화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 고분자 합성
제목 Compressed liquid DME, New Solvent for dispersion polymerization without the separation process
초록 Dimethyl ether (DME) has received a great deal of attention in industrial application. After DME prove to be the eco-friendly chemical material, more researchers take part in the DME application project. We found that a variety of monomeres can be dissolved in the compressed liquid phase of DME due to its chemically polar property. Compressed liquid DME can be used as polymerization media. To investigate monomers which can be used for synthesis of spherical polymer particle via dispersion polymerization, the experiments are performed with changing monomer. N-vinyl carbazole, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, acrylonitrile, glycidyl methacrylate, and Acrylic acid have been carried. The polymer morphology was characterized using a field emission scanning electron microscope (FE-SEM). The number-average particle size and the particle size distribution (PSD) were assessed with and image analyzer, TDI Scope Eye version 3.1, with FE-SEM images.
저자 조동우1, 오경실2, 배원3, 김화용1
소속 1서울대, 2LG화학, 3미원스페셜티케미컬
키워드 dimethyl ether; DME; compressed liquid DME; dispersion polymerization
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