제염용액에서 IRN-77 양이온수지에 대한 금속이온의 이온교환 특성

양영석

Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.6, 1116-1123, December, 1995

Export Citation

제염용액에서 IRN-77 양이온수지에 대한 금속이온의 이온교환 특성

Ion-Exchange Characteristics of Metal tons on IRN-77 Cation Resin in Decontamination Solution

양영석

초록

Amberlite IRN-77 양이온교환수지는 철과 코발트이온에 대해서 비슷한 이온교환용량을 보였다. 그러나 제염용액내 유기산 가운데 EDTA는 철이온 보다 코발트이온과 강한 착화합물을 형성하여 코발트이온에 대한 이온교환용량을 현저히 감소시키는 주요원인이었다. 반면에 oxalic acid와 citiric acid의 영향은 미미하였다. 이같은 이온교환공정에 지배적인 영향을 미치는 EDTA하에서 균일상 입자내 확산모델을 적용하여 구한 철과 코발트이온의 입자내 확산계수는 각각 0.82×10^-8∼ 3.78×10^-8㎠/sec와 1.33×10^-8∼3.45×10^-8㎠/sec 이었다.

Amberlite IRN-77 cation exchange resin showed similar ion exchange capacities to ferrous ion and cobaltous ion. But, EDTA contained as one of organic acid formed stronger complex with cobaltous ion than ferrous ion and diminished the ion exchange capacity to cobaltous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. Also, in the presence of EDTA dominantly affecting on the ion exchange process, intraparticle diffusivities of the ferrous ion and cobaltous ion were determined by the homogeneous intraparticle model and they were 0.82 ×10^-8∼3.78×10^-8 ㎠/sec and 1.33×10^-8∼3.45×10^-8 ㎠/sec, respectively.

[References]

Perrigo LD, Divine JR, "Decontamination Method," Pacific Norhwest Laboratory-SA-7770 (1980)
NEA Group, "Decontamination Methods as RElated to Decommissioning of Nuclear Facilities," NEA (1981)
Shaw RA, Naughton MD, Miller AD, "Decontamination and Deconmmissioning of Nuclear Facilities," 679, Plenum Press, New York (1980)
Zimmerman GJ, Smee JL, "Development of an Improved Reagent for CAN-DECON Decontamination Reagents by Cation Exchange Resin," AECL, WNRE-288 (1976)
Smee JL, "Development of an Improved Reagent for the CAN-DECON Decontamination Process; Part I, Some Theoretical Considerations," AECL, WNRE-239 (1975)
Smee JL, "Decontamination and Decommissioning of Nuclear Facilities," 281, Plenum Press, New York (1980)
Ringbom A, "Complexation in Analytical Chemistry," Chemical Analysis, VI, Interscience Publishers, New York (1963)
Swee CF, Richard GR, Ind. Eng. Chem. Fundam., 18, 68 (1979)
Crank J, "The Mathematics of Diffusion," 2, Chap. 6, ClarendonPress, Oxford (1975)
Barry BJ, "Colorimetric Determination of Iron in CAN-DECON Solution using o-Phenanthroline," AECL, Private Memorandom, Jan, 19 (1984)
Pronin AY, Musave SK, Chmutov KV, Russ. J. Phys. Chem., 40, 638 (1969)
Glueckauf E, Coates JI, J. Chem. Soc., 1315 (1947)
Helfferich FG, "Ion Exchange," 264, McGraw-Hill Book Co., New York (1962)
Huang TC, Weng HS, Tseng TT, J. Inorg. Nucl. Chem., 31, 183 (1969)
Huang TC, Li KY, Ind. Eng. Chem. Fundam., 12, 50 (1973)

[1] Perrigo LD, Divine JR, "Decontamination Method," Pacific Norhwest Laboratory-SA-7770 (1980)

[2] NEA Group, "Decontamination Methods as RElated to Decommissioning of Nuclear Facilities," NEA (1981)

[3] Shaw RA, Naughton MD, Miller AD, "Decontamination and Deconmmissioning of Nuclear Facilities," 679, Plenum Press, New York (1980)

[4] Zimmerman GJ, Smee JL, "Development of an Improved Reagent for CAN-DECON Decontamination Reagents by Cation Exchange Resin," AECL, WNRE-288 (1976)

[5] Smee JL, "Development of an Improved Reagent for the CAN-DECON Decontamination Process; Part I, Some Theoretical Considerations," AECL, WNRE-239 (1975)

[6] Smee JL, "Decontamination and Decommissioning of Nuclear Facilities," 281, Plenum Press, New York (1980)

[7] Ringbom A, "Complexation in Analytical Chemistry," Chemical Analysis, VI, Interscience Publishers, New York (1963)

[8] Swee CF, Richard GR, Ind. Eng. Chem. Fundam., 18, 68 (1979)

[9] Crank J, "The Mathematics of Diffusion," 2, Chap. 6, ClarendonPress, Oxford (1975)

[10] Barry BJ, "Colorimetric Determination of Iron in CAN-DECON Solution using o-Phenanthroline," AECL, Private Memorandom, Jan, 19 (1984)

[11] Pronin AY, Musave SK, Chmutov KV, Russ. J. Phys. Chem., 40, 638 (1969)

[12] Glueckauf E, Coates JI, J. Chem. Soc., 1315 (1947)

[13] Helfferich FG, "Ion Exchange," 264, McGraw-Hill Book Co., New York (1962)

[14] Huang TC, Weng HS, Tseng TT, J. Inorg. Nucl. Chem., 31, 183 (1969)

[15] Huang TC, Li KY, Ind. Eng. Chem. Fundam., 12, 50 (1973)