Thin Solid Films, Vol.518, No.24, 7541-7544, 2010
The influence on immersion time of titanium conversion coatings on electrogalvanized steel
The study aims to replace chromate treatments of electrogalvanized steels by immersing the electrogalvanized steel in a titanium trichloride (TiCl(3)) bath. The influence of immersion time on surface morphology and corrosion resistance of the titanium conversion coatings was investigated. The titanium conversion coating prepared for 300 s immersion time with a uniform structure has the most excellent anticorrosive performance. Furthermore, the coating comprises a loose outer layer and a dense inner layer structure with a thickness of 150 nm. X-ray photoelectron spectroscope analysis shows that the coating consisted of Zn and Ti oxides and/or hydroxides. (C) 2010 Elsevier B.V. All rights reserved.