화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 봄 (05/13 ~ 05/14, BEXCO(부산))
권호 14권 1호
발표분야 정밀화학
제목 A synthetic method for quarternary ammonium salts as eco-friendly surfactant through the reaction of 3-alkoxy-2-hydroxypropyl chloride or alkyl 2,3-epoxypropyl ether with tertiary amines
초록 Alkyl alcohols derived from fatty acids with different degrees of carbon numbers were reacted with epichlorohydrin to provide 3-alkoxy-2-hydroxypropyl chlorides in the presence of H2SO4 and alkyl 2,3-epoxypropyl ether with equimolar amount of NaOH. These chlorides were subsequently reacted with various tertiary amine derivatives with long alkyl groups to afford corresponding quarteranary ammonium salts. The reaction products were unambiguously characterized via 1D & 2D NMR spectroscopic methods . These salts can serve as environment-friendly surfactants.
저자 Md. Maniruzzaman Manir1, 유현아1, 김형규2, 최규용2, 김병조2, 이종기2, 문석식1
소속 1공주대, 2에이케이켐텍(주)
키워드 environment-friendly surfactants; quarternary ammonium salts; 3-alkoxy-2-hydroxypropyl chloride
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