Low Swelling Poly(ester) Urethane Composite Containing Modified Hollow Glass Microspheres for Seawater-Resistant Encapsulant

Yuseon Heo; Hyungu Im; Sungjin Yun; Jooheon Kim

Macromolecular Research, Vol.20, No.12, 1271-1280, December, 2012

DOI10.1007/s13233-012-0192-1 Export Citation

Low Swelling Poly(ester) Urethane Composite Containing Modified Hollow Glass Microspheres for Seawater-Resistant Encapsulant

Yuseon Heo, Hyungu Im, Sungjin Yun, and Jooheon Kim^†

School of Chemical Engineering & Material Science, Chung-Ang University, Seoul, 156-756, Korea

E-mail:

A novel poly(ester) urethane system filled with poly(ester) urethane grafted with hollow glass microspheres was fabricated via a melt mixing method for use as an underwater encapsulant. The poly(ester) urethane/poly(ester) urethane grafted with hollow glass microsphere (HGM) composites (PU/PU-g-HGM composites) were prepared using various PU-g-HGM contents. Studies of these composites showed that the swelling ratio of PU/PUg-HGM composites in seawater and paraffin oil decreased with increasing HGM content of grafted poly(ester) urethane, while the tensile strength of PU/PU-g-HGM composites could be incrementally increased by rising PU-g-HGM content. This finding is due to the enhanced interfacial adhesion between poly(ester) urethane and poly(ester) urethane-grafted HGM due to good compatibility between these components. The tensile strength of the PU/PU-g-HGM composites in seawater (or paraffin oil) also exhibited higher levels than those of poly(ester) urethane and PU/pristine HGMs composites in seawater (or paraffin oil) as the immersion time increased. Therefore, the PU/PU-g-HGM composites were expected to have potential applications as underwater encapsulants.

Keywords:poly(ester) urethane;hollow glass microsphere;marine applications;encapsulant.

[References]

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