| 학회 |
한국화학공학회 |
| 학술대회 |
2012년 봄 (04/25 ~ 04/27, 제주 ICC) |
| 권호 |
18권 1호, p.1081 |
| 발표분야 |
촉매 |
| 제목 |
Visible light Photocatalysis with Tetrakis(4-carboxyphenyl)porphyrin bridged periodic mesoporous organosilica |
| 초록 |
In this work, A new route is introduced for J-aggregated TCPP (tetrakis(4-carboxyphenyl)porphyrin) moiety bridged periodic mesoporous organosilica (PMO) which could give chirality by chiral inductor factors such as specific CTAB ratio, D/L-(-/+)-tartaric acid. These are because of so-called chiral symmetry breaking of TCPP-silane during assembly. These materials were illustrated to give superiority in the oxidation of various alcohols under sunlight as well as hydrogenations. |
| 저자 |
정은영, 박상언
|
| 소속 |
인하대 |
| 키워드 |
Tetrakis(4-carboxyphenyl)porphyrin bridged periodic mesoporous organosilica |
| E-Mail |
|
| 원문파일 |
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