Thin Solid Films, Vol.518, No.4, 1140-1144, 2009
Microstructure-Property relationships in thin film ITO
Polycrystalline tin-doped indium oxide (ITO) thin films were prepared by pulsed laser deposition (PLD) with an ITO (In(2)O(3)-10 wt.% SnO(2)) target and deposited on borosilicate glass substrates. By changing independently the deposition temperature and the oxygen pressure, a variety of microstructures were deposited. These different microstructures were mainly investigated not only by transmission electron microscopy (TEM) with cross-section and plan-view electron micrographs, but also by scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction. Composition changes in ITO thin films grown under different deposition conditions were characterized by energy dispersive X-ray spectroscopy (EDX). The optical and electrical properties were studied respectively by UV-visible spectrophotometry and a four-point probe. The best compromise in terms of high transmittance (T) in the visible range and low resistivity (rho) was obtained for films deposited between 0.66 and 2 Pa oxygen pressure (Po(2)) at 200 degrees C substrate temperature (T(s)). The influence of Po(2) and T(s) on the microstructure and ITO film properties is discussed. (C) 2009 Elsevier B.V. All rights reserved.
Keywords:Indium tin oxide;Pulsed laser deposition;Microstructure;Transmission electron microscopy;Crystallization