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Petroleum Chemistry, Vol.52, No.3, 139-154, 2012
Tetramerization of ethylene to octene-1 (a review)
Data on the activity, selectivity, and reaction conditions for the selective oligomerization of ethylene to octene-1 mediated by chromium-containing organic compounds in combination with organoaluminum compounds have been summarized and analyzed. Possible schemes for the mechanism of the formation of octene-1 and byproduct cyclic hydrocarbons (methylenecyclopentane and methylcyclopentane) and higher (> C-8) linear olefins have been briefly discussed.