화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 1893-1901, November, 2012
DOI10.1016/j.jiec.2012.04.019  Export Citation
5-Hydroxymethylfurfural production from sugars and cellulose in acid- and base-catalyzed conditions under hot compressed water
Pornlada Daorattanachai, Supawadee Namuangruk1, Nawin Viriya-empikul1, Navadol Laosiripojana, and Kajornsak Faungnawakij1, †
  • The Joint Graduate School of Energy and Environment (JGSEE), King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand
  • 1National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Klong Laung, Pathumthani 12120, Thailand
E-mail:
The conversion of glucose, fructose, and cellulose to 5-hydroxymethylfurfural (HMF) was studied under hot compressed water. The effect of acid (H3PO4) and base (NaOH) catalysts was examined by combining experimental and theoretical studies. The experimental results showed that formation of HMF from fructose is more facile than that from glucose and cellulose. The density functional calculations explained the effect of catalysts on reaction mechanism and energy profile of glucose transformation. The ring-opening of b-glucose is predicted as the rate-limiting step in non-catalytic system, while the tautomerization or the hydride-shift is the rate-limiting step in the basic and acidic conditions, respectively.
Keywords:Hot compressed water;Phosphoric acid;5-Hydroxymethylfurfural;Density functional theory;Isomerization;Enediol intermediate
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