL, Dempsey MD, J. Electrochem. Soc., 128, 2493 (1981)
Murphy DW, Christian PA, Disalvo FJ, Carides JN, Waszczak JV, J. Electrochem. Soc., 128, 2053 (1981)
Naoi K, Oura Y, Maeda M, Nakamura S, J. Electrochem. Soc., 142(2), 417 (1995)
Hillman AR, Loveday DC, Bruckenstein S, Langmuir, 7, 191 (1991)
Kaufman JH, Kanazawa KK, Street FB, Phys. Rev. Lett., 53, 2461 (1984)
Orata D, Buttry DA, J. Am. Chem. Soc., 109, 3574 (1987)
Varineau PT, Buttry DA, J. Phys. Chem., 91, 1292 (1987)
Ward MD, J. Phys. Chem., 92, 2049 (1988)
Naoi K, Lien MM, Smyrl WH, J. Electroanal. Chem., 272, 273 (1989)
Feldman BJ, Melroy OR, J. Electroanal. Chem., 234, 213 (1987)
Masuda H, Baba N, Chem. Lett., 1877 (1987)
Cordoba-Torresi SI, Gabrielli C, Hugot-Legoff A, Torresi R, J. Electrochem. Soc., 138, 1548 (1991)
Ward MD, Buttry DA, Science, 249, 1000 (1990)
Deakin MR, Buttry DA, Anal. Chem., 61, A1147 (1989)
Smyrl WH, Naoi K, "New Monitoring Techniques in Corrosion; Microbalance and Surface Acoustic Devices," in Perspectives on Corrosion, G. Prentice and W.H. Smyrl, AIChE Symposium Series (1990)
Minunni M, Mascini M, Guilbault GG, Hock B, Anal. Lett., 28, 749 (1995)
Sauerbrey G, Z. Phys., 155, 206 (1959)
Schumacher R, Gordon JR, Melroy O, J. Electroanal. Chem., 216, 127 (1987)

[Referenced By]

[1] Whittingham MS, Jacobson AJ, "Intercalation Chemistry," 595, Academic Press, New York (1982)

[2] Murphy DW, Christian PA, Science, 205, 651 (1979)

[3] West K, Zachau-Christiansen B, Ostergard MJL, Jacobsen T, J. Power Sources, 20, 165 (1987)

[4] Jacobsen T, West K, Zachau-Christiansen B, Atlung S, Electrochim. Acta, 30, 1205 (1985)

[5] Abraham KM, Goldman JL, Dempsey MD, J. Electrochem. Soc., 128, 2493 (1981)

[6] Murphy DW, Christian PA, Disalvo FJ, Carides JN, Waszczak JV, J. Electrochem. Soc., 128, 2053 (1981)

[7] Naoi K, Oura Y, Maeda M, Nakamura S, J. Electrochem. Soc., 142(2), 417 (1995)

[8] Hillman AR, Loveday DC, Bruckenstein S, Langmuir, 7, 191 (1991)

[9] Kaufman JH, Kanazawa KK, Street FB, Phys. Rev. Lett., 53, 2461 (1984)

[10] Orata D, Buttry DA, J. Am. Chem. Soc., 109, 3574 (1987)

[11] Varineau PT, Buttry DA, J. Phys. Chem., 91, 1292 (1987)

[12] Ward MD, J. Phys. Chem., 92, 2049 (1988)

[13] Naoi K, Lien MM, Smyrl WH, J. Electroanal. Chem., 272, 273 (1989)

[14] Feldman BJ, Melroy OR, J. Electroanal. Chem., 234, 213 (1987)

[15] Masuda H, Baba N, Chem. Lett., 1877 (1987)

[16] Cordoba-Torresi SI, Gabrielli C, Hugot-Legoff A, Torresi R, J. Electrochem. Soc., 138, 1548 (1991)

[17] Ward MD, Buttry DA, Science, 249, 1000 (1990)

[18] Deakin MR, Buttry DA, Anal. Chem., 61, A1147 (1989)

[19] Smyrl WH, Naoi K, "New Monitoring Techniques in Corrosion; Microbalance and Surface Acoustic Devices," in Perspectives on Corrosion, G. Prentice and W.H. Smyrl, AIChE Symposium Series (1990)

[20] Minunni M, Mascini M, Guilbault GG, Hock B, Anal. Lett., 28, 749 (1995)

[21] Sauerbrey G, Z. Phys., 155, 206 (1959)

[22] Schumacher R, Gordon JR, Melroy O, J. Electroanal. Chem., 216, 127 (1987)