Degradation of tricyclazole by colloidal manganese dioxide in the absence and presence of surfactants

Qamruzzaman; Abu Nasar

Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 897-902, May, 2014

DOI10.1016/j.jiec.2013.06.020 Export Citation

Degradation of tricyclazole by colloidal manganese dioxide in the absence and presence of surfactants

Qamruzzaman, and Abu Nasar^†

Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, India

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The kinetics of the degradation of tricyclazole by water soluble colloidal MnO2 in acidic medium (HClO4) has been studied spectrophotometrically in the absence and presence of surfactants. The experiments have been performed under the pseudo-first-order reaction conditions with respect to MnO2. To determine the rate constant as functions of [tricyclazole], [MnO2] and [HClO4], the pseudo-first-order reaction conditions have been maintained throughout the entire kinetic runs. The degradation has been observed to be first-order with respect to MnO2 while fractional-order in both tricyclazole and HClO4. The anionic surfactant, sodium dodecyl sulfate (SDS) has been observed to be ineffective whereas nonionic surfactant, Triton X-100 (TX-100) accelerates the reaction rate. However, the cationic surfactant cetyl trimethyl ammonium bromide (CTAB) causes flocculation with oppositely charged colloidal MnO2 and therefore could not be studied further. The catalytic effect of TX-100 has been discussed in the light of the mathematical model proposed by Tuncay et al. [25]. The kinetic data have been exploited to generate the various activation parameters for the oxidative degradation of tricyclazole by colloidal MnO2.

Keywords:Kinetics;Tricyclazole;Surfactants;Pseudo-first order;Manganese dioxide

[References]

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Pareja L, Bueno MJM, Cesio V, Heinzen H, Alba ARF, J. Chromatography A, 1218, 4790 (2011)
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[1] Froyd JD, Paget CJ, Guse LR, Dreikorn BA, Pafford JF, Phytopathology, 66, 1135 (1976)

[2] Froyd JD, Guse LR, Kushiro Y, Phytopathology, 68, 818 (1978)

[3] Tokousbalides MC, Sisler HD, Pesticide Biochemistry Physiology, 8, 26 (1978)

[4] Lee JK, Jung HM, Kim SY, Appl. Environ. Microbiol., 69, 3427 (2003)

[5] Wheeler MH, Greenblat GA, Experimental Mycology, 12, 151 (1998)

[6] Butler MJ, Gardiner RB, Day AW, Biological Control, 32, 326 (2005)

[7] Fai PB, Grant A, Chemosphere, 74, 1165 (2009)

[8] Calhela RC, Adrade JV, Ferreira IC, Estevinho LM, Food Microbiology, 23, 393 (2006)

[9] Cuthbertson AGS, Murchie AK, Crop Protection, 22, 1125 (2003)

[10] Tang T, Qian K, Shi T, Wang F, Li J, Cao Y, Anal. Chim. Acta, 680, 26 (2010)

[11] Pareja L, Bueno MJM, Cesio V, Heinzen H, Alba ARF, J. Chromatography A, 1218, 4790 (2011)

[12] Kawata K, Mukai H, Yasuhara A, J. Chromatography A, 710, 243 (1995)

[13] Lee SJ, Park HJ, Kim W, Jin JS, El-Aty AMA, Shim JH, Shin SC, Biomedical Chromatography, 23, 434 (2009)

[14] Preja L, Alba ARF, Cesio V, Heinzen H, Trends in Analytical Chemistry, 30, 270 (2011)

[15] Krieger MS, Cook WL, Kennard LM, J. Agric. Food Chem., 48, 2178 (2000)

[16] Sancho E, Vega CF, Villarroel MJ, Moliner EA, Ferrando MD, Comparative Biochemistry Physiology Part C, 150, 25 (2009)

[17] Padovani L, Capri E, Padovani C, Puglisi E, Trevisan M, Chemosphere, 62, 303 (2006)

[18] John E, Nature’s Building Blocks: An A.Z Guide to the Elements. Oxford, Oxford University, UK, 2001. (2001)

[19] Akram M, Altaf M, Kabir-Ud-Din, Indian J. Chem., 46A, 1427 (2007)

[20] Kabir-Ud-Din, Fatma W, Khan Z, Colloids Surf. A: Physicochem. Eng. Asp., 234, 159 (2004)

[21] Perezbenito JF, Arias C, Amat E, J. Colloid Interface Sci., 177(2), 288 (1996)

[22] Khan Z, Kumar P, Kabir-Ud-Din, Colloids Surf. A: Physicochem. Eng. Asp., 248, 25 (2004)

[23] Akram M, Altaf M, Kabir-Ud-Din, Colloids Surf. B: Biointerfaces, 82, 217 (2011)

[24] Benito JFP, Arias C, J. Colloid Interface Sci., 149, 92 (1992)

[25] Tuncay M, Yuce N, Arlkan B, Gokturk S, Colloids Surf. A: Physicochem. Eng. Asp., 149, 279 (1999)

[26] Kabir-Ud-Din, Iqubal SMS, Khan Z, Colloid Polym. Sci., 284, 276 (2005)

[27] Kabir-Ud-Din, Iqubal SMS, Colloid J., 72, 195 (2010)

[28] Ilyas M, Malik MA, Khan Z, Colloid Polym. Sci., 285, 1169 (2007)

[29] Kabir-Ud-Din, Iqubal SMS, Khan Z, Colloid Polym. Sci., 283, 504 (2005)

[30] Akram M, Altaf M, Kabir-Ud-Din, Al-Thabaiti SA, J. Saudi Chem. Soc., 16, 217 (2012)

[31] Khan Z, Kumar P, Kabir-ud-Din, J. Colloid Interface Sci., 290(1), 184 (2005)

[32] Qamruzzaman, Nasar A, Chemical Papers, http://dx.doi.org/10.2478/s11696-013-0424-7. (2013)

[33] Qamruzzaman, Nasar A, Chem. Sci. Rev. Lett., 1, 113 (2012)

[34] Phong TK, Nhung DTT, Motobayash T, Thuyet DQ, Watanabe H, Water Air Soil Pollut., 202, 03 (2009)

[35] Liu J, Min H, Ye L, Biodegradation, 19, 695 (2008)

[36] Chevalier Y, Zemb T, Reports on Progress in Physics, 53, 279 (1990)

[37] Xiarchos I, Doulia D, J. Hazard. Mater., 136(3), 882 (2006)

[38] Benito JFP, Brillas E, Pouplana R, Inorg. Chem., 28, 390 (1989)

[39] Al-Thabaiti SA, Al-Nowaiser FM, Obaid AY, Al-Youbi AO, Khan Z, Colloid Polym. Sci., 285, 1479 (2007)

[40] Perez FM, Benito JFP, Can. J. Chem., 63, 988 (1985)

[41] Freeman F, Kappos JC, J. Am. Chem. Soc., 107, 6628 (1985)

[42] Richmond W, Tondre C, Krzyzanowska E, Szymanowski J, J. Chem. Soc.-Faraday Trans., 91, 657 (1995)

[43] Son SG, Hebrant M, Tecilla P, Scrimin P, Tondre C, J. Phys. Chem., 96, 11072 (1992)

[44] Laidler KJ, Chemical Kinetics, Tata McGraw Hills, New Delhi, 1973p. 67. (1973)